It's a Trap: Thiol‐Michael Chemistry on a DASA Photoswitch

Donor–acceptor Stenhouse adducts (DASA) are popular photoswitches capable of toggling between two isomers depending on the light and temperature of the system. The cyclized polar form is accessed by visible‐light irradiation, whereas the linear nonpolar form is recovered in the dark. Upon the format...

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Veröffentlicht in:	Chemistry : a European journal 2020-01, Vol.26 (4), p.809-813
Hauptverfasser:	Alves, Jessica, Wiedbrauk, Sandra, Gräfe, David, Walden, Sarah L., Blinco, James P., Barner‐Kowollik, Christopher
Format:	Artikel
Sprache:	eng
Schlagworte:	Adducts Chemistry donor–acceptor Stenhouse adducts Irradiation Isomers Light irradiation Michael reaction molecular switches Organic chemistry photogated reactivity Radiation selective reactions thiol-Michael addition
Online-Zugang:	Volltext
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