Utilization of gum xanthan based superporous hydrogels for the effective removal of methyl violet from aqueous solution

[Display omitted] •Superporous hydrogels of gum xanthan with AM and AA were synthesized using gas blowing technique.•Swelling kinetics followed first-order kinetics model.•SPH successfully removed methyl violet dye from the solution.•Adsorption kinetics followed pseudo-second-order rate equation.•Ad...

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Veröffentlicht in:International journal of biological macromolecules 2020-01, Vol.143, p.413-423
Hauptverfasser: Mittal, Hemant, Babu, Reshma, Alhassan, Saeed M.
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container_title International journal of biological macromolecules
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creator Mittal, Hemant
Babu, Reshma
Alhassan, Saeed M.
description [Display omitted] •Superporous hydrogels of gum xanthan with AM and AA were synthesized using gas blowing technique.•Swelling kinetics followed first-order kinetics model.•SPH successfully removed methyl violet dye from the solution.•Adsorption kinetics followed pseudo-second-order rate equation.•Adsorption isotherm followed monolayer Langmuir model with qm value of 287.54 mg·g−1. In this research work the superporous hydrogels (SPHs) of acrylic acid (AA) and acrylamide (AM) with gum xanthan (GX) were synthesized using glass blowing and foaming technique and tested the feasibility of synthesized SPHs to remove removal of methyl violet dye (MV) by the process of adsorption from aqueous solution. Swelling properties of synthesized SPHs with different concentrations of GX were studied in deionized water and the swelling kinetics followed first-order model. The adsorption of MV using SPHs was highly influenced by the solution pH. Adsorption kinetics followed non-linear pseudo-second-order rate equation, whereas, isotherm of adsorption followed monolayer Langmuir model. Diffusion mechanism of dye molecules was controlled by the combination of two mechanisms i.e. intraparticle and liquid film diffusion mechanisms. Furthermore, during desorption studies, SPHs were efficiently used for the five continuous adsorption-desorption cycles. Hence, the removal of cationic dyes could be done using SPHs of GX as effective adsorbents.
doi_str_mv 10.1016/j.ijbiomac.2019.11.008
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In this research work the superporous hydrogels (SPHs) of acrylic acid (AA) and acrylamide (AM) with gum xanthan (GX) were synthesized using glass blowing and foaming technique and tested the feasibility of synthesized SPHs to remove removal of methyl violet dye (MV) by the process of adsorption from aqueous solution. Swelling properties of synthesized SPHs with different concentrations of GX were studied in deionized water and the swelling kinetics followed first-order model. The adsorption of MV using SPHs was highly influenced by the solution pH. Adsorption kinetics followed non-linear pseudo-second-order rate equation, whereas, isotherm of adsorption followed monolayer Langmuir model. Diffusion mechanism of dye molecules was controlled by the combination of two mechanisms i.e. intraparticle and liquid film diffusion mechanisms. Furthermore, during desorption studies, SPHs were efficiently used for the five continuous adsorption-desorption cycles. Hence, the removal of cationic dyes could be done using SPHs of GX as effective adsorbents.</description><subject>Adsorption</subject><subject>Adsorption isotherm</subject><subject>Methyl violet</subject><subject>Superporous hydrogels</subject><subject>Swelling kinetics</subject><issn>0141-8130</issn><issn>1879-0003</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2020</creationdate><recordtype>article</recordtype><recordid>eNqFkMFu1DAQhi0EokvhFSofuSSM443jvYEqCkiVuNCz5djjrldOvNjOwvL0ONqWK6eRRt_8_-gj5IZBy4CJD4fWH0YfJ23aDtiuZawFkC_Ihslh1wAAf0k2wLaskYzDFXmT86FuRc_ka3LF2TBIsdtuyK-H4oP_o4uPM42OPi4T_a3nstczHXVGS_NyxHSMKS6Z7s82xUcMmbqYaNkjRefQFH9CmnCKJx3WkAnL_hzoyceAhboUJ6p_Lrgm5BiWtesteeV0yPjuaV6Th7vPP26_Nvffv3y7_XTfGC5kabTmYOxoBFo7StNxYAPXaF3fOye7bhSjxQGcGKXoDQ49Wm04gINtxbotvybvL7nHFOsLuajJZ4Mh6Hn9R3W8Az4MnewrKi6oSTHnhE4dk590OisGapWuDupZulqlK8ZUlV4Pb546lnFC--_s2XIFPl6Aag5PHpPKxuNs0PpU7Skb_f86_gJ5N5rJ</recordid><startdate>20200115</startdate><enddate>20200115</enddate><creator>Mittal, Hemant</creator><creator>Babu, Reshma</creator><creator>Alhassan, Saeed M.</creator><general>Elsevier B.V</general><scope>NPM</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>7X8</scope></search><sort><creationdate>20200115</creationdate><title>Utilization of gum xanthan based superporous hydrogels for the effective removal of methyl violet from aqueous solution</title><author>Mittal, Hemant ; Babu, Reshma ; Alhassan, Saeed M.</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c368t-aa30cdbc6eddb8c230173aedf55ff822b6bde70f6b865ce75edac300f043ae243</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2020</creationdate><topic>Adsorption</topic><topic>Adsorption isotherm</topic><topic>Methyl violet</topic><topic>Superporous hydrogels</topic><topic>Swelling kinetics</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Mittal, Hemant</creatorcontrib><creatorcontrib>Babu, Reshma</creatorcontrib><creatorcontrib>Alhassan, Saeed M.</creatorcontrib><collection>PubMed</collection><collection>CrossRef</collection><collection>MEDLINE - Academic</collection><jtitle>International journal of biological macromolecules</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Mittal, Hemant</au><au>Babu, Reshma</au><au>Alhassan, Saeed M.</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Utilization of gum xanthan based superporous hydrogels for the effective removal of methyl violet from aqueous solution</atitle><jtitle>International journal of biological macromolecules</jtitle><addtitle>Int J Biol Macromol</addtitle><date>2020-01-15</date><risdate>2020</risdate><volume>143</volume><spage>413</spage><epage>423</epage><pages>413-423</pages><issn>0141-8130</issn><eissn>1879-0003</eissn><abstract>[Display omitted] •Superporous hydrogels of gum xanthan with AM and AA were synthesized using gas blowing technique.•Swelling kinetics followed first-order kinetics model.•SPH successfully removed methyl violet dye from the solution.•Adsorption kinetics followed pseudo-second-order rate equation.•Adsorption isotherm followed monolayer Langmuir model with qm value of 287.54 mg·g−1. 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subjects Adsorption
Adsorption isotherm
Methyl violet
Superporous hydrogels
Swelling kinetics
title Utilization of gum xanthan based superporous hydrogels for the effective removal of methyl violet from aqueous solution
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