High-pressure effects on the benzene pre-crystallization metastable states

. We report new results on the liquid to solid phase transition of benzene. We determine experimentally and investigate the properties of a number of parameters of the benzene metastable state under different pressures (from 0.1 up to 2200atm). It is shown that the supercooling, pressure drop, incub...

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Veröffentlicht in:	The European physical journal. E, Soft matter and biological physics Soft matter and biological physics, 2019-08, Vol.42 (8), p.96-10, Article 96
Hauptverfasser:	Azreg-Aïnou, Mustapha, İbrahimoğlu, Beycan
Format:	Artikel
Sprache:	eng
Schlagworte:	Benzene Biological and Medical Physics Biophysics Complex Fluids and Microfluidics Complex Systems Condensed matter physics Crystallization External pressure Freezing Helium Hydrocarbons Interpolation Metastable state Nanotechnology Parameters Phase transitions Physics Physics and Astronomy Polymer Sciences Pressure drop Pressure effects Regular Article Soft and Granular Matter Solid phases Supercooling Surfaces and Interfaces Thin Films
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container_title	The European physical journal. E, Soft matter and biological physics
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creator	Azreg-Aïnou, Mustapha İbrahimoğlu, Beycan
description	. We report new results on the liquid to solid phase transition of benzene. We determine experimentally and investigate the properties of a number of parameters of the benzene metastable state under different pressures (from 0.1 up to 2200atm). It is shown that the supercooling, pressure drop, incubation period, time of abrupt transition from the metastable state to the crystalline state, and time of isothermal freezing all decrease as the external pressure increases, then they all vanish at 2200atm and 356K which may mark the end-point of metastability. Quadratic interpolation formulas for these parameters are provided. The densities and molar heat capacities of supercooled benzene under different pressures have been calculated too. Graphical abstract
doi_str_mv	10.1140/epje/i2019-11863-2
format	Article
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We report new results on the liquid to solid phase transition of benzene. We determine experimentally and investigate the properties of a number of parameters of the benzene metastable state under different pressures (from 0.1 up to 2200atm). It is shown that the supercooling, pressure drop, incubation period, time of abrupt transition from the metastable state to the crystalline state, and time of isothermal freezing all decrease as the external pressure increases, then they all vanish at 2200atm and 356K which may mark the end-point of metastability. Quadratic interpolation formulas for these parameters are provided. The densities and molar heat capacities of supercooled benzene under different pressures have been calculated too. 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E, Soft matter and biological physics</title><addtitle>Eur. Phys. J. E</addtitle><addtitle>Eur Phys J E Soft Matter</addtitle><description>. We report new results on the liquid to solid phase transition of benzene. We determine experimentally and investigate the properties of a number of parameters of the benzene metastable state under different pressures (from 0.1 up to 2200atm). It is shown that the supercooling, pressure drop, incubation period, time of abrupt transition from the metastable state to the crystalline state, and time of isothermal freezing all decrease as the external pressure increases, then they all vanish at 2200atm and 356K which may mark the end-point of metastability. Quadratic interpolation formulas for these parameters are provided. The densities and molar heat capacities of supercooled benzene under different pressures have been calculated too. 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subjects	Benzene Biological and Medical Physics Biophysics Complex Fluids and Microfluidics Complex Systems Condensed matter physics Crystallization External pressure Freezing Helium Hydrocarbons Interpolation Metastable state Nanotechnology Parameters Phase transitions Physics Physics and Astronomy Polymer Sciences Pressure drop Pressure effects Regular Article Soft and Granular Matter Solid phases Supercooling Surfaces and Interfaces Thin Films
title	High-pressure effects on the benzene pre-crystallization metastable states
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