Structure-Property Relationships via Recovery Rheology in Viscoelastic Materials
The recoverable strain is shown to correlate to the temporal evolution of microstructure via time-resolved small-angle neutron scattering and dynamic shear rheology. Investigating two distinct polymeric materials of wormlike micelles and fibrin network, we demonstrate that, in addition to the nonlin...
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| Veröffentlicht in: | Physical review letters 2019-06, Vol.122 (24), p.248003-248003, Article 248003 |
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| container_title | Physical review letters |
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| creator | Lee, Johnny Ching-Wei Weigandt, Katie M Kelley, Elizabeth G Rogers, Simon A |
| description | The recoverable strain is shown to correlate to the temporal evolution of microstructure via time-resolved small-angle neutron scattering and dynamic shear rheology. Investigating two distinct polymeric materials of wormlike micelles and fibrin network, we demonstrate that, in addition to the nonlinear structure-property relationships, the shear and normal stress evolution is dictated by the recoverable strain. A distinct sequence of physical processes under large amplitude oscillatory shear (LAOS) is identified that clearly contains information regarding both the steady-state flow curve and the linear-regime frequency sweep, contrary to most interpretations that LAOS responses are either distinct from or somehow intermediate between the two cases. This work provides a physically motivated and straightforward path to further explore the structure-property relationships of viscoelastic materials under dynamic flow conditions. |
| doi_str_mv | 10.1103/PhysRevLett.122.248003 |
| format | Article |
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Investigating two distinct polymeric materials of wormlike micelles and fibrin network, we demonstrate that, in addition to the nonlinear structure-property relationships, the shear and normal stress evolution is dictated by the recoverable strain. A distinct sequence of physical processes under large amplitude oscillatory shear (LAOS) is identified that clearly contains information regarding both the steady-state flow curve and the linear-regime frequency sweep, contrary to most interpretations that LAOS responses are either distinct from or somehow intermediate between the two cases. 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| ispartof | Physical review letters, 2019-06, Vol.122 (24), p.248003-248003, Article 248003 |
| issn | 0031-9007 1079-7114 |
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| source | American Physical Society Journals; EZB-FREE-00999 freely available EZB journals |
| subjects | Equilibrium flow Evolution Fibrin Materials recovery Micelles Neutron scattering Recoverable strain Rheological properties Rheology Shear Viscoelastic materials Viscoelasticity |
| title | Structure-Property Relationships via Recovery Rheology in Viscoelastic Materials |
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