Interactions between polystyrene particles with diameters of several tens to hundreds of micrometers at the oil–water interface

[Display omitted] Hypothesis: The charged spherical colloidal particles at the fluid–fluid interface experience considerably strong and long-ranged electrostatic and capillary interactions. The contribution of capillary force becomes more significant as the particle size increases beyond a certain limit. The relative strengths of the two competing interactions between the spherical polystyrene particles at the oil–water interface are quantified depending on their size. Experiments: The studied particles, obtained using the microfluidic method, have diameters of tens to hundreds of micrometers. The scaling behaviors of the commercially available colloidal particles with diameters of ~3 μm are also compared. An optical laser tweezer apparatus is used to directly or indirectly measure the interparticle force. Subsequently, the capillary force that can be attributed to the gravity-induced interface deformation and contact line undulation is calculated and compared with the measured interaction force. Findings: Regardless of the particle diameter (~3–330 μm), the measured force is observed to decay as r−4, where r denotes the center-to-center separation, demonstrating that the dipolar electrostatic interaction is important and that the gravity-induced capillary interaction is negligible. Furthermore, numerical calculations with respect to the undulated meniscus confirm that the magnitude of capillary interaction is significantly smaller than that of the measured electrostatic interaction.