Ion-exchange resin as a new tool for characterisation of coordination compounds and MOFs by NMR spectroscopy
1 H and 13 C NMR spectroscopy is used to investigate the organic constituents of metal complexes, MOFs and coordination compounds synthesised under solvothermal and precipitation conditions. The elucidation of the ligands in paramagnetic compounds bearing Cu 2+ (d 9 ), Gd 3+ (f 7 ), Eu 3+ (f 6 ), Fe...
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| Veröffentlicht in: | Chemical communications (Cambridge, England) England), 2019-07, Vol.55 (56), p.816-819 |
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| container_title | Chemical communications (Cambridge, England) |
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| creator | Galaço, Ayla Roberta Borges da Silva de Oliveira, Kleber Thiago Donatoni, Maria Carolina Walton, Richard I Serra, Osvaldo Antonio |
| description | 1
H and
13
C NMR spectroscopy is used to investigate the organic constituents of metal complexes, MOFs and coordination compounds synthesised under solvothermal and precipitation conditions. The elucidation of the ligands in paramagnetic compounds bearing Cu
2+
(d
9
), Gd
3+
(f
7
), Eu
3+
(f
6
), Fe
3+
(d
5
), ions after treatment with a cationic exchange resin is possible. We prove the efficiency of two post-synthesis linker modifications on diamagnetic IRMOF-3 Zn
2+
(d
10
) with ethyl isocyanate and benzyl bromide.
1
H and
13
C NMR spectroscopy is used to investigate the organic constituents of paramagnetic MOFs and coordination compounds using a cationic exchange resin. Post-modifications on MOFs were performed and quantitatively determined by this methodology. |
| doi_str_mv | 10.1039/c9cc03721g |
| format | Article |
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H and
13
C NMR spectroscopy is used to investigate the organic constituents of metal complexes, MOFs and coordination compounds synthesised under solvothermal and precipitation conditions. The elucidation of the ligands in paramagnetic compounds bearing Cu
2+
(d
9
), Gd
3+
(f
7
), Eu
3+
(f
6
), Fe
3+
(d
5
), ions after treatment with a cationic exchange resin is possible. We prove the efficiency of two post-synthesis linker modifications on diamagnetic IRMOF-3 Zn
2+
(d
10
) with ethyl isocyanate and benzyl bromide.
1
H and
13
C NMR spectroscopy is used to investigate the organic constituents of paramagnetic MOFs and coordination compounds using a cationic exchange resin. Post-modifications on MOFs were performed and quantitatively determined by this methodology.</description><identifier>ISSN: 1359-7345</identifier><identifier>EISSN: 1364-548X</identifier><identifier>DOI: 10.1039/c9cc03721g</identifier><identifier>PMID: 31232423</identifier><language>eng</language><publisher>England: Royal Society of Chemistry</publisher><subject>Benzyl bromide ; Cation exchanging ; Coordination compounds ; Copper ; Diamagnetism ; Gadolinium ; Ion exchange ; Ion exchange resins ; Isocyanates ; Metal-organic frameworks ; Metallurgical constituents ; NMR spectroscopy ; Spectrum analysis</subject><ispartof>Chemical communications (Cambridge, England), 2019-07, Vol.55 (56), p.816-819</ispartof><rights>Copyright Royal Society of Chemistry 2019</rights><lds50>peer_reviewed</lds50><oa>free_for_read</oa><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c399t-400b45c2ccc7ccf58643e0f31ca67cfeaea2f395200e98a457fdbdccd48e78bb3</citedby><cites>FETCH-LOGICAL-c399t-400b45c2ccc7ccf58643e0f31ca67cfeaea2f395200e98a457fdbdccd48e78bb3</cites><orcidid>0000-0002-9131-4800 ; 0000-0001-9706-2774 ; 0000-0003-1851-2218</orcidid></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><link.rule.ids>314,776,780,27901,27902</link.rule.ids><backlink>$$Uhttps://www.ncbi.nlm.nih.gov/pubmed/31232423$$D View this record in MEDLINE/PubMed$$Hfree_for_read</backlink></links><search><creatorcontrib>Galaço, Ayla Roberta Borges da Silva</creatorcontrib><creatorcontrib>de Oliveira, Kleber Thiago</creatorcontrib><creatorcontrib>Donatoni, Maria Carolina</creatorcontrib><creatorcontrib>Walton, Richard I</creatorcontrib><creatorcontrib>Serra, Osvaldo Antonio</creatorcontrib><title>Ion-exchange resin as a new tool for characterisation of coordination compounds and MOFs by NMR spectroscopy</title><title>Chemical communications (Cambridge, England)</title><addtitle>Chem Commun (Camb)</addtitle><description>1
H and
13
C NMR spectroscopy is used to investigate the organic constituents of metal complexes, MOFs and coordination compounds synthesised under solvothermal and precipitation conditions. The elucidation of the ligands in paramagnetic compounds bearing Cu
2+
(d
9
), Gd
3+
(f
7
), Eu
3+
(f
6
), Fe
3+
(d
5
), ions after treatment with a cationic exchange resin is possible. We prove the efficiency of two post-synthesis linker modifications on diamagnetic IRMOF-3 Zn
2+
(d
10
) with ethyl isocyanate and benzyl bromide.
1
H and
13
C NMR spectroscopy is used to investigate the organic constituents of paramagnetic MOFs and coordination compounds using a cationic exchange resin. Post-modifications on MOFs were performed and quantitatively determined by this methodology.</description><subject>Benzyl bromide</subject><subject>Cation exchanging</subject><subject>Coordination compounds</subject><subject>Copper</subject><subject>Diamagnetism</subject><subject>Gadolinium</subject><subject>Ion exchange</subject><subject>Ion exchange resins</subject><subject>Isocyanates</subject><subject>Metal-organic frameworks</subject><subject>Metallurgical constituents</subject><subject>NMR spectroscopy</subject><subject>Spectrum analysis</subject><issn>1359-7345</issn><issn>1364-548X</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2019</creationdate><recordtype>article</recordtype><recordid>eNp90ctLHTEUB-BQKvXRbrpvibgphWnznJksy6BW8AFiobshc-bEjsxNpskMev97o9dacGE2SThfDkl-hHzk7Btn0nwHA8BkJfj1G7LDZakKrerfbx_W2hSVVHqb7KZ0w_Lgun5HtiUXUighd8h4EnyBd_DH-mukEdPgqU3UUo-3dA5hpC5EmsvRwoxxSHYegqfBUQgh9oPf7CGsprD4Pp_0PT27OEq0W9Pzs0uaJoQ5hgRhWr8nW86OCT88zXvk19HhVfOzOL04Pml-nBYgjZkLxVinNAgAqACcrkslkTnJwZYVOLRohZNGC8bQ1FbpyvVdD9CrGqu66-Qe-bLpO8Xwd8E0t6shAY6j9RiW1AqhSqE4lyLTgxf0JizR59tlpWXFTWl0Vl83CvJLUkTXTnFY2bhuOWsfMmgb0zSPGRxn_Pmp5dKtsH-m_z49g_0NiAmeq_9DbKfeZfPpNSPvARIRl7Y</recordid><startdate>20190709</startdate><enddate>20190709</enddate><creator>Galaço, Ayla Roberta Borges da Silva</creator><creator>de Oliveira, Kleber Thiago</creator><creator>Donatoni, Maria Carolina</creator><creator>Walton, Richard I</creator><creator>Serra, Osvaldo Antonio</creator><general>Royal Society of Chemistry</general><scope>NPM</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>7SR</scope><scope>7U5</scope><scope>8BQ</scope><scope>8FD</scope><scope>JG9</scope><scope>L7M</scope><scope>7X8</scope><orcidid>https://orcid.org/0000-0002-9131-4800</orcidid><orcidid>https://orcid.org/0000-0001-9706-2774</orcidid><orcidid>https://orcid.org/0000-0003-1851-2218</orcidid></search><sort><creationdate>20190709</creationdate><title>Ion-exchange resin as a new tool for characterisation of coordination compounds and MOFs by NMR spectroscopy</title><author>Galaço, Ayla Roberta Borges da Silva ; de Oliveira, Kleber Thiago ; Donatoni, Maria Carolina ; Walton, Richard I ; Serra, Osvaldo Antonio</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c399t-400b45c2ccc7ccf58643e0f31ca67cfeaea2f395200e98a457fdbdccd48e78bb3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2019</creationdate><topic>Benzyl bromide</topic><topic>Cation exchanging</topic><topic>Coordination compounds</topic><topic>Copper</topic><topic>Diamagnetism</topic><topic>Gadolinium</topic><topic>Ion exchange</topic><topic>Ion exchange resins</topic><topic>Isocyanates</topic><topic>Metal-organic frameworks</topic><topic>Metallurgical constituents</topic><topic>NMR spectroscopy</topic><topic>Spectrum analysis</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Galaço, Ayla Roberta Borges da Silva</creatorcontrib><creatorcontrib>de Oliveira, Kleber Thiago</creatorcontrib><creatorcontrib>Donatoni, Maria Carolina</creatorcontrib><creatorcontrib>Walton, Richard I</creatorcontrib><creatorcontrib>Serra, Osvaldo Antonio</creatorcontrib><collection>PubMed</collection><collection>CrossRef</collection><collection>Engineered Materials Abstracts</collection><collection>Solid State and Superconductivity Abstracts</collection><collection>METADEX</collection><collection>Technology Research Database</collection><collection>Materials Research Database</collection><collection>Advanced Technologies Database with Aerospace</collection><collection>MEDLINE - Academic</collection><jtitle>Chemical communications (Cambridge, England)</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Galaço, Ayla Roberta Borges da Silva</au><au>de Oliveira, Kleber Thiago</au><au>Donatoni, Maria Carolina</au><au>Walton, Richard I</au><au>Serra, Osvaldo Antonio</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Ion-exchange resin as a new tool for characterisation of coordination compounds and MOFs by NMR spectroscopy</atitle><jtitle>Chemical communications (Cambridge, England)</jtitle><addtitle>Chem Commun (Camb)</addtitle><date>2019-07-09</date><risdate>2019</risdate><volume>55</volume><issue>56</issue><spage>816</spage><epage>819</epage><pages>816-819</pages><issn>1359-7345</issn><eissn>1364-548X</eissn><abstract>1
H and
13
C NMR spectroscopy is used to investigate the organic constituents of metal complexes, MOFs and coordination compounds synthesised under solvothermal and precipitation conditions. The elucidation of the ligands in paramagnetic compounds bearing Cu
2+
(d
9
), Gd
3+
(f
7
), Eu
3+
(f
6
), Fe
3+
(d
5
), ions after treatment with a cationic exchange resin is possible. We prove the efficiency of two post-synthesis linker modifications on diamagnetic IRMOF-3 Zn
2+
(d
10
) with ethyl isocyanate and benzyl bromide.
1
H and
13
C NMR spectroscopy is used to investigate the organic constituents of paramagnetic MOFs and coordination compounds using a cationic exchange resin. Post-modifications on MOFs were performed and quantitatively determined by this methodology.</abstract><cop>England</cop><pub>Royal Society of Chemistry</pub><pmid>31232423</pmid><doi>10.1039/c9cc03721g</doi><tpages>4</tpages><orcidid>https://orcid.org/0000-0002-9131-4800</orcidid><orcidid>https://orcid.org/0000-0001-9706-2774</orcidid><orcidid>https://orcid.org/0000-0003-1851-2218</orcidid><oa>free_for_read</oa></addata></record> |
| fulltext | fulltext |
| identifier | ISSN: 1359-7345 |
| ispartof | Chemical communications (Cambridge, England), 2019-07, Vol.55 (56), p.816-819 |
| issn | 1359-7345 1364-548X |
| language | eng |
| recordid | cdi_proquest_miscellaneous_2246241132 |
| source | Royal Society Of Chemistry Journals 2008-; Alma/SFX Local Collection |
| subjects | Benzyl bromide Cation exchanging Coordination compounds Copper Diamagnetism Gadolinium Ion exchange Ion exchange resins Isocyanates Metal-organic frameworks Metallurgical constituents NMR spectroscopy Spectrum analysis |
| title | Ion-exchange resin as a new tool for characterisation of coordination compounds and MOFs by NMR spectroscopy |
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