Diferrocenylmercury diphosphine diastereomers with unique geometries: trans-chelation at Pd(ii) with short Hg(ii)Pd(ii) contacts

Diphosphine chelate ligands are essential in many catalytic processes with both the electronic structure and bite angle having a dramatic influence on the coordination behavior and catalytic performance. The synthesis of a new class of diferrocenylmercury-supported diphosphine chelate ligands was ac...

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Veröffentlicht in:	Dalton transactions : an international journal of inorganic chemistry 2019-09, Vol.48 (35), p.13430-13439
Hauptverfasser:	Tagne Kuate, Alain C, Lalancette, Roger A, Bannenberg, Thomas, Tamm, Matthias, Jäkle, Frieder
Format:	Artikel
Sprache:	eng
Schlagworte:	Angles (geometry) Catalysis Chelates Chelation Chemical synthesis Coordination compounds Critical point Crystallography Electronic structure Ligands Mercury (metal) Mercury compounds Single crystals Transition metals
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