Self‐Assembly of a Phosphate‐Centered Polyoxo‐Titanium Cluster: Discovery of the Heteroatom Keggin Family

Over the past 200 years, the most famous and important heteroatom Keggin architecture in polyoxometalates has only been synthesized with Mo, W, V, or Nb. Now, the self‐assembly of two phosphate (PO43−)‐centered polyoxo‐titanium clusters (PTCs) is presented, PTi16 and PTi12, which display classic het...

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Veröffentlicht in:	Angewandte Chemie International Edition 2019-11, Vol.58 (48), p.17260-17264
Hauptverfasser:	Li, Ning, Liu, Jiang, Liu, Jing‐Jing, Dong, Long‐Zhang, Li, Shun‐Li, Dong, Bao‐Xia, Kan, Yu‐He, Lan, Ya‐Qian
Format:	Artikel
Sprache:	eng
Schlagworte:	Assembly Carbon dioxide CO2 photoreduction Keggin structures Molybdenum Organic chemistry Phosphates polyoxo-titanium cluster Polyoxometallates Titanium
Online-Zugang:	Volltext
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