Grain boundary segregation in bright nitrided α-irons alloyed with chromium, molybdenum and silicon

Interfacial segregation in bright nitrided binary alpha -iron alloys containing 3.0 at% Cr, 2.4 at% Mo and 3.6 at% Si were studied by Auger electron spectroscopy. Chromium, molybdenum and silicon were found to segregate to interfaces in these alloys. Segregation of chromium and molybdenum is, howeve...

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Veröffentlicht in:Journal of materials science 1983-11, Vol.18 (11), p.3421-3426
Hauptverfasser: PULKKINEN, R. E. E, LAHDENIEMI, M
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LAHDENIEMI, M
description Interfacial segregation in bright nitrided binary alpha -iron alloys containing 3.0 at% Cr, 2.4 at% Mo and 3.6 at% Si were studied by Auger electron spectroscopy. Chromium, molybdenum and silicon were found to segregate to interfaces in these alloys. Segregation of chromium and molybdenum is, however, partly reduced by the formation of clusters or precipitate between nitrogen and solute atoms. Segregation of silicon is slight owing to the repulsive interaction between silicon and nitrogen atoms. It was not found that such surface active elements as sulfur and phosphorus had segregated to the interfaces in the bright nitrided alloys studied.
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subjects Cross-disciplinary physics: materials science
rheology
Exact sciences and technology
Materials science
Metals, semimetals and alloys
Other heat and thermomechanical treatments
Phase diagrams and microstructures developed by solidification and solid-solid phase transformations
Physics
Specific materials
Treatment of materials and its effects on microstructure and properties
title Grain boundary segregation in bright nitrided α-irons alloyed with chromium, molybdenum and silicon
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