3‑Thioaryne Intermediates for the Synthesis of Diverse Thioarenes

The synthetic utility of 3-thioaryne intermediates has been demonstrated through an aryne relay approach. The efficient synthesis of o-silylaryl triflate-type 3-thioaryne precursors has been achieved by the regioselective silylthiolation of 3-(triflyloxy)­arynes with silyl sulfides. Various 3-thioar...

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Veröffentlicht in:	Organic letters 2019-07, Vol.21 (13), p.5252-5258
Hauptverfasser:	Nakamura, Yu, Miyata, Yoshihiro, Uchida, Keisuke, Yoshida, Suguru, Hosoya, Takamitsu
Format:	Artikel
Sprache:	eng
Online-Zugang:	Volltext
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