Cobalt-Catalyzed Hydroacylative Dimerization of Allenes Leading to Skipped Dienes

A cobalt–diphosphine catalyst has been found to promote a selective 1:2 coupling reaction between aldehydes and allenes to form β,δ-dialkylidene ketones, featuring skipped diene moieties, with high regioselectivities and stereoselectivities. The reaction is distinct from previously reported, rhodium...

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Veröffentlicht in:	Organic letters 2019-08, Vol.21 (15), p.6173-6178
Hauptverfasser:	Ding, Wei, Ho, Yan King Terence, Okuda, Yasuhiro, Wijaya, Christopher Kevin, Tan, Zheng Hao, Yoshikai, Naohiko
Format:	Artikel
Sprache:	eng
Online-Zugang:	Volltext
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