Nickel-catalyzed reductive defunctionalization of esters in the absence of an external reductant: activation of C-O bonds

The nickel-catalyzed reductive cleavage of esters in the absence of an external reductant, which involves the cleavage of an inert acyl C-O bond in O -alkyl esters is reported. Various groups, such as N-containing heterocycles, esters, amides, and even arene rings can function as a directing group....

Ausführliche Beschreibung

Gespeichert in:

Bibliographische Detailangaben
Veröffentlicht in:	Chemical communications (Cambridge, England) England), 2019-11, Vol.55 (9), p.1361-13613
Hauptverfasser:	Iyori, Yasuaki, Takahashi, Kenjiro, Yamazaki, Ken, Ano, Yusuke, Chatani, Naoto
Format:	Artikel
Sprache:	eng
Schlagworte:	Amides Cleavage Esters Nickel
Online-Zugang:	Volltext
Tags:	Tag hinzufügen Keine Tags, Fügen Sie den ersten Tag hinzu!

container_end_page	13613
container_issue	9
container_start_page	1361
container_title	Chemical communications (Cambridge, England)
container_volume	55
creator	Iyori, Yasuaki Takahashi, Kenjiro Yamazaki, Ken Ano, Yusuke Chatani, Naoto
description	The nickel-catalyzed reductive cleavage of esters in the absence of an external reductant, which involves the cleavage of an inert acyl C-O bond in O -alkyl esters is reported. Various groups, such as N-containing heterocycles, esters, amides, and even arene rings can function as a directing group. The nickel-catalyzed reductive cleavage of esters in the absence of an external reductant, which involves the cleavage of an inert acyl C-O bond in O -alkyl esters is reported.
doi_str_mv	10.1039/c9cc07710c
format	Article
fullrecord	<record><control><sourceid>proquest_cross</sourceid><recordid>TN_cdi_proquest_miscellaneous_2309806855</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><sourcerecordid>2312550732</sourcerecordid><originalsourceid>FETCH-LOGICAL-c380t-52401e77f363972b8a7048b0ea4056ea458116e032f315c3440d0996a9c3a9eb3</originalsourceid><addsrcrecordid>eNpdkc1LxDAQxYsoqKsX70LAiwjVSZM0iTcpfsHiXhS8lTSdYrWbrk0r7v71pu6ygnPIPHi_PBJeFJ1QuKTA9JXV1oKUFOxOdEBZymPB1evuqIWOJeNiPzr0_h3CUKEOouVTbT-wia3pTbNcYUk6LAfb119ISqwGF2TrTFOvzChIWxH0PXae1I70b0hM4dFZHA3jCH4HL-CbFOP6a2LGtO3tLJ6RonWlP4r2KtN4PN7sSfRyd_ucPcTT2f1jdjONLVPQxyLhQFHKiqVMy6RQRgJXBaDhINJwCkVpisCSilFhGedQgtap0ZYZjQWbROfr3EXXfg7h8fm89habxjhsB58nDLSCVAkR0LN_6Hs7jN8ZKZoIAZIlgbpYU7Zrve-wyhddPTfdMqeQjy3kmc6y3xayAJ-u4c7bLffXEvsBx-mDqA</addsrcrecordid><sourcetype>Aggregation Database</sourcetype><iscdi>true</iscdi><recordtype>article</recordtype><pqid>2312550732</pqid></control><display><type>article</type><title>Nickel-catalyzed reductive defunctionalization of esters in the absence of an external reductant: activation of C-O bonds</title><source>Royal Society Of Chemistry Journals 2008-</source><source>Alma/SFX Local Collection</source><creator>Iyori, Yasuaki ; Takahashi, Kenjiro ; Yamazaki, Ken ; Ano, Yusuke ; Chatani, Naoto</creator><creatorcontrib>Iyori, Yasuaki ; Takahashi, Kenjiro ; Yamazaki, Ken ; Ano, Yusuke ; Chatani, Naoto</creatorcontrib><description>The nickel-catalyzed reductive cleavage of esters in the absence of an external reductant, which involves the cleavage of an inert acyl C-O bond in O -alkyl esters is reported. Various groups, such as N-containing heterocycles, esters, amides, and even arene rings can function as a directing group. The nickel-catalyzed reductive cleavage of esters in the absence of an external reductant, which involves the cleavage of an inert acyl C-O bond in O -alkyl esters is reported.</description><identifier>ISSN: 1359-7345</identifier><identifier>EISSN: 1364-548X</identifier><identifier>DOI: 10.1039/c9cc07710c</identifier><language>eng</language><publisher>Cambridge: Royal Society of Chemistry</publisher><subject>Amides ; Cleavage ; Esters ; Nickel</subject><ispartof>Chemical communications (Cambridge, England), 2019-11, Vol.55 (9), p.1361-13613</ispartof><rights>Copyright Royal Society of Chemistry 2019</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c380t-52401e77f363972b8a7048b0ea4056ea458116e032f315c3440d0996a9c3a9eb3</citedby><cites>FETCH-LOGICAL-c380t-52401e77f363972b8a7048b0ea4056ea458116e032f315c3440d0996a9c3a9eb3</cites><orcidid>0000-0001-8330-7478 ; 0000-0003-2492-696X</orcidid></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><link.rule.ids>314,776,780,27901,27902</link.rule.ids></links><search><creatorcontrib>Iyori, Yasuaki</creatorcontrib><creatorcontrib>Takahashi, Kenjiro</creatorcontrib><creatorcontrib>Yamazaki, Ken</creatorcontrib><creatorcontrib>Ano, Yusuke</creatorcontrib><creatorcontrib>Chatani, Naoto</creatorcontrib><title>Nickel-catalyzed reductive defunctionalization of esters in the absence of an external reductant: activation of C-O bonds</title><title>Chemical communications (Cambridge, England)</title><description>The nickel-catalyzed reductive cleavage of esters in the absence of an external reductant, which involves the cleavage of an inert acyl C-O bond in O -alkyl esters is reported. Various groups, such as N-containing heterocycles, esters, amides, and even arene rings can function as a directing group. The nickel-catalyzed reductive cleavage of esters in the absence of an external reductant, which involves the cleavage of an inert acyl C-O bond in O -alkyl esters is reported.</description><subject>Amides</subject><subject>Cleavage</subject><subject>Esters</subject><subject>Nickel</subject><issn>1359-7345</issn><issn>1364-548X</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2019</creationdate><recordtype>article</recordtype><recordid>eNpdkc1LxDAQxYsoqKsX70LAiwjVSZM0iTcpfsHiXhS8lTSdYrWbrk0r7v71pu6ygnPIPHi_PBJeFJ1QuKTA9JXV1oKUFOxOdEBZymPB1evuqIWOJeNiPzr0_h3CUKEOouVTbT-wia3pTbNcYUk6LAfb119ISqwGF2TrTFOvzChIWxH0PXae1I70b0hM4dFZHA3jCH4HL-CbFOP6a2LGtO3tLJ6RonWlP4r2KtN4PN7sSfRyd_ucPcTT2f1jdjONLVPQxyLhQFHKiqVMy6RQRgJXBaDhINJwCkVpisCSilFhGedQgtap0ZYZjQWbROfr3EXXfg7h8fm89habxjhsB58nDLSCVAkR0LN_6Hs7jN8ZKZoIAZIlgbpYU7Zrve-wyhddPTfdMqeQjy3kmc6y3xayAJ-u4c7bLffXEvsBx-mDqA</recordid><startdate>20191107</startdate><enddate>20191107</enddate><creator>Iyori, Yasuaki</creator><creator>Takahashi, Kenjiro</creator><creator>Yamazaki, Ken</creator><creator>Ano, Yusuke</creator><creator>Chatani, Naoto</creator><general>Royal Society of Chemistry</general><scope>AAYXX</scope><scope>CITATION</scope><scope>7SR</scope><scope>7U5</scope><scope>8BQ</scope><scope>8FD</scope><scope>JG9</scope><scope>L7M</scope><scope>7X8</scope><orcidid>https://orcid.org/0000-0001-8330-7478</orcidid><orcidid>https://orcid.org/0000-0003-2492-696X</orcidid></search><sort><creationdate>20191107</creationdate><title>Nickel-catalyzed reductive defunctionalization of esters in the absence of an external reductant: activation of C-O bonds</title><author>Iyori, Yasuaki ; Takahashi, Kenjiro ; Yamazaki, Ken ; Ano, Yusuke ; Chatani, Naoto</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c380t-52401e77f363972b8a7048b0ea4056ea458116e032f315c3440d0996a9c3a9eb3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2019</creationdate><topic>Amides</topic><topic>Cleavage</topic><topic>Esters</topic><topic>Nickel</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Iyori, Yasuaki</creatorcontrib><creatorcontrib>Takahashi, Kenjiro</creatorcontrib><creatorcontrib>Yamazaki, Ken</creatorcontrib><creatorcontrib>Ano, Yusuke</creatorcontrib><creatorcontrib>Chatani, Naoto</creatorcontrib><collection>CrossRef</collection><collection>Engineered Materials Abstracts</collection><collection>Solid State and Superconductivity Abstracts</collection><collection>METADEX</collection><collection>Technology Research Database</collection><collection>Materials Research Database</collection><collection>Advanced Technologies Database with Aerospace</collection><collection>MEDLINE - Academic</collection><jtitle>Chemical communications (Cambridge, England)</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Iyori, Yasuaki</au><au>Takahashi, Kenjiro</au><au>Yamazaki, Ken</au><au>Ano, Yusuke</au><au>Chatani, Naoto</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Nickel-catalyzed reductive defunctionalization of esters in the absence of an external reductant: activation of C-O bonds</atitle><jtitle>Chemical communications (Cambridge, England)</jtitle><date>2019-11-07</date><risdate>2019</risdate><volume>55</volume><issue>9</issue><spage>1361</spage><epage>13613</epage><pages>1361-13613</pages><issn>1359-7345</issn><eissn>1364-548X</eissn><abstract>The nickel-catalyzed reductive cleavage of esters in the absence of an external reductant, which involves the cleavage of an inert acyl C-O bond in O -alkyl esters is reported. Various groups, such as N-containing heterocycles, esters, amides, and even arene rings can function as a directing group. The nickel-catalyzed reductive cleavage of esters in the absence of an external reductant, which involves the cleavage of an inert acyl C-O bond in O -alkyl esters is reported.</abstract><cop>Cambridge</cop><pub>Royal Society of Chemistry</pub><doi>10.1039/c9cc07710c</doi><tpages>4</tpages><orcidid>https://orcid.org/0000-0001-8330-7478</orcidid><orcidid>https://orcid.org/0000-0003-2492-696X</orcidid></addata></record>
fulltext	fulltext
identifier	ISSN: 1359-7345
ispartof	Chemical communications (Cambridge, England), 2019-11, Vol.55 (9), p.1361-13613
issn	1359-7345 1364-548X
language	eng
recordid	cdi_proquest_miscellaneous_2309806855
source	Royal Society Of Chemistry Journals 2008-; Alma/SFX Local Collection
subjects	Amides Cleavage Esters Nickel
title	Nickel-catalyzed reductive defunctionalization of esters in the absence of an external reductant: activation of C-O bonds
url	https://sfx.bib-bvb.de/sfx_tum?ctx_ver=Z39.88-2004&ctx_enc=info:ofi/enc:UTF-8&ctx_tim=2025-02-02T10%3A51%3A18IST&url_ver=Z39.88-2004&url_ctx_fmt=infofi/fmt:kev:mtx:ctx&rfr_id=info:sid/primo.exlibrisgroup.com:primo3-Article-proquest_cross&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.genre=article&rft.atitle=Nickel-catalyzed%20reductive%20defunctionalization%20of%20esters%20in%20the%20absence%20of%20an%20external%20reductant:%20activation%20of%20C-O%20bonds&rft.jtitle=Chemical%20communications%20(Cambridge,%20England)&rft.au=Iyori,%20Yasuaki&rft.date=2019-11-07&rft.volume=55&rft.issue=9&rft.spage=1361&rft.epage=13613&rft.pages=1361-13613&rft.issn=1359-7345&rft.eissn=1364-548X&rft_id=info:doi/10.1039/c9cc07710c&rft_dat=%3Cproquest_cross%3E2312550732%3C/proquest_cross%3E%3Curl%3E%3C/url%3E&disable_directlink=true&sfx.directlink=off&sfx.report_link=0&rft_id=info:oai/&rft_pqid=2312550732&rft_id=info:pmid/&rfr_iscdi=true