Synthesis of Blue-Luminescent Seven-Membered Phosphorus Heterocycles

Synthesis of Blue-Luminescent Seven-Membered Phosphorus Heterocycles

A facile synthetic procedure to prepare π-extended seven-membered phosphorus heterocycles, both symmetric and asymmetric, is reported. The prepared molecules present a persistent nonplanar framework and are soluble in a wide variety of solvents. The seven-membered phosphorus heterocycles can be elec...

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Veröffentlicht in:Journal of organic chemistry 2020-01, Vol.85 (2), p.1247-1252
Hauptverfasser: Regulska, Elzbieta, Ruppert, Heiko, Rominger, Frank, Romero-Nieto, Carlos
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container_title Journal of organic chemistry
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creator Regulska, Elzbieta
Ruppert, Heiko
Rominger, Frank
Romero-Nieto, Carlos
description A facile synthetic procedure to prepare π-extended seven-membered phosphorus heterocycles, both symmetric and asymmetric, is reported. The prepared molecules present a persistent nonplanar framework and are soluble in a wide variety of solvents. The seven-membered phosphorus heterocycles can be electrochemically reduced and oxidized, and photoluminesce with a blue color.
doi_str_mv 10.1021/acs.joc.9b02723
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title Synthesis of Blue-Luminescent Seven-Membered Phosphorus Heterocycles
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