Influence of Solvent in Crystal Engineering: A Significant Change to the Order–Disorder Transition in Ferrocene

We present the structure of a novel solvate adduct formed by dissolving ferrocene, FeCp2, in hexafluorobenzene, C6F6. This adduct demonstrates the remarkably strong interactions between the five-membered aromatic rings of FeCp2 and the six-membered aromatic ring of C6F6. These molecular interactions...

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Veröffentlicht in:	Journal of the American Chemical Society 2020-01, Vol.142 (4), p.1731-1734
Hauptverfasser:	Bear, Joseph C, Cockcroft, Jeremy K, Williams, Jeffrey H
Format:	Artikel
Sprache:	eng
Online-Zugang:	Volltext
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