Intramolecular Magnetic Interaction of Spin‐Delocalized Neutral Radicals through m‐Phenylene Spacers

A new diradical having two 4,8,10‐trioxotriangulene (TOT) neutral radical units linked through an m‐phenylene moiety was synthesized and characterized by ESR measurements. An electrochemical study showed that the diradical undergoes two one‐electron reductions to generate corresponding dianion speci...

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Veröffentlicht in:	ChemPlusChem (Weinheim, Germany) Germany), 2019-06, Vol.84 (6), p.680-685
Hauptverfasser:	Murata, Tsuyoshi, Asakura, Noriaki, Ukai, Shusaku, Ueda, Akira, Kanzaki, Yuki, Sato, Kazunobu, Takui, Takeji, Morita, Yasushi
Format:	Artikel
Sprache:	eng
Schlagworte:	Anions Chemistry Couplings Dimers Electrochemistry electron spin resonance ferromagnetic interactions Ferromagnetism neutral diradicals spin delocalization Temperature dependence trioxotriangulenes
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