Rhodium‐Catalyzed ortho‐Bromination of O‐Phenyl Carbamates Accelerated by a Secondary Amide‐Pendant Cyclopentadienyl Ligand

It has been established that a newly developed cyclopentadienyl rhodium(III) [CpARhIII] complex, bearing an acidic secondary amide moiety on the Cp ring, is able to catalyze the ortho‐bromination of O‐phenyl carbamates with N‐bromosuccinimide (NBS) at room temperature. The presence of the acidic sec...

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Veröffentlicht in:	Chemistry : a European journal 2020-05, Vol.26 (26), p.5774-5779
Hauptverfasser:	Tanaka, Jin, Shibata, Yu, Joseph, Anton, Nogami, Juntaro, Terasawa, Jyunichi, Yoshimura, Ryo, Tanaka, Ken
Format:	Artikel
Sprache:	eng
Schlagworte:	Bromination Carbamates (tradename) Carbonyl compounds Carbonyl groups Carbonyls Chemistry cyclopentadienyl ligand hydrogen bond Hydrogen bonds Ligands ortho-bromination phenyl carbamates Rhodium Room temperature
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