Electronic Structure, Vibrational Spectra, and Spin-Crossover Properties of Vacuum-Evaporable Iron(II) Bis(dihydrobis(pyrazolyl)borate) Complexes with Diimine Coligands. Origin of Giant Raman Features

The vibrational properties of spin-crossover complexes [Fe­(H2B­(pz)2)2(L)] (pz = pyrazole) containing L = 2,2′-bipyridine (bipy) and 1,10-phenanthroline (phen) ligands are investigated by temperature-dependent infrared and Raman spectroscopy. For comparison, the analogous cobalt­(II) complexes [Co­...

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Veröffentlicht in:	Inorganic chemistry 2019-10, Vol.58 (19), p.12873-12887
Hauptverfasser:	Ossinger, Sascha, Naggert, Holger, Bill, Eckhard, Näther, Christian, Tuczek, Felix
Format:	Artikel
Sprache:	eng
Online-Zugang:	Volltext
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