Hydrosilylation of an Iron(IV) Nitride Complex

Hydrosilylation of an Iron(IV) Nitride Complex

The nitride ligand in iron­(IV) complex PhB­(MesIm)3FeN reacts with excess H3SiPh to afford PhB­(MesIm)3Fe­(μ-H)3(SiHPh) as the major product, which has been structurally and spectroscopically characterized. Bulkier silane HaSiPh2 provides iron­(II) amido complex PhB­(MesIm)3FeN­(H)­(SiHPh2) as the...

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Veröffentlicht in:Inorganic chemistry 2020-01, Vol.59 (1), p.579-583
Hauptverfasser: Valdez-Moreira, Juan A, Millikan, Sean P, Gao, Xinfeng, Carta, Veronica, Chen, Chun-Hsing, Smith, Jeremy M
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container_end_page 583
container_issue 1
container_start_page 579
container_title Inorganic chemistry
container_volume 59
creator Valdez-Moreira, Juan A
Millikan, Sean P
Gao, Xinfeng
Carta, Veronica
Chen, Chun-Hsing
Smith, Jeremy M
description The nitride ligand in iron­(IV) complex PhB­(MesIm)3FeN reacts with excess H3SiPh to afford PhB­(MesIm)3Fe­(μ-H)3(SiHPh) as the major product, which has been structurally and spectroscopically characterized. Bulkier silane HaSiPh2 provides iron­(II) amido complex PhB­(MesIm)3FeN­(H)­(SiHPh2) as the initial product of the reaction, with excess H2SiPh2 affording diamagnetic PhB­(MesIm)3Fe­(μ-H)3(SiPh2) as the major product. Unobserved iron­(II) hydride PhB­(MesIm)3Fe–H is implicated as an intermediate in this reaction, as suggested by the results of the reaction between iron­(II) amido PhB­(MesIm)3FeN­(H)tBu and H3SiPh, which provides PhB­(MesIm)3Fe­(H)­(μ-H)2(Si­(NHtBu)­Ph) as the sole product.
doi_str_mv 10.1021/acs.inorgchem.9b02831
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