A Dynamic Hydrogen‐Bonded Azo‐Macrocycle for Precisely Photo‐Controlled Molecular Encapsulation and Release

A light‐responsive system constructed from hydrogen‐bonded azo‐macrocycles demonstrates precisely controlled propensity in molecular encapsulation and release process. A significant decrease in the size of the cavity is observed in the course of the E→Z photoisomerization based on the results from D...

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Veröffentlicht in:	Angewandte Chemie International Edition 2019-09, Vol.58 (36), p.12519-12523
Hauptverfasser:	Ye, Zecong, Yang, Zhiyao, Wang, Lei, Chen, Lixi, Cai, Yimin, Deng, Pengchi, Feng, Wen, Li, Xiaopeng, Yuan, Lihua
Format:	Artikel
Sprache:	eng
Schlagworte:	Cage molecules Cations Encapsulation Exchanging host–guest systems hydrogen-bonded macrocycle Ionic mobility Irradiation Light irradiation Mass spectrometry Mass spectroscopy Molecular machines NMR Nuclear magnetic resonance photochemistry precise release Radiation Stoichiometry supramolecular chemistry Switches Traveling waves
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