Bidentate Geometry-Constrained Iminopyridyl Ligands in Cobalt Catalysis: Highly Markovnikov-Selective Hydrosilylation of Alkynes

Reported herein is a well-defined bidentate geometry-constrained iminopyridyl cobalt complex for an efficient and highly Markovnikov-selective hydrosilylation of alkynes, featuring a broad substrate scope including aromatic/heteroaromatic/aliphatic alkynes and primary/secondary silanes. TON is up to...

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Veröffentlicht in:	Organic letters 2019-07, Vol.21 (14), p.5767-5772
Hauptverfasser:	Zong, Zhijian, Yu, Qianwen, Sun, Nan, Hu, Baoxiang, Shen, Zhenlu, Hu, Xinquan, Jin, Liqun
Format:	Artikel
Sprache:	eng
Online-Zugang:	Volltext
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