Extraction Mechanism of Lanthanide Ions into Silica-based Microparticles Studied by Single Microparticle Manipulation and Microspectroscopy
Single porous silica microparticles coated with a styrene-divinylbenzene polymer (SDB) impregnated with octyl(phenyl)-N,N-diisobutylcarbamoylmethylphosphine oxide (CMPO) were injected into an aqueous 3 mol/L nitric acid solution containing trivalent lanthanide (Ln(III)), as a high-level liquid waste...
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| Veröffentlicht in: | Analytical Sciences 2019/10/10, Vol.35(10), pp.1129-1133 |
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| creator | OTAKA, Toshiki SATO, Tatsumi ONO, Simpei NAGOSHI, Kohei ABE, Ryoji ARAI, Tsuyoshi WATANABE, Sou SANO, Yuichi TAKEUCHI, Masayuki NAKATANI, Kiyoharu |
| description | Single porous silica microparticles coated with a styrene-divinylbenzene polymer (SDB) impregnated with octyl(phenyl)-N,N-diisobutylcarbamoylmethylphosphine oxide (CMPO) were injected into an aqueous 3 mol/L nitric acid solution containing trivalent lanthanide (Ln(III)), as a high-level liquid waste model. We used the microcapillary manipulation-injection technique; and the extraction rate of Ln(III), as an Ln(III)-CMPO complex, into the single microparticles was measured by luminescence microspectroscopy. The extraction rate significantly depended on the Ln(III), CMPO, or NO3− concentration, and was analyzed in terms of diffusion in the pores of the microparticles and the complex formation of Ln(III). The results indicated that the rate-determining step in Ln(III) extraction was diffusion in the pore solution of the microparticles. |
| doi_str_mv | 10.2116/analsci.19P155 |
| format | Article |
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We used the microcapillary manipulation-injection technique; and the extraction rate of Ln(III), as an Ln(III)-CMPO complex, into the single microparticles was measured by luminescence microspectroscopy. The extraction rate significantly depended on the Ln(III), CMPO, or NO3− concentration, and was analyzed in terms of diffusion in the pores of the microparticles and the complex formation of Ln(III). The results indicated that the rate-determining step in Ln(III) extraction was diffusion in the pore solution of the microparticles.</description><identifier>ISSN: 0910-6340</identifier><identifier>EISSN: 1348-2246</identifier><identifier>DOI: 10.2116/analsci.19P155</identifier><identifier>PMID: 31281133</identifier><language>eng</language><publisher>Singapore: The Japan Society for Analytical Chemistry</publisher><subject>Analytical Chemistry ; Chemistry ; Complex formation ; diffusion ; Diffusion rate ; Divinylbenzene ; extraction ; high-level liquid waste ; lanthanide ; Liquid wastes ; Microparticles ; microspectroscopy ; Nitric acid ; Silica ; Silica-based microparticle ; Silicon dioxide ; Styrene</subject><ispartof>Analytical Sciences, 2019/10/10, Vol.35(10), pp.1129-1133</ispartof><rights>2019 by The Japan Society for Analytical Chemistry</rights><rights>The Japan Society for Analytical Chemistry 2019</rights><rights>Copyright Japan Science and Technology Agency 2019</rights><lds50>peer_reviewed</lds50><oa>free_for_read</oa><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c531t-2658abb80bd725a04452fc3e7868194b737c8115599566533cde2fdf6173ae833</citedby><cites>FETCH-LOGICAL-c531t-2658abb80bd725a04452fc3e7868194b737c8115599566533cde2fdf6173ae833</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://link.springer.com/content/pdf/10.2116/analsci.19P155$$EPDF$$P50$$Gspringer$$H</linktopdf><linktohtml>$$Uhttps://link.springer.com/10.2116/analsci.19P155$$EHTML$$P50$$Gspringer$$H</linktohtml><link.rule.ids>315,781,785,1884,27929,27930,41493,42562,51324</link.rule.ids><backlink>$$Uhttps://www.ncbi.nlm.nih.gov/pubmed/31281133$$D View this record in MEDLINE/PubMed$$Hfree_for_read</backlink></links><search><creatorcontrib>OTAKA, Toshiki</creatorcontrib><creatorcontrib>SATO, Tatsumi</creatorcontrib><creatorcontrib>ONO, Simpei</creatorcontrib><creatorcontrib>NAGOSHI, Kohei</creatorcontrib><creatorcontrib>ABE, Ryoji</creatorcontrib><creatorcontrib>ARAI, Tsuyoshi</creatorcontrib><creatorcontrib>WATANABE, Sou</creatorcontrib><creatorcontrib>SANO, Yuichi</creatorcontrib><creatorcontrib>TAKEUCHI, Masayuki</creatorcontrib><creatorcontrib>NAKATANI, Kiyoharu</creatorcontrib><title>Extraction Mechanism of Lanthanide Ions into Silica-based Microparticles Studied by Single Microparticle Manipulation and Microspectroscopy</title><title>Analytical Sciences</title><addtitle>ANAL. SCI</addtitle><addtitle>Anal Sci</addtitle><description>Single porous silica microparticles coated with a styrene-divinylbenzene polymer (SDB) impregnated with octyl(phenyl)-N,N-diisobutylcarbamoylmethylphosphine oxide (CMPO) were injected into an aqueous 3 mol/L nitric acid solution containing trivalent lanthanide (Ln(III)), as a high-level liquid waste model. We used the microcapillary manipulation-injection technique; and the extraction rate of Ln(III), as an Ln(III)-CMPO complex, into the single microparticles was measured by luminescence microspectroscopy. The extraction rate significantly depended on the Ln(III), CMPO, or NO3− concentration, and was analyzed in terms of diffusion in the pores of the microparticles and the complex formation of Ln(III). The results indicated that the rate-determining step in Ln(III) extraction was diffusion in the pore solution of the microparticles.</description><subject>Analytical Chemistry</subject><subject>Chemistry</subject><subject>Complex formation</subject><subject>diffusion</subject><subject>Diffusion rate</subject><subject>Divinylbenzene</subject><subject>extraction</subject><subject>high-level liquid waste</subject><subject>lanthanide</subject><subject>Liquid wastes</subject><subject>Microparticles</subject><subject>microspectroscopy</subject><subject>Nitric acid</subject><subject>Silica</subject><subject>Silica-based microparticle</subject><subject>Silicon dioxide</subject><subject>Styrene</subject><issn>0910-6340</issn><issn>1348-2246</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2019</creationdate><recordtype>article</recordtype><recordid>eNp1kcFu1DAQhi0EokvhyhFZ4sIlW9sTO8kRVQtU2lWR2p4jx3EWr7J2sB2p-wy8NE4TFoHUi8f2fPOPZn6E3lOyZpSKK2llH5RZ0-o75fwFWlHIy4yxXLxEK1JRkgnIyQV6E8KBEMpKxl6jC0gXSgFW6NfmMXqponEW77T6Ia0JR-w6vJU2Tq9W4xtnAzY2OnxneqNk1sigW7wzyrtB-mhUrwO-i2Nr0ndzSpjd9_pfAO-S2DD28qmVtEt9GLSKKSg3nN6iV12aRr9b4iV6-LK5v_6WbW-_3lx_3maKA40ZE7yUTVOSpi0YlyTPOesU6KIUJa3ypoBCpek4ryouBAdQrWZd2wlagNQlwCX6NOsO3v0cdYj10QSl-15a7cZQM8ahBFaRIqEf_0MPbvTTzmsGBEglikokaj1T00DB664evDlKf6opqSeb6sWmerYpFXxYZMfmqNsz_seXBFzNQEgpu9f-b99nJTdzxSFEuddnyWX9Zxz4pDCdT3XnfLLe19rCbwUBuco</recordid><startdate>20191010</startdate><enddate>20191010</enddate><creator>OTAKA, Toshiki</creator><creator>SATO, Tatsumi</creator><creator>ONO, Simpei</creator><creator>NAGOSHI, Kohei</creator><creator>ABE, Ryoji</creator><creator>ARAI, Tsuyoshi</creator><creator>WATANABE, Sou</creator><creator>SANO, Yuichi</creator><creator>TAKEUCHI, Masayuki</creator><creator>NAKATANI, Kiyoharu</creator><general>The Japan Society for Analytical Chemistry</general><general>Springer Nature Singapore</general><general>Japan Science and Technology Agency</general><scope>NPM</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>7QF</scope><scope>7QO</scope><scope>7QQ</scope><scope>7SE</scope><scope>7SR</scope><scope>7U5</scope><scope>8BQ</scope><scope>8FD</scope><scope>FR3</scope><scope>H8G</scope><scope>JG9</scope><scope>L7M</scope><scope>P64</scope><scope>7X8</scope></search><sort><creationdate>20191010</creationdate><title>Extraction Mechanism of Lanthanide Ions into Silica-based Microparticles Studied by Single Microparticle Manipulation and Microspectroscopy</title><author>OTAKA, Toshiki ; SATO, Tatsumi ; ONO, Simpei ; NAGOSHI, Kohei ; ABE, Ryoji ; ARAI, Tsuyoshi ; WATANABE, Sou ; SANO, Yuichi ; TAKEUCHI, Masayuki ; NAKATANI, Kiyoharu</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c531t-2658abb80bd725a04452fc3e7868194b737c8115599566533cde2fdf6173ae833</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2019</creationdate><topic>Analytical Chemistry</topic><topic>Chemistry</topic><topic>Complex formation</topic><topic>diffusion</topic><topic>Diffusion rate</topic><topic>Divinylbenzene</topic><topic>extraction</topic><topic>high-level liquid waste</topic><topic>lanthanide</topic><topic>Liquid wastes</topic><topic>Microparticles</topic><topic>microspectroscopy</topic><topic>Nitric acid</topic><topic>Silica</topic><topic>Silica-based microparticle</topic><topic>Silicon dioxide</topic><topic>Styrene</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>OTAKA, Toshiki</creatorcontrib><creatorcontrib>SATO, Tatsumi</creatorcontrib><creatorcontrib>ONO, Simpei</creatorcontrib><creatorcontrib>NAGOSHI, Kohei</creatorcontrib><creatorcontrib>ABE, Ryoji</creatorcontrib><creatorcontrib>ARAI, Tsuyoshi</creatorcontrib><creatorcontrib>WATANABE, Sou</creatorcontrib><creatorcontrib>SANO, Yuichi</creatorcontrib><creatorcontrib>TAKEUCHI, Masayuki</creatorcontrib><creatorcontrib>NAKATANI, Kiyoharu</creatorcontrib><collection>PubMed</collection><collection>CrossRef</collection><collection>Aluminium Industry Abstracts</collection><collection>Biotechnology Research Abstracts</collection><collection>Ceramic Abstracts</collection><collection>Corrosion Abstracts</collection><collection>Engineered Materials Abstracts</collection><collection>Solid State and Superconductivity Abstracts</collection><collection>METADEX</collection><collection>Technology Research Database</collection><collection>Engineering Research Database</collection><collection>Copper Technical Reference Library</collection><collection>Materials Research Database</collection><collection>Advanced Technologies Database with Aerospace</collection><collection>Biotechnology and BioEngineering Abstracts</collection><collection>MEDLINE - Academic</collection><jtitle>Analytical Sciences</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>OTAKA, Toshiki</au><au>SATO, Tatsumi</au><au>ONO, Simpei</au><au>NAGOSHI, Kohei</au><au>ABE, Ryoji</au><au>ARAI, Tsuyoshi</au><au>WATANABE, Sou</au><au>SANO, Yuichi</au><au>TAKEUCHI, Masayuki</au><au>NAKATANI, Kiyoharu</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Extraction Mechanism of Lanthanide Ions into Silica-based Microparticles Studied by Single Microparticle Manipulation and Microspectroscopy</atitle><jtitle>Analytical Sciences</jtitle><stitle>ANAL. 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| subjects | Analytical Chemistry Chemistry Complex formation diffusion Diffusion rate Divinylbenzene extraction high-level liquid waste lanthanide Liquid wastes Microparticles microspectroscopy Nitric acid Silica Silica-based microparticle Silicon dioxide Styrene |
| title | Extraction Mechanism of Lanthanide Ions into Silica-based Microparticles Studied by Single Microparticle Manipulation and Microspectroscopy |
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