Multielemental single–atom-thick A layers in nanolaminated V₂(Sn, A) C (A = Fe, Co, Ni, Mn) for tailoring magnetic properties
Tailoring of individual single–atom-thick layers in nanolaminated materials offers atomic-level control over material properties. Nonetheless, multielement alloying in individual atomic layers in nanolaminates is largely unexplored. Here, we report 15 inherently nanolaminated V₂(AₓSn1-x)C (A = Fe, C...
Gespeichert in:
| Veröffentlicht in: | Proceedings of the National Academy of Sciences - PNAS 2020-01, Vol.117 (2), p.820-825 |
|---|---|
| Hauptverfasser: | , , , , , , , , , , , , , , |
| Format: | Artikel |
| Sprache: | eng |
| Schlagworte: | |
| Online-Zugang: | Volltext |
| Tags: |
Tag hinzufügen
Keine Tags, Fügen Sie den ersten Tag hinzu!
|
| container_end_page | 825 |
|---|---|
| container_issue | 2 |
| container_start_page | 820 |
| container_title | Proceedings of the National Academy of Sciences - PNAS |
| container_volume | 117 |
| creator | Li, Youbing Lu, Jun Li, Mian Chang, Keke Zha, Xianhu Zhang, Yiming Chen, Ke Persson, Per O. Å. Hultman, Lars Eklund, Per Du, Shiyu Francisco, Joseph S. Chai, Zhifang Huang, Zhengren Huang, Qing |
| description | Tailoring of individual single–atom-thick layers in nanolaminated materials offers atomic-level control over material properties. Nonetheless, multielement alloying in individual atomic layers in nanolaminates is largely unexplored. Here, we report 15 inherently nanolaminated V₂(AₓSn1-x)C (A = Fe, Co, Ni, Mn, and combinations thereof, with x ∼ 1/3) MAX phases synthesized by an alloy-guided reaction. The simultaneous occupancy of the 4 magnetic elements and Sn in the individual single–atom-thick A layers constitutes high-entropy MAX phase in which multielemental alloying exclusively occurs in the 2-dimensional (2D) A layers. V₂(AₓSn1-x)C exhibit distinct ferromagnetic behavior that can be compositionally tailored from the multielement A-layer alloying. Density functional theory and phase diagram calculations are performed to understand the structure stability of these MAX phases. This 2D multielemental alloying approach provides a structural design route to discover nanolaminated materials and expand their chemical and physical properties. In fact, the magnetic behavior of these multielemental MAX phases shows strong dependency on the combination of various elements. |
| doi_str_mv | 10.1073/pnas.1916256117 |
| format | Article |
| fullrecord | <record><control><sourceid>jstor_swepu</sourceid><recordid>TN_cdi_proquest_miscellaneous_2331257174</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><jstor_id>26896948</jstor_id><sourcerecordid>26896948</sourcerecordid><originalsourceid>FETCH-LOGICAL-j331t-3ea773e6cbd9298e0bb6287dc389a539df8942dcaecd1662e4165397c6c3283c3</originalsourceid><addsrcrecordid>eNpdkM9uEzEQxi0EoqFw5oRkiUsqZYv_xV4fQFqlFJBaOAC9Wo7XSR289mJ7Qb2VvgJv2CfBKBVSOY0085vv-2YAeI7RMUaCvhqDzsdYYk6WHGPxAMwwkrjhTKKHYIYQEU3LCDsAT3LeIYTkskWPwQHFrZCU4Rn4dT754qy3gw1Fe5hd2Hp7e_1blzg05dKZb7CDXl_ZlKELMOgQvR5c0MX28OL25mb-OSxgdwRXcN7B1_DULuAqLuBHt4Dn4QhuYoJFOx9TVYaD3gZbnIFjiqNN1Tk_BY822mf77K4egq-nb7-s3jdnn959WHVnzY5SXBpqtRDUcrPuJZGtRes1J63oDW2lXlLZb1rJSG-0NT3mnFiGeW0Lww0lLTX0EDR73fzTjtNajckNOl2pqJ06cRedimmrvJsU5pSxtvJv9nyFB9ub-p-k_b21-5PgLtU2_lBccrlksgrM7wRS_D7ZXNTgsrHe62DjlBWpd5GlwIJV9OV_6C5OKdR3VIpRjJjAf6kXe2qXS0z_khDeVsea-A-Bt6Ks</addsrcrecordid><sourcetype>Open Access Repository</sourcetype><iscdi>true</iscdi><recordtype>article</recordtype><pqid>2343104714</pqid></control><display><type>article</type><title>Multielemental single–atom-thick A layers in nanolaminated V₂(Sn, A) C (A = Fe, Co, Ni, Mn) for tailoring magnetic properties</title><source>Jstor Complete Legacy</source><source>PubMed Central</source><source>Alma/SFX Local Collection</source><source>SWEPUB Freely available online</source><source>Free Full-Text Journals in Chemistry</source><creator>Li, Youbing ; Lu, Jun ; Li, Mian ; Chang, Keke ; Zha, Xianhu ; Zhang, Yiming ; Chen, Ke ; Persson, Per O. Å. ; Hultman, Lars ; Eklund, Per ; Du, Shiyu ; Francisco, Joseph S. ; Chai, Zhifang ; Huang, Zhengren ; Huang, Qing</creator><creatorcontrib>Li, Youbing ; Lu, Jun ; Li, Mian ; Chang, Keke ; Zha, Xianhu ; Zhang, Yiming ; Chen, Ke ; Persson, Per O. Å. ; Hultman, Lars ; Eklund, Per ; Du, Shiyu ; Francisco, Joseph S. ; Chai, Zhifang ; Huang, Zhengren ; Huang, Qing</creatorcontrib><description>Tailoring of individual single–atom-thick layers in nanolaminated materials offers atomic-level control over material properties. Nonetheless, multielement alloying in individual atomic layers in nanolaminates is largely unexplored. Here, we report 15 inherently nanolaminated V₂(AₓSn1-x)C (A = Fe, Co, Ni, Mn, and combinations thereof, with x ∼ 1/3) MAX phases synthesized by an alloy-guided reaction. The simultaneous occupancy of the 4 magnetic elements and Sn in the individual single–atom-thick A layers constitutes high-entropy MAX phase in which multielemental alloying exclusively occurs in the 2-dimensional (2D) A layers. V₂(AₓSn1-x)C exhibit distinct ferromagnetic behavior that can be compositionally tailored from the multielement A-layer alloying. Density functional theory and phase diagram calculations are performed to understand the structure stability of these MAX phases. This 2D multielemental alloying approach provides a structural design route to discover nanolaminated materials and expand their chemical and physical properties. In fact, the magnetic behavior of these multielemental MAX phases shows strong dependency on the combination of various elements.</description><identifier>ISSN: 0027-8424</identifier><identifier>ISSN: 1091-6490</identifier><identifier>EISSN: 1091-6490</identifier><identifier>DOI: 10.1073/pnas.1916256117</identifier><identifier>PMID: 31879341</identifier><language>eng</language><publisher>Washington: National Academy of Sciences</publisher><subject>Alloying ; Cobalt ; Density functional theory ; Entropy ; Ferromagnetism ; Iron ; Magnetic properties ; Manganese ; Material properties ; Nickel ; Occupancy ; Organic chemistry ; Phase diagrams ; Phases ; Physical properties ; Physical Sciences ; Structural design ; Structural engineering</subject><ispartof>Proceedings of the National Academy of Sciences - PNAS, 2020-01, Vol.117 (2), p.820-825</ispartof><rights>Copyright National Academy of Sciences Jan 14, 2020</rights><rights>2020</rights><lds50>peer_reviewed</lds50><oa>free_for_read</oa><woscitedreferencessubscribed>false</woscitedreferencessubscribed></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://www.jstor.org/stable/pdf/26896948$$EPDF$$P50$$Gjstor$$H</linktopdf><linktohtml>$$Uhttps://www.jstor.org/stable/26896948$$EHTML$$P50$$Gjstor$$H</linktohtml><link.rule.ids>230,314,550,723,776,780,799,881,27901,27902,53766,53768,57992,58225</link.rule.ids><backlink>$$Uhttps://urn.kb.se/resolve?urn=urn:nbn:se:liu:diva-163448$$DView record from Swedish Publication Index$$Hfree_for_read</backlink></links><search><creatorcontrib>Li, Youbing</creatorcontrib><creatorcontrib>Lu, Jun</creatorcontrib><creatorcontrib>Li, Mian</creatorcontrib><creatorcontrib>Chang, Keke</creatorcontrib><creatorcontrib>Zha, Xianhu</creatorcontrib><creatorcontrib>Zhang, Yiming</creatorcontrib><creatorcontrib>Chen, Ke</creatorcontrib><creatorcontrib>Persson, Per O. Å.</creatorcontrib><creatorcontrib>Hultman, Lars</creatorcontrib><creatorcontrib>Eklund, Per</creatorcontrib><creatorcontrib>Du, Shiyu</creatorcontrib><creatorcontrib>Francisco, Joseph S.</creatorcontrib><creatorcontrib>Chai, Zhifang</creatorcontrib><creatorcontrib>Huang, Zhengren</creatorcontrib><creatorcontrib>Huang, Qing</creatorcontrib><title>Multielemental single–atom-thick A layers in nanolaminated V₂(Sn, A) C (A = Fe, Co, Ni, Mn) for tailoring magnetic properties</title><title>Proceedings of the National Academy of Sciences - PNAS</title><description>Tailoring of individual single–atom-thick layers in nanolaminated materials offers atomic-level control over material properties. Nonetheless, multielement alloying in individual atomic layers in nanolaminates is largely unexplored. Here, we report 15 inherently nanolaminated V₂(AₓSn1-x)C (A = Fe, Co, Ni, Mn, and combinations thereof, with x ∼ 1/3) MAX phases synthesized by an alloy-guided reaction. The simultaneous occupancy of the 4 magnetic elements and Sn in the individual single–atom-thick A layers constitutes high-entropy MAX phase in which multielemental alloying exclusively occurs in the 2-dimensional (2D) A layers. V₂(AₓSn1-x)C exhibit distinct ferromagnetic behavior that can be compositionally tailored from the multielement A-layer alloying. Density functional theory and phase diagram calculations are performed to understand the structure stability of these MAX phases. This 2D multielemental alloying approach provides a structural design route to discover nanolaminated materials and expand their chemical and physical properties. In fact, the magnetic behavior of these multielemental MAX phases shows strong dependency on the combination of various elements.</description><subject>Alloying</subject><subject>Cobalt</subject><subject>Density functional theory</subject><subject>Entropy</subject><subject>Ferromagnetism</subject><subject>Iron</subject><subject>Magnetic properties</subject><subject>Manganese</subject><subject>Material properties</subject><subject>Nickel</subject><subject>Occupancy</subject><subject>Organic chemistry</subject><subject>Phase diagrams</subject><subject>Phases</subject><subject>Physical properties</subject><subject>Physical Sciences</subject><subject>Structural design</subject><subject>Structural engineering</subject><issn>0027-8424</issn><issn>1091-6490</issn><issn>1091-6490</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2020</creationdate><recordtype>article</recordtype><sourceid>D8T</sourceid><recordid>eNpdkM9uEzEQxi0EoqFw5oRkiUsqZYv_xV4fQFqlFJBaOAC9Wo7XSR289mJ7Qb2VvgJv2CfBKBVSOY0085vv-2YAeI7RMUaCvhqDzsdYYk6WHGPxAMwwkrjhTKKHYIYQEU3LCDsAT3LeIYTkskWPwQHFrZCU4Rn4dT754qy3gw1Fe5hd2Hp7e_1blzg05dKZb7CDXl_ZlKELMOgQvR5c0MX28OL25mb-OSxgdwRXcN7B1_DULuAqLuBHt4Dn4QhuYoJFOx9TVYaD3gZbnIFjiqNN1Tk_BY822mf77K4egq-nb7-s3jdnn959WHVnzY5SXBpqtRDUcrPuJZGtRes1J63oDW2lXlLZb1rJSG-0NT3mnFiGeW0Lww0lLTX0EDR73fzTjtNajckNOl2pqJ06cRedimmrvJsU5pSxtvJv9nyFB9ub-p-k_b21-5PgLtU2_lBccrlksgrM7wRS_D7ZXNTgsrHe62DjlBWpd5GlwIJV9OV_6C5OKdR3VIpRjJjAf6kXe2qXS0z_khDeVsea-A-Bt6Ks</recordid><startdate>20200114</startdate><enddate>20200114</enddate><creator>Li, Youbing</creator><creator>Lu, Jun</creator><creator>Li, Mian</creator><creator>Chang, Keke</creator><creator>Zha, Xianhu</creator><creator>Zhang, Yiming</creator><creator>Chen, Ke</creator><creator>Persson, Per O. Å.</creator><creator>Hultman, Lars</creator><creator>Eklund, Per</creator><creator>Du, Shiyu</creator><creator>Francisco, Joseph S.</creator><creator>Chai, Zhifang</creator><creator>Huang, Zhengren</creator><creator>Huang, Qing</creator><general>National Academy of Sciences</general><scope>7QG</scope><scope>7QL</scope><scope>7QP</scope><scope>7QR</scope><scope>7SN</scope><scope>7SS</scope><scope>7T5</scope><scope>7TK</scope><scope>7TM</scope><scope>7TO</scope><scope>7U9</scope><scope>8FD</scope><scope>C1K</scope><scope>FR3</scope><scope>H94</scope><scope>M7N</scope><scope>P64</scope><scope>RC3</scope><scope>7X8</scope><scope>5PM</scope><scope>ABXSW</scope><scope>ADTPV</scope><scope>AOWAS</scope><scope>D8T</scope><scope>DG8</scope><scope>ZZAVC</scope></search><sort><creationdate>20200114</creationdate><title>Multielemental single–atom-thick A layers in nanolaminated V₂(Sn, A) C (A = Fe, Co, Ni, Mn) for tailoring magnetic properties</title><author>Li, Youbing ; Lu, Jun ; Li, Mian ; Chang, Keke ; Zha, Xianhu ; Zhang, Yiming ; Chen, Ke ; Persson, Per O. Å. ; Hultman, Lars ; Eklund, Per ; Du, Shiyu ; Francisco, Joseph S. ; Chai, Zhifang ; Huang, Zhengren ; Huang, Qing</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-j331t-3ea773e6cbd9298e0bb6287dc389a539df8942dcaecd1662e4165397c6c3283c3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2020</creationdate><topic>Alloying</topic><topic>Cobalt</topic><topic>Density functional theory</topic><topic>Entropy</topic><topic>Ferromagnetism</topic><topic>Iron</topic><topic>Magnetic properties</topic><topic>Manganese</topic><topic>Material properties</topic><topic>Nickel</topic><topic>Occupancy</topic><topic>Organic chemistry</topic><topic>Phase diagrams</topic><topic>Phases</topic><topic>Physical properties</topic><topic>Physical Sciences</topic><topic>Structural design</topic><topic>Structural engineering</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Li, Youbing</creatorcontrib><creatorcontrib>Lu, Jun</creatorcontrib><creatorcontrib>Li, Mian</creatorcontrib><creatorcontrib>Chang, Keke</creatorcontrib><creatorcontrib>Zha, Xianhu</creatorcontrib><creatorcontrib>Zhang, Yiming</creatorcontrib><creatorcontrib>Chen, Ke</creatorcontrib><creatorcontrib>Persson, Per O. Å.</creatorcontrib><creatorcontrib>Hultman, Lars</creatorcontrib><creatorcontrib>Eklund, Per</creatorcontrib><creatorcontrib>Du, Shiyu</creatorcontrib><creatorcontrib>Francisco, Joseph S.</creatorcontrib><creatorcontrib>Chai, Zhifang</creatorcontrib><creatorcontrib>Huang, Zhengren</creatorcontrib><creatorcontrib>Huang, Qing</creatorcontrib><collection>Animal Behavior Abstracts</collection><collection>Bacteriology Abstracts (Microbiology B)</collection><collection>Calcium & Calcified Tissue Abstracts</collection><collection>Chemoreception Abstracts</collection><collection>Ecology Abstracts</collection><collection>Entomology Abstracts (Full archive)</collection><collection>Immunology Abstracts</collection><collection>Neurosciences Abstracts</collection><collection>Nucleic Acids Abstracts</collection><collection>Oncogenes and Growth Factors Abstracts</collection><collection>Virology and AIDS Abstracts</collection><collection>Technology Research Database</collection><collection>Environmental Sciences and Pollution Management</collection><collection>Engineering Research Database</collection><collection>AIDS and Cancer Research Abstracts</collection><collection>Algology Mycology and Protozoology Abstracts (Microbiology C)</collection><collection>Biotechnology and BioEngineering Abstracts</collection><collection>Genetics Abstracts</collection><collection>MEDLINE - Academic</collection><collection>PubMed Central (Full Participant titles)</collection><collection>SWEPUB Linköpings universitet full text</collection><collection>SwePub</collection><collection>SwePub Articles</collection><collection>SWEPUB Freely available online</collection><collection>SWEPUB Linköpings universitet</collection><collection>SwePub Articles full text</collection><jtitle>Proceedings of the National Academy of Sciences - PNAS</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Li, Youbing</au><au>Lu, Jun</au><au>Li, Mian</au><au>Chang, Keke</au><au>Zha, Xianhu</au><au>Zhang, Yiming</au><au>Chen, Ke</au><au>Persson, Per O. Å.</au><au>Hultman, Lars</au><au>Eklund, Per</au><au>Du, Shiyu</au><au>Francisco, Joseph S.</au><au>Chai, Zhifang</au><au>Huang, Zhengren</au><au>Huang, Qing</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Multielemental single–atom-thick A layers in nanolaminated V₂(Sn, A) C (A = Fe, Co, Ni, Mn) for tailoring magnetic properties</atitle><jtitle>Proceedings of the National Academy of Sciences - PNAS</jtitle><date>2020-01-14</date><risdate>2020</risdate><volume>117</volume><issue>2</issue><spage>820</spage><epage>825</epage><pages>820-825</pages><issn>0027-8424</issn><issn>1091-6490</issn><eissn>1091-6490</eissn><abstract>Tailoring of individual single–atom-thick layers in nanolaminated materials offers atomic-level control over material properties. Nonetheless, multielement alloying in individual atomic layers in nanolaminates is largely unexplored. Here, we report 15 inherently nanolaminated V₂(AₓSn1-x)C (A = Fe, Co, Ni, Mn, and combinations thereof, with x ∼ 1/3) MAX phases synthesized by an alloy-guided reaction. The simultaneous occupancy of the 4 magnetic elements and Sn in the individual single–atom-thick A layers constitutes high-entropy MAX phase in which multielemental alloying exclusively occurs in the 2-dimensional (2D) A layers. V₂(AₓSn1-x)C exhibit distinct ferromagnetic behavior that can be compositionally tailored from the multielement A-layer alloying. Density functional theory and phase diagram calculations are performed to understand the structure stability of these MAX phases. This 2D multielemental alloying approach provides a structural design route to discover nanolaminated materials and expand their chemical and physical properties. In fact, the magnetic behavior of these multielemental MAX phases shows strong dependency on the combination of various elements.</abstract><cop>Washington</cop><pub>National Academy of Sciences</pub><pmid>31879341</pmid><doi>10.1073/pnas.1916256117</doi><tpages>6</tpages><oa>free_for_read</oa></addata></record> |
| fulltext | fulltext |
| identifier | ISSN: 0027-8424 |
| ispartof | Proceedings of the National Academy of Sciences - PNAS, 2020-01, Vol.117 (2), p.820-825 |
| issn | 0027-8424 1091-6490 1091-6490 |
| language | eng |
| recordid | cdi_proquest_miscellaneous_2331257174 |
| source | Jstor Complete Legacy; PubMed Central; Alma/SFX Local Collection; SWEPUB Freely available online; Free Full-Text Journals in Chemistry |
| subjects | Alloying Cobalt Density functional theory Entropy Ferromagnetism Iron Magnetic properties Manganese Material properties Nickel Occupancy Organic chemistry Phase diagrams Phases Physical properties Physical Sciences Structural design Structural engineering |
| title | Multielemental single–atom-thick A layers in nanolaminated V₂(Sn, A) C (A = Fe, Co, Ni, Mn) for tailoring magnetic properties |
| url | https://sfx.bib-bvb.de/sfx_tum?ctx_ver=Z39.88-2004&ctx_enc=info:ofi/enc:UTF-8&ctx_tim=2025-02-20T16%3A32%3A31IST&url_ver=Z39.88-2004&url_ctx_fmt=infofi/fmt:kev:mtx:ctx&rfr_id=info:sid/primo.exlibrisgroup.com:primo3-Article-jstor_swepu&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.genre=article&rft.atitle=Multielemental%20single%E2%80%93atom-thick%20A%20layers%20in%20nanolaminated%20V%E2%82%82(Sn,%20A)%20C%20(A%20=%20Fe,%20Co,%20Ni,%20Mn)%20for%20tailoring%20magnetic%20properties&rft.jtitle=Proceedings%20of%20the%20National%20Academy%20of%20Sciences%20-%20PNAS&rft.au=Li,%20Youbing&rft.date=2020-01-14&rft.volume=117&rft.issue=2&rft.spage=820&rft.epage=825&rft.pages=820-825&rft.issn=0027-8424&rft.eissn=1091-6490&rft_id=info:doi/10.1073/pnas.1916256117&rft_dat=%3Cjstor_swepu%3E26896948%3C/jstor_swepu%3E%3Curl%3E%3C/url%3E&disable_directlink=true&sfx.directlink=off&sfx.report_link=0&rft_id=info:oai/&rft_pqid=2343104714&rft_id=info:pmid/31879341&rft_jstor_id=26896948&rfr_iscdi=true |