A luminescent edge-interlocked prismatic heteroleptic metallocage assembled through a ligand replacement reaction
A luminescent edge-interlocked heteroleptic metallocage based on Cu 3 (pyrazolate) 3 was prepared through a ligand replacement reaction from a homoleptic metallocage and a new ligand. Its structure was confirmed by XRD and MALDI-TOF mass spectrometry. Theoretical calculations revealed the new ligand...
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| Veröffentlicht in: | Chemical communications (Cambridge, England) England), 2019-10, Vol.55 (8), p.11992-11995 |
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| container_end_page | 11995 |
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| container_issue | 8 |
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| container_title | Chemical communications (Cambridge, England) |
| container_volume | 55 |
| creator | Zhan, Shun-Ze Li, Jing-Hong Zhang, Guo-Hui Liu, Xiao-Wei Li, Mian Zheng, Ji Ng, Seik Weng Li, Dan |
| description | A luminescent edge-interlocked heteroleptic metallocage based on Cu
3
(pyrazolate)
3
was prepared through a ligand replacement reaction from a homoleptic metallocage and a new ligand. Its structure was confirmed by XRD and MALDI-TOF mass spectrometry. Theoretical calculations revealed the new ligand was evidently responsible for the bathochromic shift of the optimal excitation. This work provides a heteroleptic strategy to regulate the interlocking fashion and photophysical mechanism of metallocages based on Cu
3
(pyrazolate)
3
.
A luminescent edge-interlocked heteroleptic metallocages based on Cu
3
(pyrazolate)
3
was prepared through a ligand replacement reaction from a homoleptic metallocage and a new ligand. |
| doi_str_mv | 10.1039/c9cc05236d |
| format | Article |
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3
(pyrazolate)
3
was prepared through a ligand replacement reaction from a homoleptic metallocage and a new ligand. Its structure was confirmed by XRD and MALDI-TOF mass spectrometry. Theoretical calculations revealed the new ligand was evidently responsible for the bathochromic shift of the optimal excitation. This work provides a heteroleptic strategy to regulate the interlocking fashion and photophysical mechanism of metallocages based on Cu
3
(pyrazolate)
3
.
A luminescent edge-interlocked heteroleptic metallocages based on Cu
3
(pyrazolate)
3
was prepared through a ligand replacement reaction from a homoleptic metallocage and a new ligand.</description><identifier>ISSN: 1359-7345</identifier><identifier>EISSN: 1364-548X</identifier><identifier>DOI: 10.1039/c9cc05236d</identifier><identifier>PMID: 31498358</identifier><language>eng</language><publisher>England: Royal Society of Chemistry</publisher><subject>Crystallography ; Ligands ; Mass spectrometry ; Mathematical analysis</subject><ispartof>Chemical communications (Cambridge, England), 2019-10, Vol.55 (8), p.11992-11995</ispartof><rights>Copyright Royal Society of Chemistry 2019</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c337t-458a651e57294c25ddfcb12a1d7c2459d03d74965ee73285a10543737739aaa83</citedby><cites>FETCH-LOGICAL-c337t-458a651e57294c25ddfcb12a1d7c2459d03d74965ee73285a10543737739aaa83</cites><orcidid>0000-0002-4936-4599 ; 0000-0002-4937-7218 ; 0000-0002-9821-8942 ; 0000-0002-9152-6192 ; 0000-0003-0877-6551 ; 0000-0003-1159-592X ; 0000-0003-1293-3636</orcidid></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><link.rule.ids>314,776,780,27903,27904</link.rule.ids><backlink>$$Uhttps://www.ncbi.nlm.nih.gov/pubmed/31498358$$D View this record in MEDLINE/PubMed$$Hfree_for_read</backlink></links><search><creatorcontrib>Zhan, Shun-Ze</creatorcontrib><creatorcontrib>Li, Jing-Hong</creatorcontrib><creatorcontrib>Zhang, Guo-Hui</creatorcontrib><creatorcontrib>Liu, Xiao-Wei</creatorcontrib><creatorcontrib>Li, Mian</creatorcontrib><creatorcontrib>Zheng, Ji</creatorcontrib><creatorcontrib>Ng, Seik Weng</creatorcontrib><creatorcontrib>Li, Dan</creatorcontrib><title>A luminescent edge-interlocked prismatic heteroleptic metallocage assembled through a ligand replacement reaction</title><title>Chemical communications (Cambridge, England)</title><addtitle>Chem Commun (Camb)</addtitle><description>A luminescent edge-interlocked heteroleptic metallocage based on Cu
3
(pyrazolate)
3
was prepared through a ligand replacement reaction from a homoleptic metallocage and a new ligand. Its structure was confirmed by XRD and MALDI-TOF mass spectrometry. Theoretical calculations revealed the new ligand was evidently responsible for the bathochromic shift of the optimal excitation. This work provides a heteroleptic strategy to regulate the interlocking fashion and photophysical mechanism of metallocages based on Cu
3
(pyrazolate)
3
.
A luminescent edge-interlocked heteroleptic metallocages based on Cu
3
(pyrazolate)
3
was prepared through a ligand replacement reaction from a homoleptic metallocage and a new ligand.</description><subject>Crystallography</subject><subject>Ligands</subject><subject>Mass spectrometry</subject><subject>Mathematical analysis</subject><issn>1359-7345</issn><issn>1364-548X</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2019</creationdate><recordtype>article</recordtype><recordid>eNpd0ctr3DAQB2BRUppXL703GHIJBTeSRrKs4-I-IdBLC7mZWWl214lsbyT7kP--cjZNoLro9fFDmmHsg-CfBQd77axzXEuo_Bt2IqBSpVb17dGy1rY0oPQxO03pjuchdP2OHYNQtgZdn7CHVRHmvhsoORqmgvyWym6YKIbR3ZMv9rFLPU6dK3aUT8dA-2XT04QhE9xSgSlRvw4ZT7s4zttdgUXotjj4ItI-oKN-iY6EburG4Zy93WBI9P55PmN_vn393fwob359_9msbkoHYKZS6RorLUgbaZWT2vuNWwuJwhsnlbaegzfKVprIgKw1Cq4VGDAGLCLWcMauDrn7OD7MlKa27_InQ8CBxjm1UtZGiwoqyPTyP3o3znHIr2slcF5xI9WiPh2Ui2NKkTZtLk6P8bEVvF0a0Ta2aZ4a8SXji-fIed2Tf6H_Kp_BxwOIyb3cvnYS_gIetI2o</recordid><startdate>20191003</startdate><enddate>20191003</enddate><creator>Zhan, Shun-Ze</creator><creator>Li, Jing-Hong</creator><creator>Zhang, Guo-Hui</creator><creator>Liu, Xiao-Wei</creator><creator>Li, Mian</creator><creator>Zheng, Ji</creator><creator>Ng, Seik Weng</creator><creator>Li, Dan</creator><general>Royal Society of Chemistry</general><scope>NPM</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>7SR</scope><scope>7U5</scope><scope>8BQ</scope><scope>8FD</scope><scope>JG9</scope><scope>L7M</scope><scope>7X8</scope><orcidid>https://orcid.org/0000-0002-4936-4599</orcidid><orcidid>https://orcid.org/0000-0002-4937-7218</orcidid><orcidid>https://orcid.org/0000-0002-9821-8942</orcidid><orcidid>https://orcid.org/0000-0002-9152-6192</orcidid><orcidid>https://orcid.org/0000-0003-0877-6551</orcidid><orcidid>https://orcid.org/0000-0003-1159-592X</orcidid><orcidid>https://orcid.org/0000-0003-1293-3636</orcidid></search><sort><creationdate>20191003</creationdate><title>A luminescent edge-interlocked prismatic heteroleptic metallocage assembled through a ligand replacement reaction</title><author>Zhan, Shun-Ze ; Li, Jing-Hong ; Zhang, Guo-Hui ; Liu, Xiao-Wei ; Li, Mian ; Zheng, Ji ; Ng, Seik Weng ; Li, Dan</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c337t-458a651e57294c25ddfcb12a1d7c2459d03d74965ee73285a10543737739aaa83</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2019</creationdate><topic>Crystallography</topic><topic>Ligands</topic><topic>Mass spectrometry</topic><topic>Mathematical analysis</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Zhan, Shun-Ze</creatorcontrib><creatorcontrib>Li, Jing-Hong</creatorcontrib><creatorcontrib>Zhang, Guo-Hui</creatorcontrib><creatorcontrib>Liu, Xiao-Wei</creatorcontrib><creatorcontrib>Li, Mian</creatorcontrib><creatorcontrib>Zheng, Ji</creatorcontrib><creatorcontrib>Ng, Seik Weng</creatorcontrib><creatorcontrib>Li, Dan</creatorcontrib><collection>PubMed</collection><collection>CrossRef</collection><collection>Engineered Materials Abstracts</collection><collection>Solid State and Superconductivity Abstracts</collection><collection>METADEX</collection><collection>Technology Research Database</collection><collection>Materials Research Database</collection><collection>Advanced Technologies Database with Aerospace</collection><collection>MEDLINE - Academic</collection><jtitle>Chemical communications (Cambridge, England)</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Zhan, Shun-Ze</au><au>Li, Jing-Hong</au><au>Zhang, Guo-Hui</au><au>Liu, Xiao-Wei</au><au>Li, Mian</au><au>Zheng, Ji</au><au>Ng, Seik Weng</au><au>Li, Dan</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>A luminescent edge-interlocked prismatic heteroleptic metallocage assembled through a ligand replacement reaction</atitle><jtitle>Chemical communications (Cambridge, England)</jtitle><addtitle>Chem Commun (Camb)</addtitle><date>2019-10-03</date><risdate>2019</risdate><volume>55</volume><issue>8</issue><spage>11992</spage><epage>11995</epage><pages>11992-11995</pages><issn>1359-7345</issn><eissn>1364-548X</eissn><abstract>A luminescent edge-interlocked heteroleptic metallocage based on Cu
3
(pyrazolate)
3
was prepared through a ligand replacement reaction from a homoleptic metallocage and a new ligand. Its structure was confirmed by XRD and MALDI-TOF mass spectrometry. Theoretical calculations revealed the new ligand was evidently responsible for the bathochromic shift of the optimal excitation. This work provides a heteroleptic strategy to regulate the interlocking fashion and photophysical mechanism of metallocages based on Cu
3
(pyrazolate)
3
.
A luminescent edge-interlocked heteroleptic metallocages based on Cu
3
(pyrazolate)
3
was prepared through a ligand replacement reaction from a homoleptic metallocage and a new ligand.</abstract><cop>England</cop><pub>Royal Society of Chemistry</pub><pmid>31498358</pmid><doi>10.1039/c9cc05236d</doi><tpages>4</tpages><orcidid>https://orcid.org/0000-0002-4936-4599</orcidid><orcidid>https://orcid.org/0000-0002-4937-7218</orcidid><orcidid>https://orcid.org/0000-0002-9821-8942</orcidid><orcidid>https://orcid.org/0000-0002-9152-6192</orcidid><orcidid>https://orcid.org/0000-0003-0877-6551</orcidid><orcidid>https://orcid.org/0000-0003-1159-592X</orcidid><orcidid>https://orcid.org/0000-0003-1293-3636</orcidid></addata></record> |
| fulltext | fulltext |
| identifier | ISSN: 1359-7345 |
| ispartof | Chemical communications (Cambridge, England), 2019-10, Vol.55 (8), p.11992-11995 |
| issn | 1359-7345 1364-548X |
| language | eng |
| recordid | cdi_proquest_miscellaneous_2287516363 |
| source | Royal Society Of Chemistry Journals 2008-; Alma/SFX Local Collection |
| subjects | Crystallography Ligands Mass spectrometry Mathematical analysis |
| title | A luminescent edge-interlocked prismatic heteroleptic metallocage assembled through a ligand replacement reaction |
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