Metal–Single-Molecule–Semiconductor Junctions Formed by a Radical Reaction Bridging Gold and Silicon Electrodes

Here we report molecular films terminated with diazonium salts moieties at both ends which enables single-molecule contacts between gold and silicon electrodes at open circuit via a radical reaction. We show that the kinetics of film grafting is crystal-facet dependent, being more favorable on ⟨111⟩...

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Veröffentlicht in:	Journal of the American Chemical Society 2019-09, Vol.141 (37), p.14788-14797
Hauptverfasser:	Peiris, Chandramalika R, Vogel, Yan B, Le Brun, Anton P, Aragonès, Albert C, Coote, Michelle L, Díez-Pérez, Ismael, Ciampi, Simone, Darwish, Nadim
Format:	Artikel
Sprache:	eng
Online-Zugang:	Volltext
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