Nickel‐Catalyzed Electrochemical Reductive Relay Cross‐Coupling of Alkyl Halides to Aryl Halides
A highly regioselective Ni‐catalyzed electrochemical reductive relay cross‐coupling between an aryl halide and an alkyl halide has been developed in an undivided cell. Various functional groups are tolerated under these mild reaction conditions, which provides an alternative approach for the synthes...
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| Veröffentlicht in: | Angewandte Chemie International Edition 2020-04, Vol.59 (16), p.6520-6524 |
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| container_issue | 16 |
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| container_title | Angewandte Chemie International Edition |
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| creator | Jiao, Ke‐Jin Liu, Dong Ma, Hong‐Xing Qiu, Hui Fang, Ping Mei, Tian‐Sheng |
| description | A highly regioselective Ni‐catalyzed electrochemical reductive relay cross‐coupling between an aryl halide and an alkyl halide has been developed in an undivided cell. Various functional groups are tolerated under these mild reaction conditions, which provides an alternative approach for the synthesis of 1,1‐diarylalkanes.
Electrochemical reductive relay: A highly regioselective Ni‐catalyzed electrochemical reductive relay cross‐coupling between an aryl halide and an alkyl halide has been developed in an undivided cell. Various functional groups are tolerated under these mild reaction conditions, which provides an alternative approach for the synthesis of 1,1‐diarylalkanes. |
| doi_str_mv | 10.1002/anie.201912753 |
| format | Article |
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Electrochemical reductive relay: A highly regioselective Ni‐catalyzed electrochemical reductive relay cross‐coupling between an aryl halide and an alkyl halide has been developed in an undivided cell. Various functional groups are tolerated under these mild reaction conditions, which provides an alternative approach for the synthesis of 1,1‐diarylalkanes.</description><edition>International ed. in English</edition><identifier>ISSN: 1433-7851</identifier><identifier>EISSN: 1521-3773</identifier><identifier>DOI: 10.1002/anie.201912753</identifier><identifier>PMID: 31793156</identifier><language>eng</language><publisher>Germany: Wiley Subscription Services, Inc</publisher><subject>arenes ; Aromatic compounds ; Cross coupling ; Electrochemistry ; Functional groups ; Halides ; Nickel ; reaction mechanisms</subject><ispartof>Angewandte Chemie International Edition, 2020-04, Vol.59 (16), p.6520-6524</ispartof><rights>2019 Wiley‐VCH Verlag GmbH & Co. KGaA, Weinheim</rights><rights>2019 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim.</rights><rights>2020 Wiley‐VCH Verlag GmbH & Co. KGaA, Weinheim</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c4103-bef28eae24990d8103841cfebf9b42dcd6a8702d273474eecd89a85a27829e683</citedby><cites>FETCH-LOGICAL-c4103-bef28eae24990d8103841cfebf9b42dcd6a8702d273474eecd89a85a27829e683</cites><orcidid>0000-0002-4985-1071</orcidid></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://onlinelibrary.wiley.com/doi/pdf/10.1002%2Fanie.201912753$$EPDF$$P50$$Gwiley$$H</linktopdf><linktohtml>$$Uhttps://onlinelibrary.wiley.com/doi/full/10.1002%2Fanie.201912753$$EHTML$$P50$$Gwiley$$H</linktohtml><link.rule.ids>314,776,780,1411,27901,27902,45550,45551</link.rule.ids><backlink>$$Uhttps://www.ncbi.nlm.nih.gov/pubmed/31793156$$D View this record in MEDLINE/PubMed$$Hfree_for_read</backlink></links><search><creatorcontrib>Jiao, Ke‐Jin</creatorcontrib><creatorcontrib>Liu, Dong</creatorcontrib><creatorcontrib>Ma, Hong‐Xing</creatorcontrib><creatorcontrib>Qiu, Hui</creatorcontrib><creatorcontrib>Fang, Ping</creatorcontrib><creatorcontrib>Mei, Tian‐Sheng</creatorcontrib><title>Nickel‐Catalyzed Electrochemical Reductive Relay Cross‐Coupling of Alkyl Halides to Aryl Halides</title><title>Angewandte Chemie International Edition</title><addtitle>Angew Chem Int Ed Engl</addtitle><description>A highly regioselective Ni‐catalyzed electrochemical reductive relay cross‐coupling between an aryl halide and an alkyl halide has been developed in an undivided cell. Various functional groups are tolerated under these mild reaction conditions, which provides an alternative approach for the synthesis of 1,1‐diarylalkanes.
Electrochemical reductive relay: A highly regioselective Ni‐catalyzed electrochemical reductive relay cross‐coupling between an aryl halide and an alkyl halide has been developed in an undivided cell. Various functional groups are tolerated under these mild reaction conditions, which provides an alternative approach for the synthesis of 1,1‐diarylalkanes.</description><subject>arenes</subject><subject>Aromatic compounds</subject><subject>Cross coupling</subject><subject>Electrochemistry</subject><subject>Functional groups</subject><subject>Halides</subject><subject>Nickel</subject><subject>reaction mechanisms</subject><issn>1433-7851</issn><issn>1521-3773</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2020</creationdate><recordtype>article</recordtype><recordid>eNqFkM9Kw0AQxhdRrFavHiXgxUvq_kmym2Mp1RZKBdFz2O5OdNttU7OJEk8-gs_ok7ihtQUvnuab4TcfMx9CFwT3CMb0Rq4M9CgmKaE8ZgfohMSUhIxzduh1xFjIRUw66NS5ueeFwMkx6jDCU0bi5ATpqVELsN-fXwNZSdt8gA6GFlRVFuoFlkZJGzyArlVl3sArK5tgUBbOtRtFvbZm9RwUedC3i8YGI2mNBhdURdAv9_0ZOsqldXC-rV30dDt8HIzCyf3deNCfhCoimIUzyKkACTRKU6yFH4mIqBxmeTqLqFY6kYJjqilnEY8AlBapFLGkXNAUEsG66Hrjuy6L1xpclS2NU2CtXEFRu4wyigWPYsE8evUHnRd1ufLXeUokPMYCY0_1NpRqXy4hz9alWcqyyQjO2vyzNv9sl79fuNza1rMl6B3-G7gH0g3wbiw0_9hl_el4uDf_AYd7k1Y</recordid><startdate>20200416</startdate><enddate>20200416</enddate><creator>Jiao, Ke‐Jin</creator><creator>Liu, Dong</creator><creator>Ma, Hong‐Xing</creator><creator>Qiu, Hui</creator><creator>Fang, Ping</creator><creator>Mei, Tian‐Sheng</creator><general>Wiley Subscription Services, Inc</general><scope>NPM</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>7TM</scope><scope>K9.</scope><scope>7X8</scope><orcidid>https://orcid.org/0000-0002-4985-1071</orcidid></search><sort><creationdate>20200416</creationdate><title>Nickel‐Catalyzed Electrochemical Reductive Relay Cross‐Coupling of Alkyl Halides to Aryl Halides</title><author>Jiao, Ke‐Jin ; Liu, Dong ; Ma, Hong‐Xing ; Qiu, Hui ; Fang, Ping ; Mei, Tian‐Sheng</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c4103-bef28eae24990d8103841cfebf9b42dcd6a8702d273474eecd89a85a27829e683</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2020</creationdate><topic>arenes</topic><topic>Aromatic compounds</topic><topic>Cross coupling</topic><topic>Electrochemistry</topic><topic>Functional groups</topic><topic>Halides</topic><topic>Nickel</topic><topic>reaction mechanisms</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Jiao, Ke‐Jin</creatorcontrib><creatorcontrib>Liu, Dong</creatorcontrib><creatorcontrib>Ma, Hong‐Xing</creatorcontrib><creatorcontrib>Qiu, Hui</creatorcontrib><creatorcontrib>Fang, Ping</creatorcontrib><creatorcontrib>Mei, Tian‐Sheng</creatorcontrib><collection>PubMed</collection><collection>CrossRef</collection><collection>Nucleic Acids Abstracts</collection><collection>ProQuest Health & Medical Complete (Alumni)</collection><collection>MEDLINE - Academic</collection><jtitle>Angewandte Chemie International Edition</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Jiao, Ke‐Jin</au><au>Liu, Dong</au><au>Ma, Hong‐Xing</au><au>Qiu, Hui</au><au>Fang, Ping</au><au>Mei, Tian‐Sheng</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Nickel‐Catalyzed Electrochemical Reductive Relay Cross‐Coupling of Alkyl Halides to Aryl Halides</atitle><jtitle>Angewandte Chemie International Edition</jtitle><addtitle>Angew Chem Int Ed Engl</addtitle><date>2020-04-16</date><risdate>2020</risdate><volume>59</volume><issue>16</issue><spage>6520</spage><epage>6524</epage><pages>6520-6524</pages><issn>1433-7851</issn><eissn>1521-3773</eissn><abstract>A highly regioselective Ni‐catalyzed electrochemical reductive relay cross‐coupling between an aryl halide and an alkyl halide has been developed in an undivided cell. Various functional groups are tolerated under these mild reaction conditions, which provides an alternative approach for the synthesis of 1,1‐diarylalkanes.
Electrochemical reductive relay: A highly regioselective Ni‐catalyzed electrochemical reductive relay cross‐coupling between an aryl halide and an alkyl halide has been developed in an undivided cell. Various functional groups are tolerated under these mild reaction conditions, which provides an alternative approach for the synthesis of 1,1‐diarylalkanes.</abstract><cop>Germany</cop><pub>Wiley Subscription Services, Inc</pub><pmid>31793156</pmid><doi>10.1002/anie.201912753</doi><tpages>5</tpages><edition>International ed. in English</edition><orcidid>https://orcid.org/0000-0002-4985-1071</orcidid></addata></record> |
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| identifier | ISSN: 1433-7851 |
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| language | eng |
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| source | Wiley Online Library Journals Frontfile Complete |
| subjects | arenes Aromatic compounds Cross coupling Electrochemistry Functional groups Halides Nickel reaction mechanisms |
| title | Nickel‐Catalyzed Electrochemical Reductive Relay Cross‐Coupling of Alkyl Halides to Aryl Halides |
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