Porous organic polymer supported rhodium as a heterogeneous catalyst for hydroformylation of alkynes to α,β-unsaturated aldehydes
A new porous organic polymer supported rhodium catalyst (Rh/POL-BINAPa&PPh 3 ) has been developed for the hydroformylation of various alkynes to afford the corresponding α,β-unsaturated aldehydes with high chem- and stereoselectivity, excellent catalytic activity and good reusability (10 cycles)...
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| Veröffentlicht in: | Chemical communications (Cambridge, England) England), 2019-11, Vol.55 (91), p.13721-13724 |
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| container_title | Chemical communications (Cambridge, England) |
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| creator | Liang, Zuyu Chen, Jianbin Chen, Xin Zhang, Kai Lv, Jinhe Zhao, Haowen Zhang, Guoying Xie, Congxia Zong, Lingbo Jia, Xiaofei |
| description | A new porous organic polymer supported rhodium catalyst (Rh/POL-BINAPa&PPh
3
) has been developed for the hydroformylation of various alkynes to afford the corresponding α,β-unsaturated aldehydes with high chem- and stereoselectivity, excellent catalytic activity and good reusability (10 cycles). The heterogeneous catalyst exhibited more catalytic activity than the comparable homogeneous Rh/BINAPa/PPh
3
system.
A novel porous organic polymer supported rhodium catalyst (Rh/POL-BINAPa&PPh
3
) was developed for the hydroformylation of alkynes to afford α,β-unsaturated aldehydes. |
| doi_str_mv | 10.1039/c9cc06834a |
| format | Article |
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3
) has been developed for the hydroformylation of various alkynes to afford the corresponding α,β-unsaturated aldehydes with high chem- and stereoselectivity, excellent catalytic activity and good reusability (10 cycles). The heterogeneous catalyst exhibited more catalytic activity than the comparable homogeneous Rh/BINAPa/PPh
3
system.
A novel porous organic polymer supported rhodium catalyst (Rh/POL-BINAPa&PPh
3
) was developed for the hydroformylation of alkynes to afford α,β-unsaturated aldehydes.</description><identifier>ISSN: 1359-7345</identifier><identifier>EISSN: 1364-548X</identifier><identifier>DOI: 10.1039/c9cc06834a</identifier><language>eng</language><publisher>Cambridge: Royal Society of Chemistry</publisher><subject>Aldehydes ; Alkynes ; Catalysts ; Catalytic activity ; NMR ; Nuclear magnetic resonance ; Polymers ; Rhodium ; Stereoselectivity</subject><ispartof>Chemical communications (Cambridge, England), 2019-11, Vol.55 (91), p.13721-13724</ispartof><rights>Copyright Royal Society of Chemistry 2019</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c314t-8dfd62e35214fab6ebc49685199e542c26f174c300a6d515eff0062d959e106b3</citedby><cites>FETCH-LOGICAL-c314t-8dfd62e35214fab6ebc49685199e542c26f174c300a6d515eff0062d959e106b3</cites><orcidid>0000-0002-1209-2745 ; 0000-0002-5306-0395 ; 0000-0003-1104-7237</orcidid></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><link.rule.ids>314,777,781,27905,27906</link.rule.ids></links><search><creatorcontrib>Liang, Zuyu</creatorcontrib><creatorcontrib>Chen, Jianbin</creatorcontrib><creatorcontrib>Chen, Xin</creatorcontrib><creatorcontrib>Zhang, Kai</creatorcontrib><creatorcontrib>Lv, Jinhe</creatorcontrib><creatorcontrib>Zhao, Haowen</creatorcontrib><creatorcontrib>Zhang, Guoying</creatorcontrib><creatorcontrib>Xie, Congxia</creatorcontrib><creatorcontrib>Zong, Lingbo</creatorcontrib><creatorcontrib>Jia, Xiaofei</creatorcontrib><title>Porous organic polymer supported rhodium as a heterogeneous catalyst for hydroformylation of alkynes to α,β-unsaturated aldehydes</title><title>Chemical communications (Cambridge, England)</title><description>A new porous organic polymer supported rhodium catalyst (Rh/POL-BINAPa&PPh
3
) has been developed for the hydroformylation of various alkynes to afford the corresponding α,β-unsaturated aldehydes with high chem- and stereoselectivity, excellent catalytic activity and good reusability (10 cycles). The heterogeneous catalyst exhibited more catalytic activity than the comparable homogeneous Rh/BINAPa/PPh
3
system.
A novel porous organic polymer supported rhodium catalyst (Rh/POL-BINAPa&PPh
3
) was developed for the hydroformylation of alkynes to afford α,β-unsaturated aldehydes.</description><subject>Aldehydes</subject><subject>Alkynes</subject><subject>Catalysts</subject><subject>Catalytic activity</subject><subject>NMR</subject><subject>Nuclear magnetic resonance</subject><subject>Polymers</subject><subject>Rhodium</subject><subject>Stereoselectivity</subject><issn>1359-7345</issn><issn>1364-548X</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2019</creationdate><recordtype>article</recordtype><recordid>eNpdkctKxTAQhosoeN24FwJuRKwmzeU0SyneQNCFgruSk0481bapSbro2ifSB_GZTM8RBWczs_jm55_5k2Sf4FOCqTzTUmsscsrUWrJFqGApZ_nT-jRzmc4o45vJtvcvOBbh-Vbyfm-dHTyy7ll1tUa9bcYWHPJD31sXoEJuYat6aJHySKEFBHD2GTqYlrQKqhl9QMY6tBgrZ-PQjo0Kte2QNUg1r2MHHgWLvj5Ovj7TofMqDE5NwqqpIC6B3002jGo87P30neTx8uKhuE5v765uivPbVFPCQppXphIZUJ4RZtRcwFwzKXJOpATOMp0JQ2ZMU4yVqDjhYAzGIqskl0CwmNOd5Gil2zv7NoAPZVt7DU2jlueUGY0_xCSTs4ge_kNf7OC66G6i4i95tBSp4xWlnfXegSl7V7fKjSXB5ZRHWciiWOZxHuGDFey8_uX-8qLfBg2LLA</recordid><startdate>20191125</startdate><enddate>20191125</enddate><creator>Liang, Zuyu</creator><creator>Chen, Jianbin</creator><creator>Chen, Xin</creator><creator>Zhang, Kai</creator><creator>Lv, Jinhe</creator><creator>Zhao, Haowen</creator><creator>Zhang, Guoying</creator><creator>Xie, Congxia</creator><creator>Zong, Lingbo</creator><creator>Jia, Xiaofei</creator><general>Royal Society of Chemistry</general><scope>AAYXX</scope><scope>CITATION</scope><scope>7SR</scope><scope>7U5</scope><scope>8BQ</scope><scope>8FD</scope><scope>JG9</scope><scope>L7M</scope><scope>7X8</scope><orcidid>https://orcid.org/0000-0002-1209-2745</orcidid><orcidid>https://orcid.org/0000-0002-5306-0395</orcidid><orcidid>https://orcid.org/0000-0003-1104-7237</orcidid></search><sort><creationdate>20191125</creationdate><title>Porous organic polymer supported rhodium as a heterogeneous catalyst for hydroformylation of alkynes to α,β-unsaturated aldehydes</title><author>Liang, Zuyu ; Chen, Jianbin ; Chen, Xin ; Zhang, Kai ; Lv, Jinhe ; Zhao, Haowen ; Zhang, Guoying ; Xie, Congxia ; Zong, Lingbo ; Jia, Xiaofei</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c314t-8dfd62e35214fab6ebc49685199e542c26f174c300a6d515eff0062d959e106b3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2019</creationdate><topic>Aldehydes</topic><topic>Alkynes</topic><topic>Catalysts</topic><topic>Catalytic activity</topic><topic>NMR</topic><topic>Nuclear magnetic resonance</topic><topic>Polymers</topic><topic>Rhodium</topic><topic>Stereoselectivity</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Liang, Zuyu</creatorcontrib><creatorcontrib>Chen, Jianbin</creatorcontrib><creatorcontrib>Chen, Xin</creatorcontrib><creatorcontrib>Zhang, Kai</creatorcontrib><creatorcontrib>Lv, Jinhe</creatorcontrib><creatorcontrib>Zhao, Haowen</creatorcontrib><creatorcontrib>Zhang, Guoying</creatorcontrib><creatorcontrib>Xie, Congxia</creatorcontrib><creatorcontrib>Zong, Lingbo</creatorcontrib><creatorcontrib>Jia, Xiaofei</creatorcontrib><collection>CrossRef</collection><collection>Engineered Materials Abstracts</collection><collection>Solid State and Superconductivity Abstracts</collection><collection>METADEX</collection><collection>Technology Research Database</collection><collection>Materials Research Database</collection><collection>Advanced Technologies Database with Aerospace</collection><collection>MEDLINE - Academic</collection><jtitle>Chemical communications (Cambridge, England)</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Liang, Zuyu</au><au>Chen, Jianbin</au><au>Chen, Xin</au><au>Zhang, Kai</au><au>Lv, Jinhe</au><au>Zhao, Haowen</au><au>Zhang, Guoying</au><au>Xie, Congxia</au><au>Zong, Lingbo</au><au>Jia, Xiaofei</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Porous organic polymer supported rhodium as a heterogeneous catalyst for hydroformylation of alkynes to α,β-unsaturated aldehydes</atitle><jtitle>Chemical communications (Cambridge, England)</jtitle><date>2019-11-25</date><risdate>2019</risdate><volume>55</volume><issue>91</issue><spage>13721</spage><epage>13724</epage><pages>13721-13724</pages><issn>1359-7345</issn><eissn>1364-548X</eissn><abstract>A new porous organic polymer supported rhodium catalyst (Rh/POL-BINAPa&PPh
3
) has been developed for the hydroformylation of various alkynes to afford the corresponding α,β-unsaturated aldehydes with high chem- and stereoselectivity, excellent catalytic activity and good reusability (10 cycles). The heterogeneous catalyst exhibited more catalytic activity than the comparable homogeneous Rh/BINAPa/PPh
3
system.
A novel porous organic polymer supported rhodium catalyst (Rh/POL-BINAPa&PPh
3
) was developed for the hydroformylation of alkynes to afford α,β-unsaturated aldehydes.</abstract><cop>Cambridge</cop><pub>Royal Society of Chemistry</pub><doi>10.1039/c9cc06834a</doi><tpages>4</tpages><orcidid>https://orcid.org/0000-0002-1209-2745</orcidid><orcidid>https://orcid.org/0000-0002-5306-0395</orcidid><orcidid>https://orcid.org/0000-0003-1104-7237</orcidid></addata></record> |
| fulltext | fulltext |
| identifier | ISSN: 1359-7345 |
| ispartof | Chemical communications (Cambridge, England), 2019-11, Vol.55 (91), p.13721-13724 |
| issn | 1359-7345 1364-548X |
| language | eng |
| recordid | cdi_proquest_miscellaneous_2310301297 |
| source | Royal Society Of Chemistry Journals 2008-; Alma/SFX Local Collection |
| subjects | Aldehydes Alkynes Catalysts Catalytic activity NMR Nuclear magnetic resonance Polymers Rhodium Stereoselectivity |
| title | Porous organic polymer supported rhodium as a heterogeneous catalyst for hydroformylation of alkynes to α,β-unsaturated aldehydes |
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