A unified structural approach to linear carbon polytypes
Compounds obtained by high-temperature treatment of graphite are thought to be linear carbon polytypes with sp-configuration and carbon–carbon chains, either conjugated triple bonded or cumulated double bonded, parallel to the c -axis. At least 10 crystallographically documented linear carbon forms...
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| Veröffentlicht in: | Nature (London) 1983-01, Vol.306 (5939), p.164-167 |
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| container_issue | 5939 |
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| container_title | Nature (London) |
| container_volume | 306 |
| creator | Heimann, R. B. Kleiman, J. Salansky, N. M. |
| description | Compounds obtained by high-temperature treatment of graphite are thought to be linear carbon polytypes with sp-configuration and carbon–carbon chains, either conjugated triple bonded or cumulated double bonded, parallel to the
c
-axis. At least 10 crystallographically documented linear carbon forms (carbynes) have been reported. To relate the contradictory and confusing information found in the literature, a simple classification is suggested here based on a linear relationship between number of atoms in a chain (
n
) and the unit cell parameters
a
0
and
c
0
of all carbyne forms known. It is assumed that chains are kinked, and that the distribution of kinked spacings may be a function of the temperature of formation of the carbyne forms in question. |
| doi_str_mv | 10.1038/306164a0 |
| format | Article |
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c
-axis. At least 10 crystallographically documented linear carbon forms (carbynes) have been reported. To relate the contradictory and confusing information found in the literature, a simple classification is suggested here based on a linear relationship between number of atoms in a chain (
n
) and the unit cell parameters
a
0
and
c
0
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c
-axis. At least 10 crystallographically documented linear carbon forms (carbynes) have been reported. To relate the contradictory and confusing information found in the literature, a simple classification is suggested here based on a linear relationship between number of atoms in a chain (
n
) and the unit cell parameters
a
0
and
c
0
of all carbyne forms known. It is assumed that chains are kinked, and that the distribution of kinked spacings may be a function of the temperature of formation of the carbyne forms in question.</description><subject>Condensed matter: structure, mechanical and thermal properties</subject><subject>Crystalline state (including molecular motions in solids)</subject><subject>Crystallographic aspects of phase transformations; pressure effects</subject><subject>Exact sciences and technology</subject><subject>Humanities and Social Sciences</subject><subject>letter</subject><subject>multidisciplinary</subject><subject>Physics</subject><subject>Science</subject><subject>Science (multidisciplinary)</subject><subject>Structure of solids and liquids; crystallography</subject><issn>0028-0836</issn><issn>1476-4687</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>1983</creationdate><recordtype>article</recordtype><recordid>eNqN0DtPwzAUhmELgUQpSPyEDAjBEDiOL3HGquImVWKB2Tp2HEiV2sFOhv57UrWwsDB58KNXRx8hlxTuKDB1z0BSyRGOyIzyUuZcqvKYzAAKlYNi8pScpbQGAEFLPiNqkY2-bVpXZ2mIox3GiF2GfR8D2s9sCFnXeocxsxhN8Fkfuu2w7V06JycNdsldHN45eX98eFs-56vXp5flYpVbTuWQC1eBAOBUqKKqSgYgFUpQyjEGxtRKGMMLV1tRl8Y0lqNQ0nAjqGWItWNzcr3vThd9jS4NetMm67oOvQtj0gUrphzn_4GiEtUO3uyhjSGl6Brdx3aDcasp6N2G-mfDiV4dmpgsdk1Eb9v06yspSsHYxG73LE0__sNFvQ5j9NMsf5PfDqt8fg</recordid><startdate>19830101</startdate><enddate>19830101</enddate><creator>Heimann, R. B.</creator><creator>Kleiman, J.</creator><creator>Salansky, N. M.</creator><general>Nature Publishing Group UK</general><general>Nature Publishing</general><scope>IQODW</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>7U5</scope><scope>8FD</scope><scope>L7M</scope><scope>H8D</scope></search><sort><creationdate>19830101</creationdate><title>A unified structural approach to linear carbon polytypes</title><author>Heimann, R. B. ; Kleiman, J. ; Salansky, N. M.</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c416t-5e905004158299730068a6088e330bbd85bb42edc5d7bbfc4a586b4b51c3aade3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>1983</creationdate><topic>Condensed matter: structure, mechanical and thermal properties</topic><topic>Crystalline state (including molecular motions in solids)</topic><topic>Crystallographic aspects of phase transformations; pressure effects</topic><topic>Exact sciences and technology</topic><topic>Humanities and Social Sciences</topic><topic>letter</topic><topic>multidisciplinary</topic><topic>Physics</topic><topic>Science</topic><topic>Science (multidisciplinary)</topic><topic>Structure of solids and liquids; crystallography</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Heimann, R. B.</creatorcontrib><creatorcontrib>Kleiman, J.</creatorcontrib><creatorcontrib>Salansky, N. M.</creatorcontrib><collection>Pascal-Francis</collection><collection>CrossRef</collection><collection>Solid State and Superconductivity Abstracts</collection><collection>Technology Research Database</collection><collection>Advanced Technologies Database with Aerospace</collection><collection>Aerospace Database</collection><jtitle>Nature (London)</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Heimann, R. B.</au><au>Kleiman, J.</au><au>Salansky, N. M.</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>A unified structural approach to linear carbon polytypes</atitle><jtitle>Nature (London)</jtitle><stitle>Nature</stitle><date>1983-01-01</date><risdate>1983</risdate><volume>306</volume><issue>5939</issue><spage>164</spage><epage>167</epage><pages>164-167</pages><issn>0028-0836</issn><eissn>1476-4687</eissn><coden>NATUAS</coden><abstract>Compounds obtained by high-temperature treatment of graphite are thought to be linear carbon polytypes with sp-configuration and carbon–carbon chains, either conjugated triple bonded or cumulated double bonded, parallel to the
c
-axis. At least 10 crystallographically documented linear carbon forms (carbynes) have been reported. To relate the contradictory and confusing information found in the literature, a simple classification is suggested here based on a linear relationship between number of atoms in a chain (
n
) and the unit cell parameters
a
0
and
c
0
of all carbyne forms known. It is assumed that chains are kinked, and that the distribution of kinked spacings may be a function of the temperature of formation of the carbyne forms in question.</abstract><cop>London</cop><pub>Nature Publishing Group UK</pub><doi>10.1038/306164a0</doi><tpages>4</tpages></addata></record> |
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| ispartof | Nature (London), 1983-01, Vol.306 (5939), p.164-167 |
| issn | 0028-0836 1476-4687 |
| language | eng |
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| source | Nature_系列刊; Springer Online Journals |
| subjects | Condensed matter: structure, mechanical and thermal properties Crystalline state (including molecular motions in solids) Crystallographic aspects of phase transformations pressure effects Exact sciences and technology Humanities and Social Sciences letter multidisciplinary Physics Science Science (multidisciplinary) Structure of solids and liquids crystallography |
| title | A unified structural approach to linear carbon polytypes |
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