Structural and Computational Analysis of 2‐Halogeno‐Glycosyl Cations in the Presence of a Superacid: An Expansive Platform

An expansive NMR‐based structural analysis of elusive glycosyl cations derived from natural and non‐natural monosaccharides in superacids is disclosed. For the first time, it has been possible to explore the consequence of deoxygenation and halogen substitution at the C2 position in a series of 2‐ha...

Ausführliche Beschreibung

Bibliographische Detailangaben

Veröffentlicht in:	Angewandte Chemie International Edition 2019-09, Vol.58 (39), p.13758-13762
Hauptverfasser:	Lebedel, Ludivine, Ardá, Ana, Martin, Amélie, Désiré, Jérôme, Mingot, Agnès, Aufiero, Marialuisa, Aiguabella Font, Nuria, Gilmour, Ryan, Jiménez‐Barbero, Jesus, Blériot, Yves, Thibaudeau, Sébastien
Format:	Artikel
Sprache:	eng
Schlagworte:	Anions Cations Computer applications conformation analysis Deoxygenation Fluorine glycosylation Intermediates Monosaccharides NMR Nuclear magnetic resonance Nucleophiles reaction mechanisms Structural analysis superacids
Online-Zugang:	Volltext
Tags:	Tag hinzufügen Keine Tags, Fügen Sie den ersten Tag hinzu!