Correlation and Relativistic Effects in Spin-Orbit Splitting

A pronounced discrepancy between Dirac-Fock calculations and experiment for the spin-orbit splitting, 2P 1/2 - 2P 3/2, in the ground states of B- and F-like ions is resolved. The discrepancy arises from the spurious terms inherent in the relativistic self-consistent-field (SCF) procedure. Removal of...

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Veröffentlicht in:	Phys. Rev. Lett.; (United States) 1982-05, Vol.48 (18), p.1245-1248
Hauptverfasser:	Huang, K. -N., Kim, Y. -K., Cheng, K. T., Desclaux, J. P.
Format:	Artikel
Sprache:	eng
Schlagworte:	640305 - Atomic, Molecular & Chemical Physics- Atomic & Molecular Theory- (-1987) ATOMIC AND MOLECULAR PHYSICS ATOMIC IONS CHARGED PARTICLES CONFIGURATION INTERACTION CORRELATIONS COUPLING ENERGY LEVELS FUNCTIONS INTERMEDIATE COUPLING IONS L-S COUPLING SELF-CONSISTENT FIELD WAVE FUNCTIONS
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