Organic semiconductor photocatalyst can bifunctionalize arenes and heteroarenes

Photoexcited electron-hole pairs on a semiconductor surface can engage in redox reactions with two different substrates. Similar to conventional electrosynthesis, the primary redox intermediates afford only separate oxidized and reduced products or, more rarely, combine to one addition product. Here...

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Veröffentlicht in:Science (American Association for the Advancement of Science) 2019-07, Vol.365 (6451), p.360-366
Hauptverfasser: Ghosh, Indrajit, Khamrai, Jagadish, Savateev, Aleksandr, Shlapakov, Nikita, Antonietti, Markus, König, Burkhard
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Sprache:eng
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