An unexpected rhenium(IV)-rhenium(VII) salt: Co(NH3)63ReVIIO4ReIVF64·6H2O

An unexpected rhenium(IV)-rhenium(VII) salt: Co(NH3)63ReVIIO4ReIVF64·6H2O

The title hydrated salt, tris-[hexa-amminecobalt(III)] tetraoxidorhenate(VII) tetra-kis-[hexa-fluorido-rhenate(IV)] hexa-hydrate, arose unexpectedly due to possible contamination of the K2ReF6 starting material with KReO4. It consists of octa-hedral [Co(NH3)6]3+ cation (Co1 site symmetry 1), tetra-h...

Ausführliche Beschreibung

Gespeichert in:
Bibliographische Detailangaben
Veröffentlicht in:Acta crystallographica. Section E, Crystallographic communications Crystallographic communications, 2019-08, Vol.75 (Pt 8), p.1158
Hauptverfasser: Louis-Jean, James, Mariappan Balasekaran, Samundeeswari, Hagenbach, Adelheid, Poineau, Frederic
Format: Artikel
Sprache:eng
Online-Zugang:Volltext
Tags: Tag hinzufügen
Keine Tags, Fügen Sie den ersten Tag hinzu!
container_end_page
container_issue Pt 8
container_start_page 1158
container_title Acta crystallographica. Section E, Crystallographic communications
container_volume 75
creator Louis-Jean, James
Mariappan Balasekaran, Samundeeswari
Hagenbach, Adelheid
Poineau, Frederic
description The title hydrated salt, tris-[hexa-amminecobalt(III)] tetraoxidorhenate(VII) tetra-kis-[hexa-fluorido-rhenate(IV)] hexa-hydrate, arose unexpectedly due to possible contamination of the K2ReF6 starting material with KReO4. It consists of octa-hedral [Co(NH3)6]3+ cation (Co1 site symmetry 1), tetra-hedral [ReVIIO4]- anions (Re site symmetry 1) and octa-hedral [ReIVF6]2- anions (Re site symmetries 1and ). The [ReF6]2- octa-hedral anions (mean Re-F = 1.834 Å), [Co(NH3)6]3+ octa-hedral cations (mean Co-N = 1.962 Å), and the [ReO4]- tetra-hedral anion (mean Re-O = 1.719 Å) are slightly distorted. A network of N-H⋯F hydrogen bonds consolidates the structure. The crystal studied was refined as a two-component twin.The title hydrated salt, tris-[hexa-amminecobalt(III)] tetraoxidorhenate(VII) tetra-kis-[hexa-fluorido-rhenate(IV)] hexa-hydrate, arose unexpectedly due to possible contamination of the K2ReF6 starting material with KReO4. It consists of octa-hedral [Co(NH3)6]3+ cation (Co1 site symmetry 1), tetra-hedral [ReVIIO4]- anions (Re site symmetry 1) and octa-hedral [ReIVF6]2- anions (Re site symmetries 1and ). The [ReF6]2- octa-hedral anions (mean Re-F = 1.834 Å), [Co(NH3)6]3+ octa-hedral cations (mean Co-N = 1.962 Å), and the [ReO4]- tetra-hedral anion (mean Re-O = 1.719 Å) are slightly distorted. A network of N-H⋯F hydrogen bonds consolidates the structure. The crystal studied was refined as a two-component twin.
doi_str_mv 10.1107/S2056989019009757
format Article
fullrecord <record><control><sourceid>proquest</sourceid><recordid>TN_cdi_proquest_miscellaneous_2275262230</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><sourcerecordid>2275262230</sourcerecordid><originalsourceid>FETCH-proquest_miscellaneous_22752622303</originalsourceid><addsrcrecordid>eNqVyrEKwjAUheEgCor6AG4d26F6kzSpdRNRGgcLVbpK0SsqbVpNC76Zu0-mgoKr0_n5OIQMKAwpBX-0ZiBkMA6ABgCBL_wG6bzJfVvzp9ukb8wZAKgnuBSsQ5ZTbdUabyXuKtxb1yPqU53bKnHcbydKOZZJs2pizQp7FXJH8hhfGnkxqmQhvcddhizqkdYhzQz2P9sl9mK-mYVueS0uNZpqm5_MDrMs1VjUZsuYL5hkjAP_4_oEJo9Euw</addsrcrecordid><sourcetype>Aggregation Database</sourcetype><iscdi>true</iscdi><recordtype>article</recordtype><pqid>2275262230</pqid></control><display><type>article</type><title>An unexpected rhenium(IV)-rhenium(VII) salt: Co(NH3)63ReVIIO4ReIVF64·6H2O</title><source>DOAJ Directory of Open Access Journals</source><source>PubMed Central</source><source>Free Full-Text Journals in Chemistry</source><source>PubMed Central Open Access</source><creator>Louis-Jean, James ; Mariappan Balasekaran, Samundeeswari ; Hagenbach, Adelheid ; Poineau, Frederic</creator><creatorcontrib>Louis-Jean, James ; Mariappan Balasekaran, Samundeeswari ; Hagenbach, Adelheid ; Poineau, Frederic</creatorcontrib><description>The title hydrated salt, tris-[hexa-amminecobalt(III)] tetraoxidorhenate(VII) tetra-kis-[hexa-fluorido-rhenate(IV)] hexa-hydrate, arose unexpectedly due to possible contamination of the K2ReF6 starting material with KReO4. It consists of octa-hedral [Co(NH3)6]3+ cation (Co1 site symmetry 1), tetra-hedral [ReVIIO4]- anions (Re site symmetry 1) and octa-hedral [ReIVF6]2- anions (Re site symmetries 1and ). The [ReF6]2- octa-hedral anions (mean Re-F = 1.834 Å), [Co(NH3)6]3+ octa-hedral cations (mean Co-N = 1.962 Å), and the [ReO4]- tetra-hedral anion (mean Re-O = 1.719 Å) are slightly distorted. A network of N-H⋯F hydrogen bonds consolidates the structure. The crystal studied was refined as a two-component twin.The title hydrated salt, tris-[hexa-amminecobalt(III)] tetraoxidorhenate(VII) tetra-kis-[hexa-fluorido-rhenate(IV)] hexa-hydrate, arose unexpectedly due to possible contamination of the K2ReF6 starting material with KReO4. It consists of octa-hedral [Co(NH3)6]3+ cation (Co1 site symmetry 1), tetra-hedral [ReVIIO4]- anions (Re site symmetry 1) and octa-hedral [ReIVF6]2- anions (Re site symmetries 1and ). The [ReF6]2- octa-hedral anions (mean Re-F = 1.834 Å), [Co(NH3)6]3+ octa-hedral cations (mean Co-N = 1.962 Å), and the [ReO4]- tetra-hedral anion (mean Re-O = 1.719 Å) are slightly distorted. A network of N-H⋯F hydrogen bonds consolidates the structure. The crystal studied was refined as a two-component twin.</description><identifier>ISSN: 2056-9890</identifier><identifier>EISSN: 2056-9890</identifier><identifier>DOI: 10.1107/S2056989019009757</identifier><language>eng</language><ispartof>Acta crystallographica. Section E, Crystallographic communications, 2019-08, Vol.75 (Pt 8), p.1158</ispartof><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><link.rule.ids>314,776,780,860,27903,27904</link.rule.ids></links><search><creatorcontrib>Louis-Jean, James</creatorcontrib><creatorcontrib>Mariappan Balasekaran, Samundeeswari</creatorcontrib><creatorcontrib>Hagenbach, Adelheid</creatorcontrib><creatorcontrib>Poineau, Frederic</creatorcontrib><title>An unexpected rhenium(IV)-rhenium(VII) salt: Co(NH3)63ReVIIO4ReIVF64·6H2O</title><title>Acta crystallographica. Section E, Crystallographic communications</title><description>The title hydrated salt, tris-[hexa-amminecobalt(III)] tetraoxidorhenate(VII) tetra-kis-[hexa-fluorido-rhenate(IV)] hexa-hydrate, arose unexpectedly due to possible contamination of the K2ReF6 starting material with KReO4. It consists of octa-hedral [Co(NH3)6]3+ cation (Co1 site symmetry 1), tetra-hedral [ReVIIO4]- anions (Re site symmetry 1) and octa-hedral [ReIVF6]2- anions (Re site symmetries 1and ). The [ReF6]2- octa-hedral anions (mean Re-F = 1.834 Å), [Co(NH3)6]3+ octa-hedral cations (mean Co-N = 1.962 Å), and the [ReO4]- tetra-hedral anion (mean Re-O = 1.719 Å) are slightly distorted. A network of N-H⋯F hydrogen bonds consolidates the structure. The crystal studied was refined as a two-component twin.The title hydrated salt, tris-[hexa-amminecobalt(III)] tetraoxidorhenate(VII) tetra-kis-[hexa-fluorido-rhenate(IV)] hexa-hydrate, arose unexpectedly due to possible contamination of the K2ReF6 starting material with KReO4. It consists of octa-hedral [Co(NH3)6]3+ cation (Co1 site symmetry 1), tetra-hedral [ReVIIO4]- anions (Re site symmetry 1) and octa-hedral [ReIVF6]2- anions (Re site symmetries 1and ). The [ReF6]2- octa-hedral anions (mean Re-F = 1.834 Å), [Co(NH3)6]3+ octa-hedral cations (mean Co-N = 1.962 Å), and the [ReO4]- tetra-hedral anion (mean Re-O = 1.719 Å) are slightly distorted. A network of N-H⋯F hydrogen bonds consolidates the structure. The crystal studied was refined as a two-component twin.</description><issn>2056-9890</issn><issn>2056-9890</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2019</creationdate><recordtype>article</recordtype><recordid>eNqVyrEKwjAUheEgCor6AG4d26F6kzSpdRNRGgcLVbpK0SsqbVpNC76Zu0-mgoKr0_n5OIQMKAwpBX-0ZiBkMA6ABgCBL_wG6bzJfVvzp9ukb8wZAKgnuBSsQ5ZTbdUabyXuKtxb1yPqU53bKnHcbydKOZZJs2pizQp7FXJH8hhfGnkxqmQhvcddhizqkdYhzQz2P9sl9mK-mYVueS0uNZpqm5_MDrMs1VjUZsuYL5hkjAP_4_oEJo9Euw</recordid><startdate>20190801</startdate><enddate>20190801</enddate><creator>Louis-Jean, James</creator><creator>Mariappan Balasekaran, Samundeeswari</creator><creator>Hagenbach, Adelheid</creator><creator>Poineau, Frederic</creator><scope>7X8</scope></search><sort><creationdate>20190801</creationdate><title>An unexpected rhenium(IV)-rhenium(VII) salt: Co(NH3)63ReVIIO4ReIVF64·6H2O</title><author>Louis-Jean, James ; Mariappan Balasekaran, Samundeeswari ; Hagenbach, Adelheid ; Poineau, Frederic</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-proquest_miscellaneous_22752622303</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2019</creationdate><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Louis-Jean, James</creatorcontrib><creatorcontrib>Mariappan Balasekaran, Samundeeswari</creatorcontrib><creatorcontrib>Hagenbach, Adelheid</creatorcontrib><creatorcontrib>Poineau, Frederic</creatorcontrib><collection>MEDLINE - Academic</collection><jtitle>Acta crystallographica. Section E, Crystallographic communications</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Louis-Jean, James</au><au>Mariappan Balasekaran, Samundeeswari</au><au>Hagenbach, Adelheid</au><au>Poineau, Frederic</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>An unexpected rhenium(IV)-rhenium(VII) salt: Co(NH3)63ReVIIO4ReIVF64·6H2O</atitle><jtitle>Acta crystallographica. Section E, Crystallographic communications</jtitle><date>2019-08-01</date><risdate>2019</risdate><volume>75</volume><issue>Pt 8</issue><spage>1158</spage><pages>1158-</pages><issn>2056-9890</issn><eissn>2056-9890</eissn><abstract>The title hydrated salt, tris-[hexa-amminecobalt(III)] tetraoxidorhenate(VII) tetra-kis-[hexa-fluorido-rhenate(IV)] hexa-hydrate, arose unexpectedly due to possible contamination of the K2ReF6 starting material with KReO4. It consists of octa-hedral [Co(NH3)6]3+ cation (Co1 site symmetry 1), tetra-hedral [ReVIIO4]- anions (Re site symmetry 1) and octa-hedral [ReIVF6]2- anions (Re site symmetries 1and ). The [ReF6]2- octa-hedral anions (mean Re-F = 1.834 Å), [Co(NH3)6]3+ octa-hedral cations (mean Co-N = 1.962 Å), and the [ReO4]- tetra-hedral anion (mean Re-O = 1.719 Å) are slightly distorted. A network of N-H⋯F hydrogen bonds consolidates the structure. The crystal studied was refined as a two-component twin.The title hydrated salt, tris-[hexa-amminecobalt(III)] tetraoxidorhenate(VII) tetra-kis-[hexa-fluorido-rhenate(IV)] hexa-hydrate, arose unexpectedly due to possible contamination of the K2ReF6 starting material with KReO4. It consists of octa-hedral [Co(NH3)6]3+ cation (Co1 site symmetry 1), tetra-hedral [ReVIIO4]- anions (Re site symmetry 1) and octa-hedral [ReIVF6]2- anions (Re site symmetries 1and ). The [ReF6]2- octa-hedral anions (mean Re-F = 1.834 Å), [Co(NH3)6]3+ octa-hedral cations (mean Co-N = 1.962 Å), and the [ReO4]- tetra-hedral anion (mean Re-O = 1.719 Å) are slightly distorted. A network of N-H⋯F hydrogen bonds consolidates the structure. The crystal studied was refined as a two-component twin.</abstract><doi>10.1107/S2056989019009757</doi></addata></record>
fulltext fulltext
identifier ISSN: 2056-9890
ispartof Acta crystallographica. Section E, Crystallographic communications, 2019-08, Vol.75 (Pt 8), p.1158
issn 2056-9890
2056-9890
language eng
recordid cdi_proquest_miscellaneous_2275262230
source DOAJ Directory of Open Access Journals; PubMed Central; Free Full-Text Journals in Chemistry; PubMed Central Open Access
title An unexpected rhenium(IV)-rhenium(VII) salt: Co(NH3)63ReVIIO4ReIVF64·6H2O
url https://sfx.bib-bvb.de/sfx_tum?ctx_ver=Z39.88-2004&ctx_enc=info:ofi/enc:UTF-8&ctx_tim=2025-01-27T21%3A51%3A00IST&url_ver=Z39.88-2004&url_ctx_fmt=infofi/fmt:kev:mtx:ctx&rfr_id=info:sid/primo.exlibrisgroup.com:primo3-Article-proquest&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.genre=article&rft.atitle=An%20unexpected%20rhenium(IV)-rhenium(VII)%20salt:%20Co(NH3)63ReVIIO4ReIVF64%C2%B76H2O&rft.jtitle=Acta%20crystallographica.%20Section%20E,%20Crystallographic%20communications&rft.au=Louis-Jean,%20James&rft.date=2019-08-01&rft.volume=75&rft.issue=Pt%208&rft.spage=1158&rft.pages=1158-&rft.issn=2056-9890&rft.eissn=2056-9890&rft_id=info:doi/10.1107/S2056989019009757&rft_dat=%3Cproquest%3E2275262230%3C/proquest%3E%3Curl%3E%3C/url%3E&disable_directlink=true&sfx.directlink=off&sfx.report_link=0&rft_id=info:oai/&rft_pqid=2275262230&rft_id=info:pmid/&rfr_iscdi=true