Spin–Orbit Charge‐Transfer Intersystem Crossing (ISC) in Compact Electron Donor–Acceptor Dyads: ISC Mechanism and Application as Novel and Potent Photodynamic Therapy Reagents

Spin–orbit charge‐transfer intersystem crossing (SOCT‐ISC) is useful for the preparation of heavy atom‐free triplet photosensitisers (PSs). Herein, a series of perylene‐Bodipy compact electron donor/acceptor dyads showing efficient SOCT‐ISC is prepared. The photophysical properties of the dyads were...

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Veröffentlicht in:	Chemistry : a European journal 2020-01, Vol.26 (5), p.1091-1102
Hauptverfasser:	Wang, Zhijia, Ivanov, Mikhail, Gao, Yuting, Bussotti, Laura, Foggi, Paolo, Zhang, Huimin, Russo, Nino, Dick, Bernhard, Zhao, Jianzhang, Di Donato, Mariangela, Mazzone, Gloria, Luo, Liang, Fedin, Matvey
Format:	Artikel
Sprache:	eng
Schlagworte:	Absorption spectra Absorption spectroscopy Atomic energy levels Biocompatible Materials - chemical synthesis Biocompatible Materials - chemistry Biocompatible Materials - pharmacology Bodipy Cell Survival - drug effects Charge transfer Chemistry Drug Design Electron paramagnetic resonance electron spin polarization Electron Spin Resonance Spectroscopy Electrons HeLa Cells Humans perylenes Photodynamic therapy Photosensitizing Agents - chemical synthesis Photosensitizing Agents - chemistry Photosensitizing Agents - pharmacology Phototoxicity Polarity Potential energy Quantum Theory Reagents Singlet Oxygen - chemistry Singlet Oxygen - metabolism Solvents - chemistry Spectrum analysis Spin Labels spin–orbital charge-transfer intersystem crossing (SOCT-ISC) Toxicity Triplet state
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