Acrylic ampholytic ionomers
In a continuing study of the preparation of ampholytic ionomers from the polymerization of ion-pair comonomers (cationic-anionic monomer pairs) with nonionic comonomers, the preparation of such ionomers from methyl methacrylate and n-butyl acrylate is described. For both systems, ionomers of varying...
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| Veröffentlicht in: | Polymer (Guilford) 1982-01, Vol.23 (6), p.843-848 |
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| container_title | Polymer (Guilford) |
| container_volume | 23 |
| creator | Salamone, J.C Mahmud, N.A Mahmud, M.U Nagabhushanam, T Watterson, A.C |
| description | In a continuing study of the preparation of ampholytic ionomers from the polymerization of ion-pair comonomers (cationic-anionic monomer pairs) with nonionic comonomers, the preparation of such ionomers from methyl methacrylate and n-butyl acrylate is described. For both systems, ionomers of varying ion contents were obtained. In the n-butyl acrylate system, a linear relationship of
T
q
vs. mol % ion content was found, but this did not occur for the methyl methacrylate ionomers. The solubilities of these materials in a wide variety of solvents is discussed. It appears that for n-butyl acrylate ionomers of high ion content in aqueous solution, a new form of polymeric surfactant is obtained. |
| doi_str_mv | 10.1016/0032-3861(82)90144-6 |
| format | Article |
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T
q
vs. mol % ion content was found, but this did not occur for the methyl methacrylate ionomers. The solubilities of these materials in a wide variety of solvents is discussed. It appears that for n-butyl acrylate ionomers of high ion content in aqueous solution, a new form of polymeric surfactant is obtained.</description><identifier>ISSN: 0032-3861</identifier><identifier>EISSN: 1873-2291</identifier><identifier>DOI: 10.1016/0032-3861(82)90144-6</identifier><language>eng</language><publisher>Elsevier Ltd</publisher><subject>ampholytic ionomers ; Ion-pair comonomers ; polyampholytes ; polymerization</subject><ispartof>Polymer (Guilford), 1982-01, Vol.23 (6), p.843-848</ispartof><rights>1982</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c335t-c191c5aa2751782e10f73ba2c9980774af0431d6641ef49f681b193d9a420b463</citedby><cites>FETCH-LOGICAL-c335t-c191c5aa2751782e10f73ba2c9980774af0431d6641ef49f681b193d9a420b463</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktohtml>$$Uhttps://dx.doi.org/10.1016/0032-3861(82)90144-6$$EHTML$$P50$$Gelsevier$$H</linktohtml><link.rule.ids>315,781,785,3551,27929,27930,46000</link.rule.ids></links><search><creatorcontrib>Salamone, J.C</creatorcontrib><creatorcontrib>Mahmud, N.A</creatorcontrib><creatorcontrib>Mahmud, M.U</creatorcontrib><creatorcontrib>Nagabhushanam, T</creatorcontrib><creatorcontrib>Watterson, A.C</creatorcontrib><title>Acrylic ampholytic ionomers</title><title>Polymer (Guilford)</title><description>In a continuing study of the preparation of ampholytic ionomers from the polymerization of ion-pair comonomers (cationic-anionic monomer pairs) with nonionic comonomers, the preparation of such ionomers from methyl methacrylate and n-butyl acrylate is described. For both systems, ionomers of varying ion contents were obtained. In the n-butyl acrylate system, a linear relationship of
T
q
vs. mol % ion content was found, but this did not occur for the methyl methacrylate ionomers. The solubilities of these materials in a wide variety of solvents is discussed. It appears that for n-butyl acrylate ionomers of high ion content in aqueous solution, a new form of polymeric surfactant is obtained.</description><subject>ampholytic ionomers</subject><subject>Ion-pair comonomers</subject><subject>polyampholytes</subject><subject>polymerization</subject><issn>0032-3861</issn><issn>1873-2291</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>1982</creationdate><recordtype>article</recordtype><recordid>eNp9kE1LAzEURYMoWKu_QBeuRBej7yWZTLIRSvELCm50HdLMG4zMNGMyFfrv27Hi0tV7i3MP3MvYBcItAqo7AMELoRVea35jAKUs1AGboK5EwbnBQzb5Q47ZSc6fAMBLLifsfObTpg3-0nX9R2w3w-4NcRU7SvmUHTWuzXT2e6fs_fHhbf5cLF6fXuazReGFKIfCo0FfOserEivNCaGpxNJxb4yGqpKuASmwVkoiNdI0SuMSjaiNkxyWUokpu9p7-xS_1pQH24XsqW3diuI6Wy6EUqaUO1DuQZ9izoka26fQubSxCHZcwo417VjTam5_lrCj_34fo12J70DJZh9o5akOifxg6xj-F2wBO1ZiXQ</recordid><startdate>19820101</startdate><enddate>19820101</enddate><creator>Salamone, J.C</creator><creator>Mahmud, N.A</creator><creator>Mahmud, M.U</creator><creator>Nagabhushanam, T</creator><creator>Watterson, A.C</creator><general>Elsevier Ltd</general><scope>AAYXX</scope><scope>CITATION</scope><scope>8FD</scope><scope>F28</scope><scope>FR3</scope></search><sort><creationdate>19820101</creationdate><title>Acrylic ampholytic ionomers</title><author>Salamone, J.C ; Mahmud, N.A ; Mahmud, M.U ; Nagabhushanam, T ; Watterson, A.C</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c335t-c191c5aa2751782e10f73ba2c9980774af0431d6641ef49f681b193d9a420b463</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>1982</creationdate><topic>ampholytic ionomers</topic><topic>Ion-pair comonomers</topic><topic>polyampholytes</topic><topic>polymerization</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Salamone, J.C</creatorcontrib><creatorcontrib>Mahmud, N.A</creatorcontrib><creatorcontrib>Mahmud, M.U</creatorcontrib><creatorcontrib>Nagabhushanam, T</creatorcontrib><creatorcontrib>Watterson, A.C</creatorcontrib><collection>CrossRef</collection><collection>Technology Research Database</collection><collection>ANTE: Abstracts in New Technology & Engineering</collection><collection>Engineering Research Database</collection><jtitle>Polymer (Guilford)</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Salamone, J.C</au><au>Mahmud, N.A</au><au>Mahmud, M.U</au><au>Nagabhushanam, T</au><au>Watterson, A.C</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Acrylic ampholytic ionomers</atitle><jtitle>Polymer (Guilford)</jtitle><date>1982-01-01</date><risdate>1982</risdate><volume>23</volume><issue>6</issue><spage>843</spage><epage>848</epage><pages>843-848</pages><issn>0032-3861</issn><eissn>1873-2291</eissn><abstract>In a continuing study of the preparation of ampholytic ionomers from the polymerization of ion-pair comonomers (cationic-anionic monomer pairs) with nonionic comonomers, the preparation of such ionomers from methyl methacrylate and n-butyl acrylate is described. For both systems, ionomers of varying ion contents were obtained. In the n-butyl acrylate system, a linear relationship of
T
q
vs. mol % ion content was found, but this did not occur for the methyl methacrylate ionomers. The solubilities of these materials in a wide variety of solvents is discussed. It appears that for n-butyl acrylate ionomers of high ion content in aqueous solution, a new form of polymeric surfactant is obtained.</abstract><pub>Elsevier Ltd</pub><doi>10.1016/0032-3861(82)90144-6</doi><tpages>6</tpages></addata></record> |
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| ispartof | Polymer (Guilford), 1982-01, Vol.23 (6), p.843-848 |
| issn | 0032-3861 1873-2291 |
| language | eng |
| recordid | cdi_proquest_miscellaneous_23366954 |
| source | Access via ScienceDirect (Elsevier) |
| subjects | ampholytic ionomers Ion-pair comonomers polyampholytes polymerization |
| title | Acrylic ampholytic ionomers |
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