Controllable syntheses of B/N anionic aminoborane chain complexes by the reaction of NH3BH3 with NaH and the mechanistic study
B/N anionic aminoborane linear or branched chain complexes, [BH3(NH2BH2)nH]− (n = 1, 2, and 3) and [BH(NH2BH3)3]−, have been synthesized through the controlled reactions of ammonia borane (NH3BH3) with NaH by adjusting the reactant ratios and reaction temperatures. The possible reaction mechanisms w...
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| Veröffentlicht in: | Dalton transactions : an international journal of inorganic chemistry 2019, Vol.48 (40), p.14984-14988 |
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| container_end_page | 14988 |
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| container_issue | 40 |
| container_start_page | 14984 |
| container_title | Dalton transactions : an international journal of inorganic chemistry |
| container_volume | 48 |
| creator | Xi-Meng, Chen Wang, Jin Si-Cong, Liu Zhang, Jie Wei, Donghui Chen, Xuenian |
| description | B/N anionic aminoborane linear or branched chain complexes, [BH3(NH2BH2)nH]− (n = 1, 2, and 3) and [BH(NH2BH3)3]−, have been synthesized through the controlled reactions of ammonia borane (NH3BH3) with NaH by adjusting the reactant ratios and reaction temperatures. The possible reaction mechanisms were elucidated based on experimental and theoretical studies. |
| doi_str_mv | 10.1039/c9dt02289a |
| format | Article |
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The possible reaction mechanisms were elucidated based on experimental and theoretical studies.</description><subject>Ammonia</subject><subject>Chain branching</subject><subject>Chains</subject><subject>Infrared spectroscopy</subject><subject>NMR</subject><subject>Nuclear magnetic resonance</subject><subject>Reaction mechanisms</subject><subject>Stability</subject><issn>1477-9226</issn><issn>1477-9234</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2019</creationdate><recordtype>article</recordtype><recordid>eNpdz7tOwzAUBmALgUS5LDyBJRaWUN_iy0grIEhVWWCuHPdETZXYJXYEXXh2XEAMTOcM3__rHISuKLmlhJupM-tEGNPGHqEJFUoVhnFx_LczeYrOYtySjEjJJuhzHnwaQtfZugMc9z5tIELEocGz6RJb3wbfOmz71oc6DNYDdhvbeuxCv-vgI9N6j3MID2BdyvoQXVZ8VnH83qYNXtoq16y_TQ857NuYcmVM43p_gU4a20W4_J3n6PXh_mVeFYvnx6f53aLYMSpTUZcauHW0ERJoKTWzWpJacakazSWtSyeYpBYEd6J0RjcNZSRLq4jRShF-jm5-endDeBshplXfRgf5bQ9hjCvGCROq5Exkev2PbsM4-HzdQQkjGNeGfwHLLm09</recordid><startdate>2019</startdate><enddate>2019</enddate><creator>Xi-Meng, Chen</creator><creator>Wang, Jin</creator><creator>Si-Cong, Liu</creator><creator>Zhang, Jie</creator><creator>Wei, Donghui</creator><creator>Chen, Xuenian</creator><general>Royal Society of Chemistry</general><scope>7SR</scope><scope>7U5</scope><scope>8BQ</scope><scope>8FD</scope><scope>JG9</scope><scope>L7M</scope><scope>7X8</scope></search><sort><creationdate>2019</creationdate><title>Controllable syntheses of B/N anionic aminoborane chain complexes by the reaction of NH3BH3 with NaH and the mechanistic study</title><author>Xi-Meng, Chen ; Wang, Jin ; Si-Cong, Liu ; Zhang, Jie ; Wei, Donghui ; Chen, Xuenian</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-p216t-b58e3ac1f46e15682a860b7367f8361b5c4261ae43c45c98ff120e15a70987703</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2019</creationdate><topic>Ammonia</topic><topic>Chain branching</topic><topic>Chains</topic><topic>Infrared spectroscopy</topic><topic>NMR</topic><topic>Nuclear magnetic resonance</topic><topic>Reaction mechanisms</topic><topic>Stability</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Xi-Meng, Chen</creatorcontrib><creatorcontrib>Wang, Jin</creatorcontrib><creatorcontrib>Si-Cong, Liu</creatorcontrib><creatorcontrib>Zhang, Jie</creatorcontrib><creatorcontrib>Wei, Donghui</creatorcontrib><creatorcontrib>Chen, Xuenian</creatorcontrib><collection>Engineered Materials Abstracts</collection><collection>Solid State and Superconductivity Abstracts</collection><collection>METADEX</collection><collection>Technology Research Database</collection><collection>Materials Research Database</collection><collection>Advanced Technologies Database with Aerospace</collection><collection>MEDLINE - Academic</collection><jtitle>Dalton transactions : an international journal of inorganic chemistry</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Xi-Meng, Chen</au><au>Wang, Jin</au><au>Si-Cong, Liu</au><au>Zhang, Jie</au><au>Wei, Donghui</au><au>Chen, Xuenian</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Controllable syntheses of B/N anionic aminoborane chain complexes by the reaction of NH3BH3 with NaH and the mechanistic study</atitle><jtitle>Dalton transactions : an international journal of inorganic chemistry</jtitle><date>2019</date><risdate>2019</risdate><volume>48</volume><issue>40</issue><spage>14984</spage><epage>14988</epage><pages>14984-14988</pages><issn>1477-9226</issn><eissn>1477-9234</eissn><abstract>B/N anionic aminoborane linear or branched chain complexes, [BH3(NH2BH2)nH]− (n = 1, 2, and 3) and [BH(NH2BH3)3]−, have been synthesized through the controlled reactions of ammonia borane (NH3BH3) with NaH by adjusting the reactant ratios and reaction temperatures. 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| fulltext | fulltext |
| identifier | ISSN: 1477-9226 |
| ispartof | Dalton transactions : an international journal of inorganic chemistry, 2019, Vol.48 (40), p.14984-14988 |
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| language | eng |
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| source | Royal Society Of Chemistry Journals 2008-; Alma/SFX Local Collection |
| subjects | Ammonia Chain branching Chains Infrared spectroscopy NMR Nuclear magnetic resonance Reaction mechanisms Stability |
| title | Controllable syntheses of B/N anionic aminoborane chain complexes by the reaction of NH3BH3 with NaH and the mechanistic study |
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