Disclosing chirality in consecutive supramolecular polymerizations: chiral induction by light in N-annulated perylenetetracarboxamides

A multichiroptical characterization of the different aggregates formed by the consecutive supramolecular polymerization of chiral N-annulated perylenetetracarboxamides is reported. They form one-handed helical aggregates, which emit circularly polarized light with remarkable |glum| values. In additi...

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Veröffentlicht in:Chemical communications (Cambridge, England) England), 2020-02, Vol.56 (15), p.2244-2247
Hauptverfasser: Greciano, Elisa E, Rodríguez, Rafael, Maeda, Katsuhiro, Sánchez, Luis
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Rodríguez, Rafael
Maeda, Katsuhiro
Sánchez, Luis
description A multichiroptical characterization of the different aggregates formed by the consecutive supramolecular polymerization of chiral N-annulated perylenetetracarboxamides is reported. They form one-handed helical aggregates, which emit circularly polarized light with remarkable |glum| values. In addition, the chiral induction by circularly polarized light in the supramolecular polymerization of the achiral counterpart is demonstrated.
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subjects Aggregates
Chirality
Circular polarization
Polarized light
Polymerization
title Disclosing chirality in consecutive supramolecular polymerizations: chiral induction by light in N-annulated perylenetetracarboxamides
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