Ca10Na10[Te9O42](H2O): a hydrothermally synthesized quaternary tellurium(vi) oxide containing edge-sharing octahedral trimers
A new tellurium(vi) oxycompound, Ca10Na10[Te9O42](H2O), was synthesized by a high-temperature, high-pressure hydrothermal reaction at 550 °C, its structure determined by single-crystal X-ray diffraction, and further characterized by energy dispersive, infrared, and X-ray photoelectron spectroscopy....
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| Veröffentlicht in: | Dalton transactions : an international journal of inorganic chemistry 2019, Vol.48 (40), p.15231-15235 |
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| container_title | Dalton transactions : an international journal of inorganic chemistry |
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| creator | Zhang, Li-Yun Lii, Kwang-Hwa |
| description | A new tellurium(vi) oxycompound, Ca10Na10[Te9O42](H2O), was synthesized by a high-temperature, high-pressure hydrothermal reaction at 550 °C, its structure determined by single-crystal X-ray diffraction, and further characterized by energy dispersive, infrared, and X-ray photoelectron spectroscopy. The compound crystallizes in the centrosymmetric trigonal space group R3c (no. 167) with a = 9.743(2), c = 66.337(13) Å, and Z = 6. The structure consists of discrete linear edge-sharing octahedral trimers with the composition Te3O1410−, which is a new type of finite Te–O oligomer with Te6+ only. The large complex anions form a hexagonal close-packed lattice with the octahedral and tetrahedral interstices being filled with Ca2+ and Na+ cations and water molecules. The octahedral trimers in every other h.c.p. layer rotate around the 31 screw axis for 120°; therefore the unit cell has a very long c axis. This work is one of the few examples of the synthesis of metal tellurates by supercritical hydrothermal techniques. |
| doi_str_mv | 10.1039/c9dt03521d |
| format | Article |
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The compound crystallizes in the centrosymmetric trigonal space group R3c (no. 167) with a = 9.743(2), c = 66.337(13) Å, and Z = 6. The structure consists of discrete linear edge-sharing octahedral trimers with the composition Te3O1410−, which is a new type of finite Te–O oligomer with Te6+ only. The large complex anions form a hexagonal close-packed lattice with the octahedral and tetrahedral interstices being filled with Ca2+ and Na+ cations and water molecules. The octahedral trimers in every other h.c.p. layer rotate around the 31 screw axis for 120°; therefore the unit cell has a very long c axis. This work is one of the few examples of the synthesis of metal tellurates by supercritical hydrothermal techniques.</description><identifier>ISSN: 1477-9226</identifier><identifier>EISSN: 1477-9234</identifier><identifier>DOI: 10.1039/c9dt03521d</identifier><language>eng</language><publisher>Cambridge: Royal Society of Chemistry</publisher><subject>Calcium ions ; Close packed lattices ; Crystal structure ; Crystallography ; Crystals ; Format ; Hexagonal lattice ; High temperature ; Hydrothermal reactions ; Interstices ; Photoelectrons ; Single crystals ; Spectrum analysis ; Tellurium ; Trimers ; Unit cell ; Water chemistry</subject><ispartof>Dalton transactions : an international journal of inorganic chemistry, 2019, Vol.48 (40), p.15231-15235</ispartof><rights>Copyright Royal Society of Chemistry 2019</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><link.rule.ids>314,776,780,4009,27902,27903,27904</link.rule.ids></links><search><creatorcontrib>Zhang, Li-Yun</creatorcontrib><creatorcontrib>Lii, Kwang-Hwa</creatorcontrib><title>Ca10Na10[Te9O42](H2O): a hydrothermally synthesized quaternary tellurium(vi) oxide containing edge-sharing octahedral trimers</title><title>Dalton transactions : an international journal of inorganic chemistry</title><description>A new tellurium(vi) oxycompound, Ca10Na10[Te9O42](H2O), was synthesized by a high-temperature, high-pressure hydrothermal reaction at 550 °C, its structure determined by single-crystal X-ray diffraction, and further characterized by energy dispersive, infrared, and X-ray photoelectron spectroscopy. The compound crystallizes in the centrosymmetric trigonal space group R3c (no. 167) with a = 9.743(2), c = 66.337(13) Å, and Z = 6. The structure consists of discrete linear edge-sharing octahedral trimers with the composition Te3O1410−, which is a new type of finite Te–O oligomer with Te6+ only. The large complex anions form a hexagonal close-packed lattice with the octahedral and tetrahedral interstices being filled with Ca2+ and Na+ cations and water molecules. The octahedral trimers in every other h.c.p. layer rotate around the 31 screw axis for 120°; therefore the unit cell has a very long c axis. This work is one of the few examples of the synthesis of metal tellurates by supercritical hydrothermal techniques.</description><subject>Calcium ions</subject><subject>Close packed lattices</subject><subject>Crystal structure</subject><subject>Crystallography</subject><subject>Crystals</subject><subject>Format</subject><subject>Hexagonal lattice</subject><subject>High temperature</subject><subject>Hydrothermal reactions</subject><subject>Interstices</subject><subject>Photoelectrons</subject><subject>Single crystals</subject><subject>Spectrum analysis</subject><subject>Tellurium</subject><subject>Trimers</subject><subject>Unit cell</subject><subject>Water chemistry</subject><issn>1477-9226</issn><issn>1477-9234</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2019</creationdate><recordtype>article</recordtype><recordid>eNpdkEtLw0AUhQdRsFY3_oIBN-0iOq9kEndS1ArFbupKpExmbpopebQzEzGC_934wIWLy70HPg7nXITOKbmkhGdXOjOB8JhRc4BGVEgZZYyLw7-bJcfoxPstIYyRmI3Qx0xR8jjM8wqypWAvkzlbTq-xwmVvXBtKcLWqqh77vhmEt-9g8L5TAVyjXI8DVFXnbFdPXu0Ut2_WANZtE5RtbLPBYDYQ-VK5L9HqoEowTlU4OFuD86foqFCVh7PfPUZPd7er2TxaLO8fZjeLaMdoEqJCQFZIzdMiZjlQkkkVyzweChDQBdCccqIyWmgtpVRUGjH8QKQyN0okCSv4GE1-fHeu3Xfgw7q2Xg_RVQNt59eME0LTNOVkQC_-odu2G7pW35TIBIllyj8BURBuFg</recordid><startdate>2019</startdate><enddate>2019</enddate><creator>Zhang, Li-Yun</creator><creator>Lii, Kwang-Hwa</creator><general>Royal Society of Chemistry</general><scope>7SR</scope><scope>7U5</scope><scope>8BQ</scope><scope>8FD</scope><scope>JG9</scope><scope>L7M</scope><scope>7X8</scope></search><sort><creationdate>2019</creationdate><title>Ca10Na10[Te9O42](H2O): a hydrothermally synthesized quaternary tellurium(vi) oxide containing edge-sharing octahedral trimers</title><author>Zhang, Li-Yun ; Lii, Kwang-Hwa</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-p216t-f4e9f7c38f52be1097a57b50520ecfe1b130a91fcc777a17d4035487bda4662f3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2019</creationdate><topic>Calcium ions</topic><topic>Close packed lattices</topic><topic>Crystal structure</topic><topic>Crystallography</topic><topic>Crystals</topic><topic>Format</topic><topic>Hexagonal lattice</topic><topic>High temperature</topic><topic>Hydrothermal reactions</topic><topic>Interstices</topic><topic>Photoelectrons</topic><topic>Single crystals</topic><topic>Spectrum analysis</topic><topic>Tellurium</topic><topic>Trimers</topic><topic>Unit cell</topic><topic>Water chemistry</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Zhang, Li-Yun</creatorcontrib><creatorcontrib>Lii, Kwang-Hwa</creatorcontrib><collection>Engineered Materials Abstracts</collection><collection>Solid State and Superconductivity Abstracts</collection><collection>METADEX</collection><collection>Technology Research Database</collection><collection>Materials Research Database</collection><collection>Advanced Technologies Database with Aerospace</collection><collection>MEDLINE - Academic</collection><jtitle>Dalton transactions : an international journal of inorganic chemistry</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Zhang, Li-Yun</au><au>Lii, Kwang-Hwa</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Ca10Na10[Te9O42](H2O): a hydrothermally synthesized quaternary tellurium(vi) oxide containing edge-sharing octahedral trimers</atitle><jtitle>Dalton transactions : an international journal of inorganic chemistry</jtitle><date>2019</date><risdate>2019</risdate><volume>48</volume><issue>40</issue><spage>15231</spage><epage>15235</epage><pages>15231-15235</pages><issn>1477-9226</issn><eissn>1477-9234</eissn><abstract>A new tellurium(vi) oxycompound, Ca10Na10[Te9O42](H2O), was synthesized by a high-temperature, high-pressure hydrothermal reaction at 550 °C, its structure determined by single-crystal X-ray diffraction, and further characterized by energy dispersive, infrared, and X-ray photoelectron spectroscopy. The compound crystallizes in the centrosymmetric trigonal space group R3c (no. 167) with a = 9.743(2), c = 66.337(13) Å, and Z = 6. The structure consists of discrete linear edge-sharing octahedral trimers with the composition Te3O1410−, which is a new type of finite Te–O oligomer with Te6+ only. The large complex anions form a hexagonal close-packed lattice with the octahedral and tetrahedral interstices being filled with Ca2+ and Na+ cations and water molecules. The octahedral trimers in every other h.c.p. layer rotate around the 31 screw axis for 120°; therefore the unit cell has a very long c axis. This work is one of the few examples of the synthesis of metal tellurates by supercritical hydrothermal techniques.</abstract><cop>Cambridge</cop><pub>Royal Society of Chemistry</pub><doi>10.1039/c9dt03521d</doi><tpages>5</tpages></addata></record> |
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| identifier | ISSN: 1477-9226 |
| ispartof | Dalton transactions : an international journal of inorganic chemistry, 2019, Vol.48 (40), p.15231-15235 |
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| source | Royal Society Of Chemistry Journals 2008-; Alma/SFX Local Collection |
| subjects | Calcium ions Close packed lattices Crystal structure Crystallography Crystals Format Hexagonal lattice High temperature Hydrothermal reactions Interstices Photoelectrons Single crystals Spectrum analysis Tellurium Trimers Unit cell Water chemistry |
| title | Ca10Na10[Te9O42](H2O): a hydrothermally synthesized quaternary tellurium(vi) oxide containing edge-sharing octahedral trimers |
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