Rational Tuning of Zirconium Metal–Organic Framework Membranes for Hydrogen Purification
The effect of organic ligands on the separation performance of Zr based metal–organic framework (Zr‐MOF) membranes was investigated. A series of Zr‐MOF membranes with different ligand chemistry and functionality were synthesized by an in situ solvothermal method and a coordination modulation techniq...
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| Veröffentlicht in: | Angewandte Chemie International Edition 2019-12, Vol.58 (52), p.19034-19040 |
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| creator | Ghalei, Behnam Wakimoto, Kazuki Wu, Chih Yi Isfahani, Ali Pournaghshband Yamamoto, Takuma Sakurai, Kento Higuchi, Masakazu Chang, Bor Kae Kitagawa, Susumu Sivaniah, Easan |
| description | The effect of organic ligands on the separation performance of Zr based metal–organic framework (Zr‐MOF) membranes was investigated. A series of Zr‐MOF membranes with different ligand chemistry and functionality were synthesized by an in situ solvothermal method and a coordination modulation technique. The thin supported MOF layers (ca. 1 μm) showed the crystallographic orientation and pore structure of original MOF structures. The MOF membranes show excellent selectivity towards hydrogen owing to the molecular sieving effect when the bulkier linkers were used. The molecular simulation confirmed that the constricted pore apertures of the Zr‐MOFs which were formed by the additional benzene rings lead to the decrease in the diffusivity of larger penetrants while hydrogen was not remarkably affected. The gas mixture separation factors of the MOF membranes reached to H2/CO2=26, H2/N2=13, H2/CH4=11.
Zr‐MOF membranes for hydrogen separation have been developed and tuned. The MOF membranes have shown great selectivity towards hydrogen, which is due to the molecular sieving effect when the bulkier ligands were used to narrow down the pore apertures of the MOFs. |
| doi_str_mv | 10.1002/anie.201911359 |
| format | Article |
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Zr‐MOF membranes for hydrogen separation have been developed and tuned. The MOF membranes have shown great selectivity towards hydrogen, which is due to the molecular sieving effect when the bulkier ligands were used to narrow down the pore apertures of the MOFs.</description><edition>International ed. in English</edition><identifier>ISSN: 1433-7851</identifier><identifier>EISSN: 1521-3773</identifier><identifier>DOI: 10.1002/anie.201911359</identifier><identifier>PMID: 31602745</identifier><language>eng</language><publisher>Germany: Wiley Subscription Services, Inc</publisher><subject>Apertures ; Benzene ; Carbon dioxide ; Chemical synthesis ; Crystallography ; Gas mixtures ; Hydrogen ; Ligands ; Membranes ; Metal-organic frameworks ; molecular simulation ; Organic chemistry ; Penetrants ; Porosity ; Purification ; Selectivity ; Separation ; Thin films ; Zirconium</subject><ispartof>Angewandte Chemie International Edition, 2019-12, Vol.58 (52), p.19034-19040</ispartof><rights>2019 Wiley‐VCH Verlag GmbH & Co. KGaA, Weinheim</rights><rights>2019 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim.</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c4769-204bbd3659e8b4027575f527b49a48019b05f7e080f882c29254cc8344f0366b3</citedby><cites>FETCH-LOGICAL-c4769-204bbd3659e8b4027575f527b49a48019b05f7e080f882c29254cc8344f0366b3</cites><orcidid>0000-0002-7039-9729 ; 0000-0001-7293-8370 ; 0000-0003-2848-9138</orcidid></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://onlinelibrary.wiley.com/doi/pdf/10.1002%2Fanie.201911359$$EPDF$$P50$$Gwiley$$H</linktopdf><linktohtml>$$Uhttps://onlinelibrary.wiley.com/doi/full/10.1002%2Fanie.201911359$$EHTML$$P50$$Gwiley$$H</linktohtml><link.rule.ids>314,776,780,1411,27901,27902,45550,45551</link.rule.ids><backlink>$$Uhttps://www.ncbi.nlm.nih.gov/pubmed/31602745$$D View this record in MEDLINE/PubMed$$Hfree_for_read</backlink></links><search><creatorcontrib>Ghalei, Behnam</creatorcontrib><creatorcontrib>Wakimoto, Kazuki</creatorcontrib><creatorcontrib>Wu, Chih Yi</creatorcontrib><creatorcontrib>Isfahani, Ali Pournaghshband</creatorcontrib><creatorcontrib>Yamamoto, Takuma</creatorcontrib><creatorcontrib>Sakurai, Kento</creatorcontrib><creatorcontrib>Higuchi, Masakazu</creatorcontrib><creatorcontrib>Chang, Bor Kae</creatorcontrib><creatorcontrib>Kitagawa, Susumu</creatorcontrib><creatorcontrib>Sivaniah, Easan</creatorcontrib><title>Rational Tuning of Zirconium Metal–Organic Framework Membranes for Hydrogen Purification</title><title>Angewandte Chemie International Edition</title><addtitle>Angew Chem Int Ed Engl</addtitle><description>The effect of organic ligands on the separation performance of Zr based metal–organic framework (Zr‐MOF) membranes was investigated. A series of Zr‐MOF membranes with different ligand chemistry and functionality were synthesized by an in situ solvothermal method and a coordination modulation technique. The thin supported MOF layers (ca. 1 μm) showed the crystallographic orientation and pore structure of original MOF structures. The MOF membranes show excellent selectivity towards hydrogen owing to the molecular sieving effect when the bulkier linkers were used. The molecular simulation confirmed that the constricted pore apertures of the Zr‐MOFs which were formed by the additional benzene rings lead to the decrease in the diffusivity of larger penetrants while hydrogen was not remarkably affected. The gas mixture separation factors of the MOF membranes reached to H2/CO2=26, H2/N2=13, H2/CH4=11.
Zr‐MOF membranes for hydrogen separation have been developed and tuned. The MOF membranes have shown great selectivity towards hydrogen, which is due to the molecular sieving effect when the bulkier ligands were used to narrow down the pore apertures of the MOFs.</description><subject>Apertures</subject><subject>Benzene</subject><subject>Carbon dioxide</subject><subject>Chemical synthesis</subject><subject>Crystallography</subject><subject>Gas mixtures</subject><subject>Hydrogen</subject><subject>Ligands</subject><subject>Membranes</subject><subject>Metal-organic frameworks</subject><subject>molecular simulation</subject><subject>Organic chemistry</subject><subject>Penetrants</subject><subject>Porosity</subject><subject>Purification</subject><subject>Selectivity</subject><subject>Separation</subject><subject>Thin films</subject><subject>Zirconium</subject><issn>1433-7851</issn><issn>1521-3773</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2019</creationdate><recordtype>article</recordtype><recordid>eNqFkLtOwzAUhi0EotxWRhSJhSXF19gZEWoBqVCEYOkSOa5duSRxsRtV3XgH3pAnwaWlSCxMPpK_851zfgBOEewiCPGlbKzuYohyhAjLd8ABYhilhHOyG2tKSMoFQx1wGMI08kLAbB90CMog5pQdgNGTnFvXyCp5bhvbTBJnkpH1yjW2rZN7PZfV5_vH0E_iIJX0vaz1wvnX-FOXXjY6JMb55HY59m6im-Sx9dZY9e08BntGVkGfbN4j8NLvPV_fpoPhzd311SBVlGd5iiEtyzHJWK5FSeNajDPDMC9pLqmIl5WQGa6hgEYIrHCOGVVKEEoNJFlWkiNwsfbOvHtrdZgXtQ1KV1Vcz7WhwAQySBFFMKLnf9Cpa328fkVhTjClbEV115TyLgSvTTHztpZ-WSBYrFIvVqkX29Rjw9lG25a1Hm_xn5gjkK-Bha308h9dcfVw1_uVfwFj2o2d</recordid><startdate>20191219</startdate><enddate>20191219</enddate><creator>Ghalei, Behnam</creator><creator>Wakimoto, Kazuki</creator><creator>Wu, Chih Yi</creator><creator>Isfahani, Ali Pournaghshband</creator><creator>Yamamoto, Takuma</creator><creator>Sakurai, Kento</creator><creator>Higuchi, Masakazu</creator><creator>Chang, Bor Kae</creator><creator>Kitagawa, Susumu</creator><creator>Sivaniah, Easan</creator><general>Wiley Subscription Services, Inc</general><scope>NPM</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>7TM</scope><scope>K9.</scope><scope>7X8</scope><orcidid>https://orcid.org/0000-0002-7039-9729</orcidid><orcidid>https://orcid.org/0000-0001-7293-8370</orcidid><orcidid>https://orcid.org/0000-0003-2848-9138</orcidid></search><sort><creationdate>20191219</creationdate><title>Rational Tuning of Zirconium Metal–Organic Framework Membranes for Hydrogen Purification</title><author>Ghalei, Behnam ; Wakimoto, Kazuki ; Wu, Chih Yi ; Isfahani, Ali Pournaghshband ; Yamamoto, Takuma ; Sakurai, Kento ; Higuchi, Masakazu ; Chang, Bor Kae ; Kitagawa, Susumu ; Sivaniah, Easan</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c4769-204bbd3659e8b4027575f527b49a48019b05f7e080f882c29254cc8344f0366b3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2019</creationdate><topic>Apertures</topic><topic>Benzene</topic><topic>Carbon dioxide</topic><topic>Chemical synthesis</topic><topic>Crystallography</topic><topic>Gas mixtures</topic><topic>Hydrogen</topic><topic>Ligands</topic><topic>Membranes</topic><topic>Metal-organic frameworks</topic><topic>molecular simulation</topic><topic>Organic chemistry</topic><topic>Penetrants</topic><topic>Porosity</topic><topic>Purification</topic><topic>Selectivity</topic><topic>Separation</topic><topic>Thin films</topic><topic>Zirconium</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Ghalei, Behnam</creatorcontrib><creatorcontrib>Wakimoto, Kazuki</creatorcontrib><creatorcontrib>Wu, Chih Yi</creatorcontrib><creatorcontrib>Isfahani, Ali Pournaghshband</creatorcontrib><creatorcontrib>Yamamoto, Takuma</creatorcontrib><creatorcontrib>Sakurai, Kento</creatorcontrib><creatorcontrib>Higuchi, Masakazu</creatorcontrib><creatorcontrib>Chang, Bor Kae</creatorcontrib><creatorcontrib>Kitagawa, Susumu</creatorcontrib><creatorcontrib>Sivaniah, Easan</creatorcontrib><collection>PubMed</collection><collection>CrossRef</collection><collection>Nucleic Acids Abstracts</collection><collection>ProQuest Health & Medical Complete (Alumni)</collection><collection>MEDLINE - Academic</collection><jtitle>Angewandte Chemie International Edition</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Ghalei, Behnam</au><au>Wakimoto, Kazuki</au><au>Wu, Chih Yi</au><au>Isfahani, Ali Pournaghshband</au><au>Yamamoto, Takuma</au><au>Sakurai, Kento</au><au>Higuchi, Masakazu</au><au>Chang, Bor Kae</au><au>Kitagawa, Susumu</au><au>Sivaniah, Easan</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Rational Tuning of Zirconium Metal–Organic Framework Membranes for Hydrogen Purification</atitle><jtitle>Angewandte Chemie International Edition</jtitle><addtitle>Angew Chem Int Ed Engl</addtitle><date>2019-12-19</date><risdate>2019</risdate><volume>58</volume><issue>52</issue><spage>19034</spage><epage>19040</epage><pages>19034-19040</pages><issn>1433-7851</issn><eissn>1521-3773</eissn><abstract>The effect of organic ligands on the separation performance of Zr based metal–organic framework (Zr‐MOF) membranes was investigated. A series of Zr‐MOF membranes with different ligand chemistry and functionality were synthesized by an in situ solvothermal method and a coordination modulation technique. The thin supported MOF layers (ca. 1 μm) showed the crystallographic orientation and pore structure of original MOF structures. The MOF membranes show excellent selectivity towards hydrogen owing to the molecular sieving effect when the bulkier linkers were used. The molecular simulation confirmed that the constricted pore apertures of the Zr‐MOFs which were formed by the additional benzene rings lead to the decrease in the diffusivity of larger penetrants while hydrogen was not remarkably affected. The gas mixture separation factors of the MOF membranes reached to H2/CO2=26, H2/N2=13, H2/CH4=11.
Zr‐MOF membranes for hydrogen separation have been developed and tuned. The MOF membranes have shown great selectivity towards hydrogen, which is due to the molecular sieving effect when the bulkier ligands were used to narrow down the pore apertures of the MOFs.</abstract><cop>Germany</cop><pub>Wiley Subscription Services, Inc</pub><pmid>31602745</pmid><doi>10.1002/anie.201911359</doi><tpages>7</tpages><edition>International ed. in English</edition><orcidid>https://orcid.org/0000-0002-7039-9729</orcidid><orcidid>https://orcid.org/0000-0001-7293-8370</orcidid><orcidid>https://orcid.org/0000-0003-2848-9138</orcidid></addata></record> |
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| subjects | Apertures Benzene Carbon dioxide Chemical synthesis Crystallography Gas mixtures Hydrogen Ligands Membranes Metal-organic frameworks molecular simulation Organic chemistry Penetrants Porosity Purification Selectivity Separation Thin films Zirconium |
| title | Rational Tuning of Zirconium Metal–Organic Framework Membranes for Hydrogen Purification |
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