Compositional changes adjacent to grain boundaries during electrical degradation of a ZnO varistor

Compositional changes adjacent to grain boundaries in heavily degraded samples of a ZnO varistor containing the additives Bi and Co have been observed with the scanning transmission electron microscope. A marked asymmetry in the distribution of Bi and Co with respect to the physical location of the...

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Veröffentlicht in:J. Appl. Phys.; (United States) 1982-03, Vol.53 (3), p.1765-1768
Hauptverfasser: Chiang, Yet-Ming, Kingery, W. D., Levinson, Lionel M.
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container_title J. Appl. Phys.; (United States)
container_volume 53
creator Chiang, Yet-Ming
Kingery, W. D.
Levinson, Lionel M.
description Compositional changes adjacent to grain boundaries in heavily degraded samples of a ZnO varistor containing the additives Bi and Co have been observed with the scanning transmission electron microscope. A marked asymmetry in the distribution of Bi and Co with respect to the physical location of the boundary is found, consistent with the accumulation of mobile cations on one side of the boundary under the influence of a dc electric field.
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identifier ISSN: 0021-8979
ispartof J. Appl. Phys.; (United States), 1982-03, Vol.53 (3), p.1765-1768
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language eng
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subjects 360602 - Other Materials- Structure & Phase Studies
ALLOYS
BISMUTH ADDITIONS
BISMUTH ALLOYS
CATIONS
CHALCOGENIDES
CHARGED PARTICLES
COBALT ADDITIONS
COBALT ALLOYS
CRYSTAL STRUCTURE
CURRENTS
DIRECT CURRENT
DISTRIBUTION
ELECTRIC CURRENTS
ELECTRIC FIELDS
ELECTRICAL EQUIPMENT
ELECTRON MICROSCOPY
GRAIN BOUNDARIES
IONS
MATERIALS SCIENCE
MICROSCOPY
MICROSTRUCTURE
OXIDES
OXYGEN COMPOUNDS
QUANTITY RATIO
RESISTORS
SCANNING ELECTRON MICROSCOPY
SEMICONDUCTOR DEVICES
SEMICONDUCTOR RESISTORS
SPATIAL DISTRIBUTION
TRANSMISSION ELECTRON MICROSCOPY
ZINC COMPOUNDS
ZINC OXIDES
title Compositional changes adjacent to grain boundaries during electrical degradation of a ZnO varistor
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