Experimental and Theoretical Studies on the Aqueous Solvation and Reactivity of SmCl2 and Comparison with SmBr2 and SmI2

Water addition to Sm­(II) has been shown to increase reactivity for both SmI2 and SmBr2. Previous work in our groups has demonstrated that this increase in reactivity can be attributed to coordination induced bond weakening enabling substrate reduction through proton-coupled electron transfer. The p...

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Veröffentlicht in:	Inorganic chemistry 2019-10, Vol.58 (20), p.13927-13932
Hauptverfasser:	Ramírez-Solís, Alejandro, Bartulovich, Caroline O, León-Pimentel, César Iván, Saint-Martin, Humberto, Anderson, William R
Format:	Artikel
Sprache:	eng
Online-Zugang:	Volltext
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