Controllability of cupric particle synthesis by linear alcohol chain number as additive and pH control in cupric acetate solution using X‐ray radiolysis
Synthesis and immobilization of caltrop cupric particles onto a Si substrate using X‐ray radiolysis directly from a liquid solution of Cu(COOCH3)2 is demonstrated. Caltrop cupric oxide particles are formed in the X‐ray radiolysis of aqueous solutions of Cu(COOCH3)2, which also contain methanol, etha...
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| Veröffentlicht in: | Journal of synchrotron radiation 2019-11, Vol.26 (6), p.1986-1995 |
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| container_end_page | 1995 |
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| container_issue | 6 |
| container_start_page | 1986 |
| container_title | Journal of synchrotron radiation |
| container_volume | 26 |
| creator | Yamaguchi, Akinobu Okada, Ikuo Sakurai, Ikuya Izumi, Hirokazu Ishihara, Mari Fukuoka, Takao Suzuki, Satoru Elphick, Kelvin Jackson, Edward Hirohata, Atsufumi Utsumi, Yuichi |
| description | Synthesis and immobilization of caltrop cupric particles onto a Si substrate using X‐ray radiolysis directly from a liquid solution of Cu(COOCH3)2 is demonstrated. Caltrop cupric oxide particles are formed in the X‐ray radiolysis of aqueous solutions of Cu(COOCH3)2, which also contain methanol, ethanol, 2‐propanol or 1‐propanol as OH scavenger. The blade lengths of the caltrop particles are dependent on the alcohol chain length. In particular, it was found that an alkyl alcohol whose chain length is longer than four is unable to synthesize any particles in aqueous solutions of Cu(COOCH3)2 in X‐ray radiolysis. These results are attributed to the alkyl alcohol chain length influencing the rate of reaction of radicals and determines the solvable ratio of its alcohol into water. In addition, it was found that the synthesized particle geometric structure and composition can also be controlled by the pH of the aqueous solution in the X‐ray radiolysis. This study may open a door to understanding and investigating a novel photochemical reaction route induced under X‐ray irradiation. The development of the X‐ray radiolysis process enables us to achieve the rapid and easy process of synthesis and immobilization of higher‐order nano/microstructure consisting of various materials.
The controllability of cupric particle synthesis by X‐ray radiolysis is demonstrated. |
| doi_str_mv | 10.1107/S1600577519010543 |
| format | Article |
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The controllability of cupric particle synthesis by X‐ray radiolysis is demonstrated.</description><identifier>ISSN: 1600-5775</identifier><identifier>ISSN: 0909-0495</identifier><identifier>EISSN: 1600-5775</identifier><identifier>DOI: 10.1107/S1600577519010543</identifier><language>eng</language><publisher>5 Abbey Square, Chester, Cheshire CH1 2HU, England: International Union of Crystallography</publisher><subject>Alcohol ; alkyl alcohol ; Aqueous solutions ; Chains ; Controllability ; Copper acetate ; Copper oxides ; cupric particle ; Ethanol ; Immobilization ; pH control ; Photochemical reactions ; Radiolysis ; Silicon substrates ; Stability ; Synthesis ; three‐dimensional additive manufacturing ; X‐ray radiolysis</subject><ispartof>Journal of synchrotron radiation, 2019-11, Vol.26 (6), p.1986-1995</ispartof><rights>International Union of Crystallography, 2019</rights><rights>Copyright Wiley Subscription Services, Inc. Nov 2019</rights><lds50>peer_reviewed</lds50><oa>free_for_read</oa><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c4652-bb833497a4a2dc11c494d291a798943dd19724e876bb9cf2879bbd8d25cce3d63</citedby><cites>FETCH-LOGICAL-c4652-bb833497a4a2dc11c494d291a798943dd19724e876bb9cf2879bbd8d25cce3d63</cites><orcidid>0000-0003-3225-0365 ; 0000-0002-1673-1292</orcidid></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://onlinelibrary.wiley.com/doi/pdf/10.1107%2FS1600577519010543$$EPDF$$P50$$Gwiley$$H</linktopdf><linktohtml>$$Uhttps://onlinelibrary.wiley.com/doi/full/10.1107%2FS1600577519010543$$EHTML$$P50$$Gwiley$$H</linktohtml><link.rule.ids>314,780,784,1417,11562,27924,27925,45574,45575,46052,46476</link.rule.ids><linktorsrc>$$Uhttps://onlinelibrary.wiley.com/doi/abs/10.1107%2FS1600577519010543$$EView_record_in_Wiley-Blackwell$$FView_record_in_$$GWiley-Blackwell</linktorsrc></links><search><creatorcontrib>Yamaguchi, Akinobu</creatorcontrib><creatorcontrib>Okada, Ikuo</creatorcontrib><creatorcontrib>Sakurai, Ikuya</creatorcontrib><creatorcontrib>Izumi, Hirokazu</creatorcontrib><creatorcontrib>Ishihara, Mari</creatorcontrib><creatorcontrib>Fukuoka, Takao</creatorcontrib><creatorcontrib>Suzuki, Satoru</creatorcontrib><creatorcontrib>Elphick, Kelvin</creatorcontrib><creatorcontrib>Jackson, Edward</creatorcontrib><creatorcontrib>Hirohata, Atsufumi</creatorcontrib><creatorcontrib>Utsumi, Yuichi</creatorcontrib><title>Controllability of cupric particle synthesis by linear alcohol chain number as additive and pH control in cupric acetate solution using X‐ray radiolysis</title><title>Journal of synchrotron radiation</title><description>Synthesis and immobilization of caltrop cupric particles onto a Si substrate using X‐ray radiolysis directly from a liquid solution of Cu(COOCH3)2 is demonstrated. Caltrop cupric oxide particles are formed in the X‐ray radiolysis of aqueous solutions of Cu(COOCH3)2, which also contain methanol, ethanol, 2‐propanol or 1‐propanol as OH scavenger. The blade lengths of the caltrop particles are dependent on the alcohol chain length. In particular, it was found that an alkyl alcohol whose chain length is longer than four is unable to synthesize any particles in aqueous solutions of Cu(COOCH3)2 in X‐ray radiolysis. These results are attributed to the alkyl alcohol chain length influencing the rate of reaction of radicals and determines the solvable ratio of its alcohol into water. In addition, it was found that the synthesized particle geometric structure and composition can also be controlled by the pH of the aqueous solution in the X‐ray radiolysis. This study may open a door to understanding and investigating a novel photochemical reaction route induced under X‐ray irradiation. The development of the X‐ray radiolysis process enables us to achieve the rapid and easy process of synthesis and immobilization of higher‐order nano/microstructure consisting of various materials.
The controllability of cupric particle synthesis by X‐ray radiolysis is demonstrated.</description><subject>Alcohol</subject><subject>alkyl alcohol</subject><subject>Aqueous solutions</subject><subject>Chains</subject><subject>Controllability</subject><subject>Copper acetate</subject><subject>Copper oxides</subject><subject>cupric particle</subject><subject>Ethanol</subject><subject>Immobilization</subject><subject>pH control</subject><subject>Photochemical reactions</subject><subject>Radiolysis</subject><subject>Silicon substrates</subject><subject>Stability</subject><subject>Synthesis</subject><subject>three‐dimensional additive manufacturing</subject><subject>X‐ray radiolysis</subject><issn>1600-5775</issn><issn>0909-0495</issn><issn>1600-5775</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2019</creationdate><recordtype>article</recordtype><recordid>eNqFkb1uFDEUhUcRSPkhD5DuSjRpFvw7HpfRipCgSBQBiVQj_y3ryGtvbE_QdDxCah6PJ8HLpkBQUNk6-s7xvT5dd4bRG4yReHuLe4S4EBxLhBFn9KA72kmLnfbij_thd1zKPUK4F4QedT-WKdacQlDaB19nSCsw0zZ7A1uVqzfBQZljXbviC-gZgo9OZVDBpHUKYNbKR4jTRrsmFlDW-uofHahoYXsFZh8PDXqOVcZVVVtqClP1KcJUfPwKX35-f8pqhqysT2Fur73qXq5UKO70-TzpPl---7S8Wtx8fH-9vLhZGNZzstB6oJRJoZgi1mBsmGSWSKyEHCSj1mIpCHOD6LWWZkUGIbW2gyXcGEdtT0-6833uNqeHyZU6bnwxrn1JdGkqI6GYcU4Gyhv6-i_0Pk05tul-U4j1YsCNwnvK5FRKdquxLb5ReR4xGndtjf-01Txy7_nmg5v_bxg_3N6RizvOGaG_ANcgmx8</recordid><startdate>201911</startdate><enddate>201911</enddate><creator>Yamaguchi, Akinobu</creator><creator>Okada, Ikuo</creator><creator>Sakurai, Ikuya</creator><creator>Izumi, Hirokazu</creator><creator>Ishihara, Mari</creator><creator>Fukuoka, Takao</creator><creator>Suzuki, Satoru</creator><creator>Elphick, Kelvin</creator><creator>Jackson, Edward</creator><creator>Hirohata, Atsufumi</creator><creator>Utsumi, Yuichi</creator><general>International Union of Crystallography</general><general>John Wiley & Sons, Inc</general><scope>AAYXX</scope><scope>CITATION</scope><scope>7U5</scope><scope>8FD</scope><scope>JQ2</scope><scope>L7M</scope><scope>7X8</scope><orcidid>https://orcid.org/0000-0003-3225-0365</orcidid><orcidid>https://orcid.org/0000-0002-1673-1292</orcidid></search><sort><creationdate>201911</creationdate><title>Controllability of cupric particle synthesis by linear alcohol chain number as additive and pH control in cupric acetate solution using X‐ray radiolysis</title><author>Yamaguchi, Akinobu ; Okada, Ikuo ; Sakurai, Ikuya ; Izumi, Hirokazu ; Ishihara, Mari ; Fukuoka, Takao ; Suzuki, Satoru ; Elphick, Kelvin ; Jackson, Edward ; Hirohata, Atsufumi ; Utsumi, Yuichi</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c4652-bb833497a4a2dc11c494d291a798943dd19724e876bb9cf2879bbd8d25cce3d63</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2019</creationdate><topic>Alcohol</topic><topic>alkyl alcohol</topic><topic>Aqueous solutions</topic><topic>Chains</topic><topic>Controllability</topic><topic>Copper acetate</topic><topic>Copper oxides</topic><topic>cupric particle</topic><topic>Ethanol</topic><topic>Immobilization</topic><topic>pH control</topic><topic>Photochemical reactions</topic><topic>Radiolysis</topic><topic>Silicon substrates</topic><topic>Stability</topic><topic>Synthesis</topic><topic>three‐dimensional additive manufacturing</topic><topic>X‐ray radiolysis</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Yamaguchi, Akinobu</creatorcontrib><creatorcontrib>Okada, Ikuo</creatorcontrib><creatorcontrib>Sakurai, Ikuya</creatorcontrib><creatorcontrib>Izumi, Hirokazu</creatorcontrib><creatorcontrib>Ishihara, Mari</creatorcontrib><creatorcontrib>Fukuoka, Takao</creatorcontrib><creatorcontrib>Suzuki, Satoru</creatorcontrib><creatorcontrib>Elphick, Kelvin</creatorcontrib><creatorcontrib>Jackson, Edward</creatorcontrib><creatorcontrib>Hirohata, Atsufumi</creatorcontrib><creatorcontrib>Utsumi, Yuichi</creatorcontrib><collection>CrossRef</collection><collection>Solid State and Superconductivity Abstracts</collection><collection>Technology Research Database</collection><collection>ProQuest Computer Science Collection</collection><collection>Advanced Technologies Database with Aerospace</collection><collection>MEDLINE - Academic</collection><jtitle>Journal of synchrotron radiation</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext_linktorsrc</fulltext></delivery><addata><au>Yamaguchi, Akinobu</au><au>Okada, Ikuo</au><au>Sakurai, Ikuya</au><au>Izumi, Hirokazu</au><au>Ishihara, Mari</au><au>Fukuoka, Takao</au><au>Suzuki, Satoru</au><au>Elphick, Kelvin</au><au>Jackson, Edward</au><au>Hirohata, Atsufumi</au><au>Utsumi, Yuichi</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Controllability of cupric particle synthesis by linear alcohol chain number as additive and pH control in cupric acetate solution using X‐ray radiolysis</atitle><jtitle>Journal of synchrotron radiation</jtitle><date>2019-11</date><risdate>2019</risdate><volume>26</volume><issue>6</issue><spage>1986</spage><epage>1995</epage><pages>1986-1995</pages><issn>1600-5775</issn><issn>0909-0495</issn><eissn>1600-5775</eissn><abstract>Synthesis and immobilization of caltrop cupric particles onto a Si substrate using X‐ray radiolysis directly from a liquid solution of Cu(COOCH3)2 is demonstrated. Caltrop cupric oxide particles are formed in the X‐ray radiolysis of aqueous solutions of Cu(COOCH3)2, which also contain methanol, ethanol, 2‐propanol or 1‐propanol as OH scavenger. The blade lengths of the caltrop particles are dependent on the alcohol chain length. In particular, it was found that an alkyl alcohol whose chain length is longer than four is unable to synthesize any particles in aqueous solutions of Cu(COOCH3)2 in X‐ray radiolysis. These results are attributed to the alkyl alcohol chain length influencing the rate of reaction of radicals and determines the solvable ratio of its alcohol into water. In addition, it was found that the synthesized particle geometric structure and composition can also be controlled by the pH of the aqueous solution in the X‐ray radiolysis. This study may open a door to understanding and investigating a novel photochemical reaction route induced under X‐ray irradiation. The development of the X‐ray radiolysis process enables us to achieve the rapid and easy process of synthesis and immobilization of higher‐order nano/microstructure consisting of various materials.
The controllability of cupric particle synthesis by X‐ray radiolysis is demonstrated.</abstract><cop>5 Abbey Square, Chester, Cheshire CH1 2HU, England</cop><pub>International Union of Crystallography</pub><doi>10.1107/S1600577519010543</doi><tpages>9</tpages><orcidid>https://orcid.org/0000-0003-3225-0365</orcidid><orcidid>https://orcid.org/0000-0002-1673-1292</orcidid><oa>free_for_read</oa></addata></record> |
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| identifier | ISSN: 1600-5775 |
| ispartof | Journal of synchrotron radiation, 2019-11, Vol.26 (6), p.1986-1995 |
| issn | 1600-5775 0909-0495 1600-5775 |
| language | eng |
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| source | Wiley Online Library Open Access |
| subjects | Alcohol alkyl alcohol Aqueous solutions Chains Controllability Copper acetate Copper oxides cupric particle Ethanol Immobilization pH control Photochemical reactions Radiolysis Silicon substrates Stability Synthesis three‐dimensional additive manufacturing X‐ray radiolysis |
| title | Controllability of cupric particle synthesis by linear alcohol chain number as additive and pH control in cupric acetate solution using X‐ray radiolysis |
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