Link between Photoelectron Circular Dichroism and Fragmentation Channel in Strong Field Ionization

Link between Photoelectron Circular Dichroism and Fragmentation Channel in Strong Field Ionization

The investigation of the photoelectron circular dichroism (PECD) in the strong field regime (800 nm, 6.9 × 1013 W/cm2) on methyloxirane (MOX) reveals a flip of the sign of PECD between different fragmentation channels. This finding is of great importance for future experiments and applications in ch...

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Veröffentlicht in:The journal of physical chemistry. A, Molecules, spectroscopy, kinetics, environment, & general theory Molecules, spectroscopy, kinetics, environment, & general theory, 2019-08, Vol.123 (30), p.6491-6495
Hauptverfasser: Fehre, Kilian, Eckart, Sebastian, Kunitski, Maksim, Janke, Christian, Trabert, Daniel, Rist, Jonas, Weller, Miriam, Hartung, Alexander, Schmidt, Lothar Ph. H, Jahnke, Till, Dörner, Reinhard, Schöffler, Markus
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container_issue 30
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container_title The journal of physical chemistry. A, Molecules, spectroscopy, kinetics, environment, & general theory
container_volume 123
creator Fehre, Kilian
Eckart, Sebastian
Kunitski, Maksim
Janke, Christian
Trabert, Daniel
Rist, Jonas
Weller, Miriam
Hartung, Alexander
Schmidt, Lothar Ph. H
Jahnke, Till
Dörner, Reinhard
Schöffler, Markus
description The investigation of the photoelectron circular dichroism (PECD) in the strong field regime (800 nm, 6.9 × 1013 W/cm2) on methyloxirane (MOX) reveals a flip of the sign of PECD between different fragmentation channels. This finding is of great importance for future experiments and applications in chemistry or pharmacy using PECD in the strong field regime as analysis method. We suggest that the observed sign change of PECD is not caused by ionization from different orbitals but by effectively selecting differently oriented nonisotropic subsamples of molecules via the fragmentation channel.
doi_str_mv 10.1021/acs.jpca.9b04210
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title Link between Photoelectron Circular Dichroism and Fragmentation Channel in Strong Field Ionization
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