Synthesis of aminyl biradicals by base-induced Csp3–Csp3 coupling of cationic azo dyes

The synthesis of the industrially important polymer parylene is achieved by polymerization of p-quinodimethane (p-QDM). The polymerization is thought to proceed via a biradical p-QDM dimer, but isolation or characterization of such a biradical has remained elusive. Here, we describe the synthesis of...

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Veröffentlicht in:	Chemical science (Cambridge) 2019-06, Vol.10 (22), p.5719-5724
Hauptverfasser:	Liu, Yizhu, Varava, Paul, Fabrizio, Alberto, Eymann, Léonard Y M, Tskhovrebov, Alexander G, Planes, Ophélie Marie, Solari, Euro, Fadaei-Tirani, Farzaneh, Scopelliti, Rosario, Sienkiewicz, Andrzej, Corminboeuf, Clémence, Severin, Kay
Format:	Artikel
Sprache:	eng
Schlagworte:	Azo dyes Chemical reactions Chemical synthesis Chemistry Coupling Crystallography Dimerization Dimers Polymerization Stability analysis
Online-Zugang:	Volltext
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