Strategies for the Synthesis of Chiral Carbon‐Bridged Group IV ansa‐Metallocenes

This minireview provides a survey of the various synthetic approaches to chiral ansa‐metallocenes of Ti, Zr, and Hf containing a carbon‐based bridge. The individual strategies to install substitution patterns at either the cyclopentadienyl framework or the bridging unit are highlighted with focus on...

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Veröffentlicht in:	Chemistry : a European journal 2019-08, Vol.25 (45), p.10531-10545
Hauptverfasser:	Bau, Michael A., Wiesler, Stefan, Younas, Sara L., Streuff, Jan
Format:	Artikel
Sprache:	eng
Schlagworte:	Carbon Catalysis Chemistry hafnium ligand design Metallocenes Organic chemistry Organometallic compounds Purification Racemization Stereoisomers stereoselective synthesis Synthesis Titanium Zirconium
Online-Zugang:	Volltext
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