Understanding the Solvent Contribution to Chemical Reaction Barriers

Absolute rate theories attempt to predict the rate constants of reactions from basic principles and independent data. For the contribution of solvent to a reaction rate constant, this requires connecting absolute rate data to fundamental solvent properties such as dielectric constant and refractive...

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Veröffentlicht in:	The journal of physical chemistry. A, Molecules, spectroscopy, kinetics, environment, & general theory Molecules, spectroscopy, kinetics, environment, & general theory, 2019-12, Vol.123 (49), p.10490-10499
Hauptverfasser:	Morris, William, Lorance, Edward D, Gould, Ian R
Format:	Artikel
Sprache:	eng
Online-Zugang:	Volltext
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