Fused Heteroaromatic Rings via Metal-Mediated/Catalyzed Intramolecular C–H Activation: A Comprehensive Review
The present review highlights the most important recent contributions toward the synthesis of functionalized fused heteroaromatic rings via intramolecular C–H activation mediated or catalyzed by transition metals. This type of reaction constitutes a versatile strategy to obtain a great variety of fu...
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Veröffentlicht in: | Topics in current chemistry (2016) 2019-08, Vol.377 (4), p.21-21, Article 21 |
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description | The present review highlights the most important recent contributions toward the synthesis of functionalized fused heteroaromatic rings via intramolecular C–H activation mediated or catalyzed by transition metals. This type of reaction constitutes a versatile strategy to obtain a great variety of fused heterocyclic systems through the formation of carbon–carbon (C–C) and C–heteroatom bonds from direct coupling between two adjacent C–H bonds or C–H/H–X bonds. The revision is focused on the synthesis of fused heterocycles through two chemical processes: (1) metal-catalyzed intramolecular oxidative C–H activation, and (2) intramolecular C–H activation mediated by metallic Lewis acids. |
doi_str_mv | 10.1007/s41061-019-0246-3 |
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subjects | Catalysis Chemistry Chemistry and Materials Science Chemistry/Food Science Copper - chemistry Heterocyclic Compounds - chemical synthesis Heterocyclic Compounds - chemistry Life Sciences Materials Science Molecular Medicine Molecular Structure Palladium - chemistry Physics Review Transition Elements |
title | Fused Heteroaromatic Rings via Metal-Mediated/Catalyzed Intramolecular C–H Activation: A Comprehensive Review |
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