rtl-M-MOFs (M = Cu, Zn) with a T-shaped bifunctional pyrazole-isophthalate ligand showing flexibility and S-shaped Type F-IV sorption isotherms with high saturation uptakes for M = Cu

Two new rtl-MOFs rtl-[Cu(HIsa-az-dmpz)] and rtl-[Zn(HIsa-az-dmpz)] have been synthesized by using the new bifunctional ligand 5-(4-(3,5-dimethyl-1H-pyrazolyl)azo)isophthalic acid (H3Isa-az-dmpz). Both frameworks are potentially porous structures with DMF molecules included in the channels of the as...

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Veröffentlicht in:	Dalton transactions : an international journal of inorganic chemistry 2019-05, Vol.48 (23), p.8057-8067
Hauptverfasser:	Millan, Simon, Gil-Hernández, Beatriz, Milles, Erik, Gökpinar, Serkan, Makhloufi, Gamall, Schmitz, Alexa, Schlüsener, Carsten, Janiak, Christoph
Format:	Artikel
Sprache:	eng
Schlagworte:	Activation Adsorption Carbon dioxide Cryogenic effects Cryogenic temperature Crystallography Gravimetry Ligands Metal-organic frameworks Phase transitions Pyrazole Saturation T shape
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