Computer modeling study of photochemical ozone formation in the propene-nitrogen oxides-dry air system. Generalized maximum ozone isopleth
Computer simulation for the propene-nitrogen oxides-dry air system was performed by using a detailed reaction model in order to represent previous experimental results. The proportional relationships between (0/sub 3/)/sub max/ and (0/sub 3/)/sub ps/, (NO/sub x/)/sub 0//sup 1///sup 2/, and K/sub 1//...
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| Veröffentlicht in: | Environ. Sci. Technol.; (United States) 1982-01, Vol.16 (1), p.45-52 |
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| container_title | Environ. Sci. Technol.; (United States) |
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| creator | Sakamaki, Fumio Okuda, Michio Akimoto, Hajime Yamazaki, Hideo |
| description | Computer simulation for the propene-nitrogen oxides-dry air system was performed by using a detailed reaction model in order to represent previous experimental results. The proportional relationships between (0/sub 3/)/sub max/ and (0/sub 3/)/sub ps/, (NO/sub x/)/sub 0//sup 1///sup 2/, and K/sub 1//sup 1///sup 2/ were sucessfully reproduced by the model. Based on the calculated data, the plot of (0/sub 3/)/sub max//(0/sub 3/)/sub ps/ vs. (C/sub 3/H/sub 6/)/sub 0//(NO/sub x/)/sub 0/ was found to fall on a single common curve, which is called a generalized maximum ozone isopleth. In the falloff region of the above plot, an approximate linear relationship between (0/sub 3/)/sub max//(0/sub 3/)/sub ps/ and ((C/sub 3/H/sub 6/)/sub 0//(NO/sub x/)/sub 0/)/sup 1///sup 2/ was obtained, implying that (0/sub 3/)/sub max/ is linear with (C/sub 3/H/sub 6/)/sub 0//sup 1///sup 2/ in the NO/sub x/-excess region. |
| doi_str_mv | 10.1021/es00095a012 |
| format | Article |
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In the falloff region of the above plot, an approximate linear relationship between (0/sub 3/)/sub max//(0/sub 3/)/sub ps/ and ((C/sub 3/H/sub 6/)/sub 0//(NO/sub x/)/sub 0/)/sup 1///sup 2/ was obtained, implying that (0/sub 3/)/sub max/ is linear with (C/sub 3/H/sub 6/)/sub 0//sup 1///sup 2/ in the NO/sub x/-excess region.</description><identifier>ISSN: 0013-936X</identifier><identifier>EISSN: 1520-5851</identifier><identifier>DOI: 10.1021/es00095a012</identifier><language>eng</language><publisher>United States: American Chemical Society</publisher><subject>500200 - Environment, Atmospheric- Chemicals Monitoring & Transport- (-1989) ; ALKENES ; CHALCOGENIDES ; CHEMICAL REACTIONS ; COMPUTERIZED SIMULATION ; ELEMENTS ; ENVIRONMENTAL SCIENCES ; HYDROCARBONS ; MATHEMATICAL MODELS ; NITROGEN ; NITROGEN COMPOUNDS ; NITROGEN OXIDES ; NONMETALS ; ORGANIC COMPOUNDS ; OXIDES ; OXYGEN COMPOUNDS ; OZONE ; PHOTOCHEMICAL REACTIONS ; PROPYLENE ; SIMULATION</subject><ispartof>Environ. Sci. 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Generalized maximum ozone isopleth</title><title>Environ. Sci. Technol.; (United States)</title><addtitle>Environ. Sci. Technol</addtitle><description>Computer simulation for the propene-nitrogen oxides-dry air system was performed by using a detailed reaction model in order to represent previous experimental results. The proportional relationships between (0/sub 3/)/sub max/ and (0/sub 3/)/sub ps/, (NO/sub x/)/sub 0//sup 1///sup 2/, and K/sub 1//sup 1///sup 2/ were sucessfully reproduced by the model. Based on the calculated data, the plot of (0/sub 3/)/sub max//(0/sub 3/)/sub ps/ vs. (C/sub 3/H/sub 6/)/sub 0//(NO/sub x/)/sub 0/ was found to fall on a single common curve, which is called a generalized maximum ozone isopleth. In the falloff region of the above plot, an approximate linear relationship between (0/sub 3/)/sub max//(0/sub 3/)/sub ps/ and ((C/sub 3/H/sub 6/)/sub 0//(NO/sub x/)/sub 0/)/sup 1///sup 2/ was obtained, implying that (0/sub 3/)/sub max/ is linear with (C/sub 3/H/sub 6/)/sub 0//sup 1///sup 2/ in the NO/sub x/-excess region.</description><subject>500200 - Environment, Atmospheric- Chemicals Monitoring & Transport- (-1989)</subject><subject>ALKENES</subject><subject>CHALCOGENIDES</subject><subject>CHEMICAL REACTIONS</subject><subject>COMPUTERIZED SIMULATION</subject><subject>ELEMENTS</subject><subject>ENVIRONMENTAL SCIENCES</subject><subject>HYDROCARBONS</subject><subject>MATHEMATICAL MODELS</subject><subject>NITROGEN</subject><subject>NITROGEN COMPOUNDS</subject><subject>NITROGEN OXIDES</subject><subject>NONMETALS</subject><subject>ORGANIC COMPOUNDS</subject><subject>OXIDES</subject><subject>OXYGEN COMPOUNDS</subject><subject>OZONE</subject><subject>PHOTOCHEMICAL REACTIONS</subject><subject>PROPYLENE</subject><subject>SIMULATION</subject><issn>0013-936X</issn><issn>1520-5851</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>1982</creationdate><recordtype>article</recordtype><recordid>eNpt0c2KFDEUBeAgCrajK18guNCF1JifSv0spXXakQYFRxA3IZ3cmspYSWqSFHTPI_jUZqhBXLi6m48D9xyEXlJyTgmj7yARQnqhCGWP0IYKRirRCfoYbQihvOp58-MpepbSTWGMk26Dfm-Dm5cMEbtgYLL-Gqe8mBMOA57HkIMewVmtJhzuggc8hOhUtsFj63EeAc8xzOCh8jbHcA0eh6M1kCoTT1jZiNMpZXDneFdQVJO9A4OdOlq3uIdIm8I8QR6foyeDmhK8eLhn6PvFx6vtp2r_ZXe5fb-vVN3QXEFnGlb36iCgHzQTqhbc1IqatjWGHmpSDx03ZNCmb6nqe6PZQHRj9IEZ3rWGn6FXa25I2cqkbQY96uA96CyF6KggTUGvV1T-u10gZels0jBNykNYkmSc123dkwLfrlDHkFKEQc7ROhVPkhJ5P4r8Z5Siq1Xb0srxL1Xxl2xa3gp59fWb_Ez3zYeLHZU_i3-zeqWTvAlL9KWZ_yb_AXxinsQ</recordid><startdate>19820101</startdate><enddate>19820101</enddate><creator>Sakamaki, Fumio</creator><creator>Okuda, Michio</creator><creator>Akimoto, Hajime</creator><creator>Yamazaki, Hideo</creator><general>American Chemical Society</general><scope>BSCLL</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>8FD</scope><scope>H8D</scope><scope>L7M</scope><scope>OTOTI</scope></search><sort><creationdate>19820101</creationdate><title>Computer modeling study of photochemical ozone formation in the propene-nitrogen oxides-dry air system. Generalized maximum ozone isopleth</title><author>Sakamaki, Fumio ; Okuda, Michio ; Akimoto, Hajime ; Yamazaki, Hideo</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-a461t-e8d6249ab5e9fc25a453d4a1d77dd1b404f83d0fcd971a99dc2f0c6dcb2d387d3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>1982</creationdate><topic>500200 - Environment, Atmospheric- Chemicals Monitoring & Transport- (-1989)</topic><topic>ALKENES</topic><topic>CHALCOGENIDES</topic><topic>CHEMICAL REACTIONS</topic><topic>COMPUTERIZED SIMULATION</topic><topic>ELEMENTS</topic><topic>ENVIRONMENTAL SCIENCES</topic><topic>HYDROCARBONS</topic><topic>MATHEMATICAL MODELS</topic><topic>NITROGEN</topic><topic>NITROGEN COMPOUNDS</topic><topic>NITROGEN OXIDES</topic><topic>NONMETALS</topic><topic>ORGANIC COMPOUNDS</topic><topic>OXIDES</topic><topic>OXYGEN COMPOUNDS</topic><topic>OZONE</topic><topic>PHOTOCHEMICAL REACTIONS</topic><topic>PROPYLENE</topic><topic>SIMULATION</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Sakamaki, Fumio</creatorcontrib><creatorcontrib>Okuda, Michio</creatorcontrib><creatorcontrib>Akimoto, Hajime</creatorcontrib><creatorcontrib>Yamazaki, Hideo</creatorcontrib><collection>Istex</collection><collection>CrossRef</collection><collection>Technology Research Database</collection><collection>Aerospace Database</collection><collection>Advanced Technologies Database with Aerospace</collection><collection>OSTI.GOV</collection><jtitle>Environ. Sci. Technol.; (United States)</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Sakamaki, Fumio</au><au>Okuda, Michio</au><au>Akimoto, Hajime</au><au>Yamazaki, Hideo</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Computer modeling study of photochemical ozone formation in the propene-nitrogen oxides-dry air system. Generalized maximum ozone isopleth</atitle><jtitle>Environ. Sci. Technol.; (United States)</jtitle><addtitle>Environ. Sci. Technol</addtitle><date>1982-01-01</date><risdate>1982</risdate><volume>16</volume><issue>1</issue><spage>45</spage><epage>52</epage><pages>45-52</pages><issn>0013-936X</issn><eissn>1520-5851</eissn><abstract>Computer simulation for the propene-nitrogen oxides-dry air system was performed by using a detailed reaction model in order to represent previous experimental results. The proportional relationships between (0/sub 3/)/sub max/ and (0/sub 3/)/sub ps/, (NO/sub x/)/sub 0//sup 1///sup 2/, and K/sub 1//sup 1///sup 2/ were sucessfully reproduced by the model. Based on the calculated data, the plot of (0/sub 3/)/sub max//(0/sub 3/)/sub ps/ vs. (C/sub 3/H/sub 6/)/sub 0//(NO/sub x/)/sub 0/ was found to fall on a single common curve, which is called a generalized maximum ozone isopleth. In the falloff region of the above plot, an approximate linear relationship between (0/sub 3/)/sub max//(0/sub 3/)/sub ps/ and ((C/sub 3/H/sub 6/)/sub 0//(NO/sub x/)/sub 0/)/sup 1///sup 2/ was obtained, implying that (0/sub 3/)/sub max/ is linear with (C/sub 3/H/sub 6/)/sub 0//sup 1///sup 2/ in the NO/sub x/-excess region.</abstract><cop>United States</cop><pub>American Chemical Society</pub><doi>10.1021/es00095a012</doi><tpages>8</tpages></addata></record> |
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| source | American Chemical Society Journals |
| subjects | 500200 - Environment, Atmospheric- Chemicals Monitoring & Transport- (-1989) ALKENES CHALCOGENIDES CHEMICAL REACTIONS COMPUTERIZED SIMULATION ELEMENTS ENVIRONMENTAL SCIENCES HYDROCARBONS MATHEMATICAL MODELS NITROGEN NITROGEN COMPOUNDS NITROGEN OXIDES NONMETALS ORGANIC COMPOUNDS OXIDES OXYGEN COMPOUNDS OZONE PHOTOCHEMICAL REACTIONS PROPYLENE SIMULATION |
| title | Computer modeling study of photochemical ozone formation in the propene-nitrogen oxides-dry air system. Generalized maximum ozone isopleth |
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