Synthetic, structural and reaction chemistry of N-heterocyclic germylene and stannylene compounds featuring N-boryl substituents

This study details the syntheses of N-heterocyclic germylenes and stannylenes featuring diazaborolyl groups, {(HCDippN)2B} (Dipp = 2,6-iPr2C6H3), as both of the N-bound substituents, with a view to generating electron rich and sterically protected metal centres. The energies of their key frontier or...

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Veröffentlicht in:Dalton transactions : an international journal of inorganic chemistry 2019-08, Vol.48 (31), p.11951-11960
Hauptverfasser: Kristinsdóttir, Lilja, Oldroyd, Nicola L, Grabiner, Rachel, Knights, Alastair W, Heilmann, Andreas, Protchenko, Andrey V, Niu, Haoyu, Kolychev, Eugene L, Campos, Jesús, Hicks, Jamie, Christensen, Kirsten E, Aldridge, Simon
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Sprache:eng
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