Mechanistic insights on the non-innocent role of electron donors: reversible photocapture of CO2 by RuII-polypyridyl complexes

The ability of [RuII(tButpy)(dmbpy)(MeCN)]2+ (1-MeCN) to capture CO2, with the assistance of triethanolamine (TEOA), has been assessed under photocatalytically-relevant conditions. The photolability of 1-MeCN has proven essential to generate a series of intermediates which only differ by the nature...

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Veröffentlicht in:	Dalton transactions : an international journal of inorganic chemistry 2019-12, Vol.48 (45), p.16894-16898
Hauptverfasser:	Queyriaux, Nicolas, Swords, Wesley B, Agarwala, Hemlata, Johnson, Ben A, Ott, Sascha, Hammarström, Leif
Format:	Artikel
Sprache:	eng
Schlagworte:	Carbon dioxide Donors (electronic) Ligands Triethanolamine
Online-Zugang:	Volltext
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