Transparent Electrothermal Film Defoggers and Antiicing Coatings based on Wrinkled Graphene

Fog, frost, ice, and other natural phenomena can inevitably affect human life and the function of equipment. Therefore, removal or prevention is an urgent problem to be solved. As a new type of 2D material, graphene possesses great application potential in defogging and antiicing. In this work, a graphene film with intentionally increased defects and uniformly distributed wrinkles is synthesized on copper–zinc alloy substrates by chemical vapor deposition, and transparent electrothermal film defoggers are prepared based on such material. The defoggers can completely remove fog within 5 s when supplying a safe voltage of 28 V. The surface resistance of the defoggers is sensitive to humidity and it can monitor the defogging process in real time. Such outstanding performance is attributed to the ultrafast evaporation mechanism, which can prevent excessive water accumulation. The antiicing performance of wrinkled graphene (WG) is further studied. The antiicing coatings can delay freezing for 1.25 h at −15 °C or 2.8 h at −10 °C. The superior performance of WG can be explained by its unique surface structure and nanoscale roughness. Taken together, WG is expected to be used in antifog glass, rearview mirror defogging, aircraft surface deicing, and other applications. Transparent electrothermal defoggers and antiicing coatings based on wrinkled graphene (WG) are prepared. WG can prevent water droplets from gathering on the surface, promote water evaporation, further effectively delay the freezing of water droplets, and realize quick defrosting.